Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
a)Gọi x,y lần lượt là số mol của Al, Fe trong hỗn hợp ban đầu (x,y>0)
Sau phản ứng hỗn hợp muối khan gồm: \(\left\{{}\begin{matrix}AlCl_3:x\left(mol\right)\\FeCl_2:y\left(mol\right)\end{matrix}\right.\)
Ta có hệ phương trình: \(\left\{{}\begin{matrix}27x+56y=13,9\\133,5x+127y=38\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x\approx0,0896\\y\approx0,205\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,0896\cdot27\cdot100\%}{13,9}\approx17,4\%\\\%m_{Fe}=\dfrac{0,205\cdot56\cdot100\%}{13,9}\approx82,6\%\end{matrix}\right.\)
Theo Bảo toàn nguyên tố Cl, H ta có:\(n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{3n_{AlCl_3}+2n_{FeCl_2}}{2}\\ =\dfrac{3\cdot0,0896+2\cdot0,205}{2}=0,3394mol\\ \Rightarrow V_{H_2}=0,3394\cdot22,4\approx7,6l\)
Gọi n Fe = a (mol )
n Mg = b (mol ) (a,b > 0)
--> 56a+24b = 13,2
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a 2a a a
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
b 2b b b
----> a+b=0,35
Ta có hệ Pt :
\(\left\{{}\begin{matrix}56a+24b=13,2\\a+b=0,35\end{matrix}\right.\)
Giải hệ PT , ta có :
a= 0,15
b = 0,2 (mol )
\(V_{HClđủ}=\left(0,15.2+0,2.2\right):0,5=1,4\left(l\right)\)
\(a,m_{Fe}=0,15.56=8,4\left(g\right)\)
\(m_{Mg}=0,2.24=4,8\left(g\right)\)
\(\%m_{Fe}=\dfrac{8,4}{13,2}.100\%\approx63,64\%\)
\(\%m_{Mg}=\dfrac{4,8}{13,2}.100\%\approx36,36\%\)
\(b,m_{FeCl_2}=0,15.127=19,05\left(g\right)\)
\(m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(c,HCl+NaOH\rightarrow NaCl+H_2O\)
0,2 0,2
\(m_{NaOH}=\dfrac{100.8}{100}=8\left(g\right)\)
\(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(V_{HCldư}=\dfrac{n}{C_M}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
\(V_{HCl}=V_{HClđủ}+V_{HCldư}=1,4+0,4=1,8\left(l\right)\)
1)nH2= 0,224/22,4=0,01(mol)
Mg +2HCl -> MgCl2 + H2
0,01<----------------- 0,01
mMg= 0,01x 24= 0,24(g)
mCu= 0,56- 0,24= 0,32(g)
%Mg = 0,24/0.56x 100% = 42,86%
%Cu = 0,32/0,56 x 100% = 57,14%
2) nHCl = 0,6 x 1 = 0,6 (mol)
Zn + 2HCl -> ZnCl2 + H2
0,2<- 0,4<- 0,2 <- 0,2
nHCl = 0,6- 0,4 = 0,2 (mol)
ZnO + 2HCl -> ZnCl2 + H2O
0,1 <- 0,2
=> mZn = 0,2 x 65 = 13(g)
mZnO = 0,1 x 81 = 8,1 (g)
1, Zn + 2HCl--> ZnCl2 + H2(1)
ZnO + 2HCl--> ZnCl2 + H2O(2)
Ta có m dd HCl=D.V=100,8.1,19=119,952g
=> mHCl=36,5.119,952/100=43,78248 g
=> nHCl=43,78248/36,5=1,19952 mol
Ta có : nZn=nH2=0,4mol
nHCl(1)=2nH2=0,8mol
=> nHCl(2)=1,19952-0,8=0,39952mol
ta có nHCl(2)/2=nZnO=0,19976mol
=> %mZn=0,4.65.100/(0,4.65+0,19976.81)=67,39%
=> %mZnO=100-67,39=32,61%
Chúc bạn hk tốt
đề có cho bt h2 vs h2o
bao nhiu mol đâu mà sao bn biết nHCL (1 ) = 2nH2 = 0,8 thế ???
\(Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+27b=5,1\\22,4a+22,4.1,5.b=5,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ a,\Rightarrow\%m_{Mg}=\dfrac{0,1.24}{5,1}.100\approx47,059\%\\ \Rightarrow\%m_{Al}\approx100\%-47,059\%\approx52,941\%\\ b,n_{HCl}=2.n_{H_2}=2.\left(0,1+0,1.1,5\right)=0,5\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,5}{2}=0,25\left(l\right)\)
a)\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
x 2x x x
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
y 3y y 1,5y
Ta có hệ:
\(\left\{{}\begin{matrix}24x+27y=5,1\\x+1,5y=\dfrac{5,6}{22,4}=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%=47,06\%\)
\(\%m_{Al}=100\%-47,06\%=52,94\%\)
b)\(\Sigma n_{HCl}=2x+3y=2\cdot0,1+3\cdot0,1=0,5mol\)
\(V=\dfrac{n}{C_M}=\dfrac{0,5}{2}=0,25l=250ml\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
x 3x x 1,5x
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
y 2y y y
\(\left\{{}\begin{matrix}27x+56y=22\\1,5x+y=\dfrac{17,92}{22,4}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,2\end{matrix}\right.\)
\(m_{Al}=0,4\cdot27=10,8g\)
\(m_{Fe}=22-10,8=11,2g\)
\(m_{HCl}=36,5\cdot\left(3x+2y\right)=36,5\cdot\left(3\cdot0,4+2\cdot0,2\right)=58,4g\)
\(m_{ddHCl}=\dfrac{m_{HCl}}{C\%}\cdot100\%=\dfrac{58,4}{25\%}\cdot100\%=233,6g\)
\(Đặt:n_{Al}=u\left(mol\right);n_{Fe}=v\left(mol\right)\left(u,v>0\right)\\ n_{H_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56u=22\\1,5a+u=0,8\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,4\\u=0,2\end{matrix}\right.\\ \Rightarrow m_{Al}=0,4.27=10,8\left(g\right);m_{Fe}=56.0,2=11,2\left(g\right)\\ n_{HCl}=2.0,8=1,6\left(mol\right)\\ m_{HCl}=1,6.36,5=58,4\left(g\right)\\ m_{ddHCl}=\dfrac{58,4.100}{25}=233,6\left(g\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2____0,4 ________0,2______ 0,2
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,04___0,08______ 0,04________
Ta có :
\(n_{H2}=\frac{0,4}{2}=0,2\left(mol\right)\)
Đổi 960ml = 0,96 (l)
\(n_{HCl}=0,96.0,5=0,48\left(mol\right)\)
\(\%m_{Zn}=\frac{0,2.65}{0,2.65+0,04.\left(65+16\right)}.100\%=80,05\%\)
\(\%m_{ZnO}=100\%-80,05\%=19,95\%\)
\(2AgNO_3+ZnCl_2\rightarrow Zn\left(NO_3\right)_2+2AgCl_2\)
_________0,24___________________0,48
\(\rightarrow m_{AgCl2}=0,48.\left(108+71\right)=68,88\left(g\right)\)