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a/ Ta có: \(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
PTHH:
\(2Mg+O_2\underrightarrow{t^o}2MgO\)
2 1
0.2 x
\(=>x=\dfrac{0.2\cdot1}{2}=0.1=n_{O_2}\)
\(=>V_{O_2\left(đktc\right)}=0.1\cdot22.4=2.24\left(l\right)\)
b/ \(2Mg+O_2\underrightarrow{t^o}2MgO\)
2 2
0.2 y
\(=>y=\left(0.2\cdot2\right):2=0.2=n_{MgO}\)
\(=>m_{MgO}=0.2\cdot\left(24+16\right)=8\left(g\right)\)
SDPU: CH4 + O2--> CO2 + H2O
PTHH: CH4 + 2O2--> CO2 + 2H2O
1 2 1 2
0,05 0,1 0,05 0,1
nCH4=V/22,4= 1,12/22,4=0,05mol
VO2=n.22,4=0,1.22,4= 2,24 lít
VCO2=n.22,4=0,05.22,4=1,12 lít
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\a, PTHH:4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ b,n_{O_2}=\dfrac{3}{4}.n_{Al}=\dfrac{3.0,2}{4}=0,15\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\\ n_{KMnO_4}=2.n_{O_2}=2.0,15=0,3\left(mol\right)\\ \Rightarrow m_{KMnO_4}=158.0,3=47,4\left(g\right)\)
Gọi \(n_{Zn}=a\left(mol\right)\rightarrow n_{Fe}=1,6a\left(mol\right)\)
Theo đề bài: \(65a+1,6a.56=7,73\rightarrow a=0,05\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}n_{Zn}=0,05\left(mol\right)\\n_{Fe}=0,05.1,6=0,08\left(mol\right)\end{matrix}\right.\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
0,05 0,1 0,05 0,05
Fe + 2HCl ---> FeCl2 + H2
0,08 0,16 0,08 0,08
\(\rightarrow V_{H_2}=\left(0,05+0,08\right).22,4=2,912\left(l\right)\)
Gọi mE = a (g)
=> \(\left\{{}\begin{matrix}m_{Fe_2O_3}=48\%.a=0,48a\left(g\right)\\m_{CuO}=32\%.a=0,32a\left(g\right)\end{matrix}\right.\rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{0,48a}{160}=0,003a\left(mol\right)\\n_{CuO}=\dfrac{0,32a}{80}=0,004a\left(mol\right)\end{matrix}\right.\)
PTHH:
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,003a->0,009a
CuO + H2 --to--> Cu + H2O
0,004a->0,004a
\(\rightarrow0,13=0,004a+0,009a\\ \Leftrightarrow a=100\left(g\right)\)
a, Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
Fe + 2HCl ---> FeCl2 + H2
a--->2a------------------>a
2Al + 6HCl ---> 2AlCl3 + 3H2
b---->3b-------------------->1,5b
=> \(\left\{{}\begin{matrix}56a+27b=16,6\\a+1,5b=0,5\end{matrix}\right.\Leftrightarrow a=b=0,2\left(mol\right)\)
=> \(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)
b) \(C\%_{HCl}=\dfrac{\left(0,2.2+0,2.3\right).36,5}{300}.100\%=12,167\%\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
gọi nFe : a , nAl: b (a,b>0) => 56a + 27b = 16,6 (g)
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a a
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b \(\dfrac{3b}{2}\)
=> \(a+\dfrac{3b}{2}=0,5\)
ta có hệ pt
\(\left\{{}\begin{matrix}56a+27b=16,6\\a+\dfrac{3b}{2}=0,5\end{matrix}\right.\)
=> a= 0,2 , b = 0,2
\(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=16,6-11,2=5,4\left(g\right)\end{matrix}\right.\)
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 0,4
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,6
=> \(m_{HCl}=\left(0,4+0,6\right).36,5=36,5\left(g\right)\)
=> \(C\%=\dfrac{36,5}{200}.100\%=18,25\%\)
2Zn+O2-to>2ZnO
0,1---0,05----0,1
n Zn=0,1 mol
nO2=0,025 mol
=>VO2=0,05.22,4=1,12l
=>mZnO=0,1.81=8,1g
c)Zn dư
=>m ZnO=0,05.81=4,05g
2Zn+O2-to>2ZnO
0,1---0,05----0,1
n Zn=6,5/65=0,1 mol
n O2=0,8/32=0,025 mol
=>VO2=0,05.22,4=1,12l
=>mZnO=0,1.81=8,1g
c)Zn dư
=>m ZnO=0,05.81=4,05g
\(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{19,5}{65}=0,3mol\)
\(Zn+\dfrac{1}{2}O_2\rightarrow\left(t^o\right)ZnO\)
1 1/2 1 (mol)
0,3 0,15 0,3 ( mol )
PƯ trên thuộc loại phản ứng hóa hợp
\(m_{ZnO}=n_{ZnO}.M_{ZnO}=0,3.81=24,3g\)
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
2H2 + O2 --to--> 2H2O
Xét \(\dfrac{0,2}{2}>\dfrac{0,08}{1}\) => H2 dư, O2 hết
=> Hiệu suất phản ứng tính theo O2
\(n_{O_2\left(pư\right)}=\dfrac{0,08.75}{100}=0,06\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
____0,12<-0,06------>0,12
=> \(Y\left\{{}\begin{matrix}m_{O_2}=\left(0,08-0,06\right).32=0,64\left(g\right)\\m_{H_2}=\left(0,2-0,12\right).2=0,16\left(g\right)\\m_{H_2O}=0,12.18=2,16\left(g\right)\end{matrix}\right.\)
CH4 + 2O2 \(\rightarrow\)CO2 + 2H2O (1)
2CO + O2 \(\rightarrow\)2CO2 (2)
nCO2=\(\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
Đặt nCH4=a
nCO=b
Ta có:
\(\left\{{}\begin{matrix}16a+28b=15\\a+b=0,75\end{matrix}\right.\)
a=0,5;b=0,25
mCH4=0,5.16=8(g)
% CH4 =\(\dfrac{8}{15}.100\%=53,3\%\)
% CO=100-53,3=46,7%
b;
Theo PTHH 1 và 2 ta có:
\(\sum n_{O_2}=0,5.2+0,25.\dfrac{1}{2}=1,125\left(mol\right)\)
VO2=1,125.22,4=25,2(lít)