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nMgCL2=0.2(mol)
nKOH=0.3(mol)
MgCL2+2KOH->Mg(OH)2+2KCl
0.2 0.3
->MgCl dư
nMg(OH)2=0.15(mol)CM=0.6(M)
nKCl=0.3(mol)CM=1.2(M)
nMgCl dư=0.2-0.3:2=0.05(mol)CM=0.2(M)
\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)
a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
3KOH +FeCl3 --> Fe(OH)3 +3KCl(1)
2Fe(OH)3 -->Fe2O3 +3H2O(2)
Fe2O3 +3CO -->2Fe +3CO2(3)
nFeCl3=0,1.1=0,1(mol)
theo (2) : nFe2O3=1/2nFe(OH)3=0,05(mol)
theo (3) : nFe=2nFe2O3=0,1(mol)
=> mFe=0,1.56=5,6(g)
\(n_{FeCl_3}=0,1mol\)
\(n_{KOH}=0,4mol\)
FeCl3+3KOH\(\rightarrow\)Fe(OH)3\(\downarrow\)+3KCl
-Tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{3}\rightarrow\)KOH dư
\(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,1mol\)
\(m_{Fe\left(OH\right)_3}=0,1.107=10,7gam\)
2Fe(OH)3\(\overset{t^0}{\rightarrow}Fe_2O_3+3H_2O\)
\(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}.0,1=0,05mol\)
\(m_{Fe_2O_3}=0,05.160=8gam\)
\(n_{KCl}=n_{KOH\left(pu\right)}=3n_{FeCl_3}=0,3mol\)
\(n_{KOH\left(dư\right)}=0,4-0,3=0,1mol\)
\(V_{dd}=0,1+0,4=0,5l\)
\(C_{M_{KOH}}=\dfrac{n}{v}=\dfrac{0,1}{0,5}=0,2M\)
\(C_{M_{KCl}}=\dfrac{n}{v}=\dfrac{0,3}{0,5}=0,6M\)