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\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
a) \(\overline{M}_A=5,875.2=11,75\left(g/mol\right)\)
b) Gọi số mol N2, H2 là a, b (mol)
\(\overline{M}_A=\dfrac{28a+2b}{a+b}=11,75\left(g/mol\right)\)
=> 16,25a = 9,75b
=> a = 0,6b
\(\left\{{}\begin{matrix}\%n_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{0,6b}{0,6b+b}.100\%=37,5\%\\\%n_{H_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{0,6b+b}.100\%=62,5\%\end{matrix}\right.\)
c)
1 mol hỗn hợp A chứa \(\left\{{}\begin{matrix}n_{N_2}=\dfrac{1.37,5}{100}=0,375\left(mol\right)\\n_{H_2}=\dfrac{1.62,5}{100}=0,625\left(mol\right)\end{matrix}\right.\)
\(\overline{M}_B=\dfrac{0,375.28+0,625.2+17x}{1+x}=6,4.2=12,8\left(g/mol\right)\)
=> x = 0,25 (mol)
a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
Có : \(d_{\dfrac{hh}{kk}}=0,3276\)
\(\Rightarrow M_{hh}=9,5004\)
\(\Rightarrow\dfrac{n_{O_2}}{n_{H_2}}=\dfrac{~1}{3}\)
=> %O2 = 25% . %H2 = 75 % .
1, a, + 8.2=16 => CH4
+ 8,5 . 2 = 17 => NH3
+ 16 . 2 =32 => O2
+ 22 . 2 = 44 => CO2
b, + 0,138 . 29 \(\approx4\) => He
+ 1,172 . 29 \(\approx34\) => H2S
+ 2,448 . 29 \(\approx71\Rightarrow Cl_2\)
+ 0,965 . 29 \(\approx28\) => N
Giả sử: \(\left\{{}\begin{matrix}n_{N_2}=x\left(mol\right)\\n_{H_2}=y\left(mol\right)\end{matrix}\right.\)
Vì: dA/He = 1,8
\(\Rightarrow\overline{M_A}=1,8.4=7,2\)
\(\Rightarrow\dfrac{28x+2y}{x+y}=7,2\)
\(\Rightarrow4x=y\)
Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là %V.
\(\Rightarrow\left\{{}\begin{matrix}\%V_{N_2}=\dfrac{x}{x+y}.100\%=\dfrac{x}{x+4x}.100\%=20\%\\\%V_{H_2}=100-20=80\%\end{matrix}\right.\)
Bạn tham khảo nhé!