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a, \(n_{OH^-}=10^{-1}.V_A\left(mol\right)\)
\(n_{H^+}=10^{-2}.V_B\left(mol\right)\)
\(n_{OH^-dư}=10^{-2}.\left(V_A+V_B\right)\left(mol\right)\)
Ta có: \(n_{OH^-}-n_{OH^-dư}=n_{H^+}\)
\(\Leftrightarrow10^{-1}.V_A-10^{-2}.\left(V_A+V_B\right)=10^{-2}.V_B\)
\(\Leftrightarrow0,09V_A=0,02V_B\)
\(\Rightarrow\dfrac{V_A}{V_B}=\dfrac{2}{9}\)
b, Ta có: \(\left\{{}\begin{matrix}V_A+V_B=0,55\\\dfrac{V_A}{V_B}=\dfrac{2}{9}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}V_A=0,1\left(l\right)\\V_B=0,45\left(l\right)\end{matrix}\right.\)
\(n_{BaCl_2}=\dfrac{1}{2}n_{Cl^-}=\dfrac{1}{2}n_{H^+}=\dfrac{1}{2}.10^{-2}.0,1=0,0005\left(mol\right)\Rightarrow m_{BaCl_2}=0,104\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{OH^-dư}=\dfrac{1}{2}.10^{-2}.0,55=0,00275\left(mol\right)\Rightarrow m_{Ba\left(OH\right)_2}=0,047025\left(g\right)\)
\(\Rightarrow\%m_{Ba\left(OH\right)_2}=\dfrac{0,047025}{0,047025+0,104}.100\%=31,14\%\)
\(\Rightarrow\%m_{BaCl_2}=62,86\%\)
Sau phản ứng, \(V_{dd}= V_1 + V_2(lít)\)
Ta có : [H+] = 10-3 ⇒ \(n_{H_2SO_4} = 5.10^{-4}V_1(mol)\)
Lại có: \(n_{NaOH} = V_2.\dfrac{10^{-14}}{10^{-12}} = 0,01V_2(mol)\)
pH = 4 < 7 Chứng tỏ axit dư
2NaOH + H2SO4 → Na2SO4 + 2H2O
0,01V2.......5.10-3V2..................................(mol)
Suy ra : \(\dfrac{5.10^{-4}V_1-5.10^{-3}V_2}{V_1+V_2}.2 = 10^{-4}\\ \Rightarrow \dfrac{V_1}{V_2} = \dfrac{101}{9}\)
Đáp án B
HCl\(\rightarrow\)H+ + Cl-
\(\rightarrow\) [H+]=CM HCl=0,1 M
\(\rightarrow\)pH=-log[H+]=1M
$pH = -log([H^+]) = -log(10^{-4}) = 4$
Đáp án C
pH= -log[H+]= -log[10-4]=4