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a.\(n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{12,25}{122,5}=0,1mol\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
2 2 3 ( mol )
0,1 0,15
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
b.\(V_{kk}=V_{O_2}.5=3,36.5=16,8l\)
c.\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{28}{56}=0,5mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
3 2 1 ( mol )
0,5 > 0,15 ( mol )
0,225 0,15 ( mol )
\(m_{Fe\left(du\right)}=n_{Fe\left(du\right)}.M_{Fe}=\left(0,5-0,225\right).56=15,4g\)
\(a) 2KClO_3 \xrightarrow{t^o,MnO_2} 2KCl +3 O_2\\ n_{O_2} = \dfrac{3}{2}n_{KClO_3} = \dfrac{3}{2}. \dfrac{9,8}{122,5} = 0,12(mol)\\ \Rightarrow V_{O_2} = 0,12.22,4 = 2,688(lít)\\ b) 2H_2O \xrightarrow{điện\ phân} 2H_2 + O_2\\ n_{O_2} = \dfrac{1}{2}n_{H_2O} = \dfrac{1}{2}. \dfrac{36.1000}{18} = 1000(mol)\\ \Rightarrow V_{O_2} = 1000.22,4 = 22400(lít)\)
\(â.\)
\(n_{KClO_3}=\dfrac{9.8}{122.5}=0.08\left(mol\right)\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(0.08........................0.12\)
\(V_{O_2}=0.12\cdot22.4=2.688\left(l\right)\)
\(b.\)
\(n_{H_2O}=\dfrac{36\cdot1000}{18}=2000\left(mol\right)\)
\(2H_2O\underrightarrow{t^0}2H_2+O_2\)
\(2000..................1000\)
\(V_{O_2}=1000\cdot22.4=22400\left(l\right)\)
2KClO3-to>2KCl+3O2
0,2---------------------0,3
4P+5O2-to->2P2O5
--0,3-------0,12 mol
n KClO3=\(\dfrac{24,5}{122,5}=0,2mol\)
=>VO2=0,3.22,4=6,72l
=>m P2O5=0,12.142=17,04g
=>Vkk=6.72.5=33,6l
nKClO3 = 24,5 : 122,5 = 0,2 (mol)
pthh : 2KClO3 -t--> 2KCl +3 O2
0,2---------------------> 0,3(MOL)
VO2 = 0,3 .22,4 = 6,72 (L)
pthh : 4P+5O2-t--> 2P2O 5
0,3---> 0,12 (mol)
=> mP2O5 = 0,12 . 142 = 17,04 (g)
ta co : Vkk = VO2:21% = 6,72 : 21% 32 (l)
a)
2KMnO4 -to-> K2MnO4 + MnO2 + O2
0.5__________________________0.25
VO2 = 0.25*22.4 = 5.6 (l)
2KClO3 -to-> 2KCl + 3O2
0.5_______________0.75
VO2 = 0.75*22.4 = 16.8 (l)
2KNO3 -to-> 2KNO2 + O2
0.5________________0.25
VO2 = 0.25*22.4 = 5.6 (l)
2HgO -to-> 2Hg + O2
0.5____________0.25
VO2 = 0.25*22.4 = 5.6 (l)
b)
nKNO3 = 50/101 (mol)
2KNO3 -to-> 2KNO2 + O2
50/101______________25/101
VO2 = 25/101 * 22.4 = 5.54 (l)
nHgO = 50/217 (mol)
2HgO -to-> 2Hg + O2
50/217 _________25/217
VO2 = 2.58 (l)
a) $2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$
b) n KMnO4 = 15,8/158 = 0,1(mol)
Theo PTHH : n O2 = 1/2 n KMnO4 = 0,05(mol)
=> V O2 = 0,05.22,4 = 1,12(lít)
c)
$3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4$
Theo PTHH : n Fe = 3/2 nO2 = 0,075(mol)
=> m Fe = 0,075.56 = 4,2(gam)
2KMNO4-to->K2MnO4+MnO2+O2
0,4--------------------------------------0,2 mol
n KMNO4=\(\dfrac{63,2}{158}\)=0,4 mol
=>H=10%
=>VO2=0,2.22,4.90%=4,032l
nKMnO4(lt) = 63,2 : 158 = 0,4 (mol)
nKMnO4(tt) = 0,4 . 10 % = 0,04 ( mol)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,04------------------------------------->0,02 (mol)
=> VO2 = 0,02.22,4 = 0,448 (L)
\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,1 0,05 ( mol )
\(V_{O_2}=n_{O_2}.24=0,05.24=1,2l\)
\(a.2KClO_3-^{t^o}\rightarrow2KCl+3O_2\\ n_{O_2}=\dfrac{3}{2}n_{KClO_3}=0,6\left(mol\right)\\ \Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\\ n_{KCl}=n_{KClO_3}=0,4\left(mol\right)\\ \Rightarrow m_{KCl}=0,4.74,5=29,8\left(g\right)\)
$,9 g?
\(n_{KClO_3}=\dfrac{4.9}{122,5}=0,04\left(mol\right)\)
2KClO3 ---to---> 2KCl + 3O2
0,04 0,06
\(V_{O_2}=0,06.22,4=1,344\left(l\right)\)