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\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)
\(n_{BaO}=\frac{1,53}{137+16}=0,01mol\)
\(C\%_{Ba\left(OH\right)_2}=\frac{0,01.\left(137+16.2+2\right).100}{1,53+4,5}=28,36\%\)
a) - Dung dịch A chứa chất tan NaOH
mddNaOH= 200(g)
=> C%ddNaOH= (4/200).100=2%
nNa=4,6/23=0,2(mol)
PTHH: Na + H2O -> NaOH + 1/2 H2
0,2_______________0,2____0,1(mol)
mddNaOH=4,6+100-0,1.2=104,4(g)
mNaOH=0,2.40=8(g)
=>C%ddNaOH= (8/104,4).100=7,663%
=> Chọn B (gần nhất)
\(n_K=\frac{5,85}{15}=0,15(mol)\\ K+H_2O \to KOH +\frac{1}{2}H_2\\ n_{KOH}=n_K=0,15(mol)\\ n_{H_2}=\frac{1}{2}.n_K=\frac{1}{2}.0,15=0,075(mol)\\ m_{dd}=5,85+100-(0,075.2)=105,7(g)\\ C\%=\frac{0,15.56}{105,7}.100=7,95\%\)
a) PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)
Ta có: \(n_{SO_3}=\dfrac{24}{80}=0,3\left(mol\right)=n_{H_2SO_4}\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3\cdot98}{20\%}=147\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{147}{1,14}\approx128,95\left(ml\right)\)
b) PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
Theo PTHH: \(n_{Fe}=n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)=n_{FeSO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,3\cdot56=16,8\left(g\right)\\V_{H_2}=0,3\cdot24,76=7,428\left(l\right)\\m_{FeSO_4}=0,3\cdot152=45,6\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddH_2SO_4}-m_{H_2}=163,2\left(g\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{45,6}{163,2}\cdot100\%\approx27,94\%\)
\(K+H_2O\rightarrow KOH+\dfrac{1}{2}H_2\)
\(n_K=2n_{H_2}=0,2\left(mol\right)\Rightarrow m_K=7,8\left(g\right)\)
=> \(m_{K_2O}=17,2-7,8=9,4\Rightarrow n_{K_2O}=0,1\left(mol\right)\)
\(K_2O+H_2O\rightarrow2KOH\)
\(\Sigma n_{KOH}=0,2+0,1.2=0,4\left(mol\right)\)
\(m_{ddsaupu}=17,2+600-0,1.2=617\left(g\right)\)
=> \(C\%_{KOH}=\dfrac{0,4.56}{712}.100=3,15\%\)
\(n_{HCl}=\dfrac{44,8}{22,4}=2\)
\(\Rightarrow m_{HCl}=2.36,5=73g\)
=> \(C\%_{HCl}=\dfrac{73}{73+327}\times100\%=18,25\%\)
b.
\(n_{HCl}=\dfrac{250.18,25\%}{36,5}=1,25mol\)
\(n_{CaCO_3}=\dfrac{50}{100}=0,5mol\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(n_{CaCl_2}=n_{CO_2}=0,5mol\)
\(n_{HClpu}=0,5.2=1mol\)
\(\Rightarrow n_{HCldu}=1,25-1=0,25\)
\(\Rightarrow m_{ddpu}=50+250-0,5.44=278g\)
\(C\%_{HCl}=\dfrac{0,25.36,5}{278}.100\%=3,28\%\)
\(C\%_{CaCl_2}=\dfrac{0,5.111}{278}.100\%=19,96\%\)
\(CaO+H_2O->Ca\left(OH\right)_2\)
0,2..........................0,2
n CaO = \(\dfrac{11,2}{40+16}=0,2mol\)
m Ca(OH)2 = \(0,2.\left(40+16.2+1.2\right)=14,8g\)
C% Ca(OH)2 = \(\dfrac{14,8}{500}.100=2,96\%\)
BaO + H2O -> Ba(OH)2
0.01 0.01
nBaO=\(\dfrac{1.53}{137+16}=0.01mol\)
C%Ba(OH)2=\(\dfrac{0.01\times\left(137+16\times2+2\right)\times100}{1.53+4.5}=28.36\%\)