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\(n_A=\dfrac{10}{22,4}=\dfrac{25}{56}mol\)
\(\left\{{}\begin{matrix}n_{SO_2}=x\left(mol\right)\\n_{O_2}=y\left(mol\right)\end{matrix}\right.\Rightarrow x+y=\dfrac{25}{56}\left(1\right)\)
\(d_A\)/CH4=3\(\Rightarrow M_A=48\)
Sử dụng đường chéo:
\(\dfrac{n_{SO_2}}{n_{O_2}}=\dfrac{x}{y}=\dfrac{1}{3}\left(2\right)\)
\(\Rightarrow\left\{{}\begin{matrix}x=\dfrac{25}{224}\\y=\dfrac{75}{224}\end{matrix}\right.\)
\(V_{SO_2}=\dfrac{25}{224}\cdot22,4=2,5l\)
\(V_{O_2}=10-2,5=7,5l\)
a, \(n_{CH_4}=\dfrac{33,6.60\%}{22,4}=0,9\left(mol\right)\)
\(n_{C_2H_6}=\dfrac{33,6.40\%}{22,4}=0,6\left(mol\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_6+7O_2\underrightarrow{t^o}4CO_2+6H_2O\)
Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{7}{2}n_{C_2H_6}=3,9\left(mol\right)\Rightarrow V_{O_2}=3,9.22,4=87,36\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=436,8\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{CO_2}=n_{CH_4}+2n_{C_2H_6}=2,1\left(mol\right)\\n_{H_2O}=2n_{CH_4}+3n_{C_2H_6}=3,6\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{CO_2}=2,1.44=92,4\left(g\right)\)
\(m_{H_2O}=3,6.18=64,8\left(g\right)\)
c, \(\overline{M_X}=\dfrac{0,9.16+0,6.30}{0,9+0,6}=21,6\left(g/mol\right)\)
\(\Rightarrow d_{X/H_2}=\dfrac{21,6}{2}=10,8\)
Đặt \(n_{O_2}=x;n_{CO_2}=y\)
\(n_X=\dfrac{4,48}{22,4}=0,2\left(mol\right)\Leftrightarrow x+y=0,2\)
Ta có: \(16x+44y=\left(x+y\right).18.2\)
\(\Leftrightarrow2y=5x\)
\(\Leftrightarrow\dfrac{y}{5}=\dfrac{x}{2}\)
Mà x+y=0,2
\(\Rightarrow\dfrac{y}{5}=\dfrac{x}{2}=\dfrac{x+y}{5+2}=\dfrac{0,2}{7}=0,0286\)
\(\Rightarrow y=5.0,0286=0,143\left(mol\right);x=0,2-0,143=0,057\left(mol\right)\)
Chọn nCO2 = 6 , nH2O = 7
Hỗn hợp Y gồm nO2 = a mol, nO3 = b mol
X + Y → CO2 + H2O
Áp dụng ĐLBT nguyên tố O: 2a + 3b = 6.2 + 7
mY = 32a + 48b = 19.2 (a+b)
=> a = 5 và b = 3
=> nX = 1/2 nY = 4 mol
=> mX = 6.44 + 7.18 - 32.5 - 48.3 = 83 gam
<=> MX = \(\dfrac{m_X}{n_X}\)= 20,75 gam/mol
<=> d\(\dfrac{X}{H_2}\)= 20,75:2 = 10,375