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a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{H_2SO_4}=0,2.98=19,6\left(g\right)\)
c, \(C\%_{H_2SO_4}=\dfrac{19,6}{50}.100\%=39,2\%\)
d, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.2..........0.3...............0.1...........0.3\)
\(m_{H_2SO_4}=0.3\cdot98=29.4\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{29.4\cdot100}{20}=147\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0.1\cdot342=34.2\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng }}=5.4+147-0.3\cdot2=151.8\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34.2}{151.8}\cdot100\%=22.53\%\)
a) Mg + H2SO4 --> MgSO4 + H2
b) \(n_{Mg}=\dfrac{3}{24}=0,125\left(mol\right)\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
0,125->0,125-->0,125-->0,125
=> VH2 = 0,125.22,4 = 2,8 (l)
\(V_{dd.H_2SO_4}=\dfrac{0,125}{2}=0,0625\left(l\right)\)
c) Sản phẩm là Magie sunfat và khí hidro
\(m_{MgSO_4}=0,125.120=15\left(g\right)\)
mH2 = 0,125.2 = 0,25 (g)
d)
\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,125}{1}\) => Hiệu suất tính theo H2
Gọi số mol CuO bị khử là a (mol)
PTHH: CuO + H2 --to--> Cu + H2O
a--->a-------->a
=> 16 - 80a + 64a = 14,4
=> a = 0,1 (mol)
=> nH2(pư) = 0,1 (mol)
=> \(H=\dfrac{0,1}{0,125}.100\%=80\%\)
$a) 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$b) n_{Al} = \dfrac{10,8}{27} = 0,4(mol)$
Theo PTHH : $n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,6(mol)$
$m_{H_2SO_4} = 0,6.98 = 58,8(gam)$
$c) n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,2(mol) \Rightarrow m_{Al_2(SO_4)_3} = 0,2.342 = 68,4(gam)$
$d) n_{H_2} = n_{H_2SO_4} = 0,6(mol) \Rightarrow V_{H_2} = 0,6.22,4 = 13,44(lít)$
\(a,2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(b.n_{Al}=\dfrac{m}{M}=0,4\left(mol\right)\)
\(Theo.PTHH\Rightarrow n_{H_2SO_4}=n_{H_2}=\dfrac{3}{2}n_{Al}=1,5.0,4=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=n.M=0,6.98=58,8\left(g\right)\)
\(c,Theo.PTHH\Rightarrow n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,5.0,4=0,2\left(mol\right)\\ \Rightarrow m_{Al_2\left(SO_4\right)_3}=n.M=0,2.342=68,4\left(g\right)\\ d,V_{H_2\left(dktc\right)}=n.22,4=0,6.22,4=13,44\left(l\right)\)
Fe + 2HCl -> FeCl2 + H2
nFe = 5,6/56 = 0,1 mol
=>nH2 = 0,1 mol
=> VH2= 0,1*22,4= 2,24 lít
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,1-->0,2------------------>0,1
=> \(\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,2.36,5}{15\%}=\dfrac{146}{3}\left(g\right)\\V_{H_2}=0,1.22,4=4,48\left(l\right)\end{matrix}\right.\)
b) Tính khối lượng H2SO4 dư sau pư, biết H2SO4 đã lấy dư so với lượng pư là 10%
a, \(n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{FeSO_4}=n_{H_2}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow m_{FeSO_4}=0,01.152=1,52\left(g\right)\)
\(V_{H_2}=0,01.22,4=0,224\left(l\right)\)
b, \(n_{H_2SO_4}=n_{Fe}=0,01\left(mol\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{0,01.98}{19,6\%}=5\left(g\right)\)
c, Ta có: m dd sau pư = 0,56 + 5 - 0,01.2 = 5,54 (g)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{1,52}{5,54}.100\%\approx27,44\%\)
$a\big)2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2$
$b\big)$
$n_{Al}=\dfrac{2,7}{27}=0,1(mol)$
Theo PT: $n_{H_2SO_4}=1,5n_{Al}=0,15(mol)$
$\to m_{dd\,H_2SO_4}=\dfrac{0,15.98}{30\%}=49(g)$
$c\big)$
Theo PT: $n_{H_2}=0,15(mol);n_{Al_2(SO_4)_3}=0,05(mol)$
$\to V_{H_2}=0,15.22,4=3,36(l)$
$\to m_{Al_2(SO_4)_3}=0,05.342=17,1(g)$