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KCl + O2
a, PT: \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Ta có: \(n_{KClO_3}=\dfrac{24,5}{122,5}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{2}n_{KClO_3}=0,3\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,3.24,79=7,437\left(g\right)\)
b, PT: \(2Cu+O_2\underrightarrow{t^o}2CuO\)
Ta có: \(n_{Cu}=\dfrac{32}{64}=0,5\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{0,3}{1}\), ta được O2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{Cu}=0,25\left(mol\right)\\n_{CuO}=n_{Cu}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,3-0,25=0,05\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,05.32=1,6\left(g\right)\)
\(m_{CuO}=0,5.80=40\left(g\right)\)
\(n_{KClO_3}=\dfrac{61,25}{122,5}=0,5mol\)
\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,5 0,75 ( mol )
\(V_{O_2}=0,75.22,4=16,8l\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,6<------------------------------0,3
=> mKMnO4 = 0,6.158 = 94,8 (g)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,2<----------------0,3
=> mKClO3 = 0,2.122,5 = 24,5 (g)
2KMnO4-to>K2MnO4+MnO2+O2
0,2-------------------------------------0,1
3Fe+2O2-to>Fe3O4
0,15----0,1 mol
=>n KMnO4=\(\dfrac{31,6}{158}\)=0,2 mol
=>VO2=0,1.22,4=2,24l
=>m Fe=0,15.56=8,4g
\(a.\)
\(n_{KClO_3}=\dfrac{3.675}{122.5}=0.03\left(mol\right)\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(0.03........................0.045\)
\(V_{O_2}=0.045\cdot22.4=1.008\left(l\right)\)
\(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
\(\Rightarrow n_{KClO_3}=\dfrac{0.5\cdot2}{3}=\dfrac{1}{3}mol\)
\(\Rightarrow m_{KClO_3}=\dfrac{1}{3}\cdot122.5=40.83\left(g\right)\)
Ta có: \(n_{KClO_3}=\dfrac{49}{122,5}=0,4\left(mol\right)\)
PT: \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
______0,4______0,4_____0,6 (mol)
\(\Rightarrow m_{KCl}=0,4.74,5=29,8\left(g\right)\)
\(V_{O_2}=0,6.22,4=13,44\left(l\right)\)