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PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\) (1)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\) (2)
a) Gọi số mol của Mg là a (mol) \(\Rightarrow n_{Al}=\dfrac{2}{3}a\left(mol\right)\)
\(\Rightarrow24a+27\cdot\dfrac{2}{3}a=6,3\) \(\Rightarrow a=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{MgO}=0,15\left(mol\right)\\n_{Al_2O_3}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgO}=0,15\cdot40=6\left(g\right)\\m_{Al_2O_3}=0,05\cdot102=5,1\left(g\right)\end{matrix}\right.\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,075\left(mol\right)\\n_{O_2\left(2\right)}=0,075\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{O_2}=0,15\left(mol\right)\) \(\Rightarrow V_{O_2}=0,15\cdot22,4=3,36\left(l\right)\)
a, PT: \(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Gọi: \(\left\{{}\begin{matrix}n_{Cu}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\\n_{Al}=z\left(mol\right)\end{matrix}\right.\) ⇒ 64x + 56y + 27z = 40,4 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{CuO}=n_{Cu}=x\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{3}y\left(mol\right)\\n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}z\left(mol\right)\end{matrix}\right.\)
⇒ 80x + 232.1/3x + 102.1/2z = 59,6 (2)
- Chất rắn A gồm: Cu, Fe và Al3O3.
⇒ 64x + 56y + 102.1/2z = 50 (3)
Từ (1), (2) và (3) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,3\left(mol\right)\\z=0,4\left(mol\right)\end{matrix}\right.\)
⇒ mCu = 0,2.64 = 12,8 (g)
mFe = 0,3.56 = 16,8 (g)
mAl = 0,4.27 = 10,8 (g)
b, Theo PT: \(n_{H_2}=n_{Cu}+\dfrac{4}{3}n_{Fe}=0,6\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,6.22,4=13,44\left(l\right)\)
\(BTKL:\)
\(m_A+m_{O_2}=m_B\)
\(\Rightarrow m_{O_2}=m_B-m_A=32-22.4=9.6\left(g\right)\)
\(n_{O_2}=\dfrac{9.6}{32}=0.3\left(mol\right)\)
\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)
Câu 20:
Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Cu}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 64y = 12,9 (1)
PT: \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
THeo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}+\dfrac{1}{2}n_{Cu}=\dfrac{1}{2}x+\dfrac{1}{2}y=\dfrac{2,24}{22,4}=0,1\left(mol\left(2\right)\right)\)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{12,9}.100\%\approx50,39\%\\\%m_{Cu}\approx49,61\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{0,953m}{22,4}=0,042545m\left(mol\right)\\ Đặt:n_{Mg}=x\left(mol\right);n_{Al}=y\left(mol\right);n_{Cu}=z\left(mol\right)\left(x,y,z>0\right)\\\Rightarrow \left\{{}\begin{matrix}24x+27y+64z=m\\40x+51y+80z=1,72m\\x+1,5y=0,042545m\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x\approx0,012845m\\y\approx0,0198m\\z\approx0,002455m\end{matrix}\right.\\ \Rightarrow\%m_{Cu}\approx\dfrac{0,002455.64m}{m}.100\%\approx15,712\%\\ \%m_{Al}\approx\dfrac{27.0,0198m}{m}.100\%\approx53,46\%\\ \%m_{Mg}\approx\dfrac{0,012845.24m}{m}.100\%\approx30,828\%\)
a)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{H_2O}=\dfrac{1,8}{18}=0,1\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
0,1<-0,05<-------0,1
2CO + O2 --to--> 2CO2
0,2<--0,1-------->0,2
=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\V_{CO}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)
b) \(m_{CO_2}=0,2.44=8,8\left(g\right)\)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{H_2O}=\dfrac{1,8}{18}=0,1mol\)
\(2CO+O_2\rightarrow2CO_2\)
a 0,5a a
\(2H_2+O_2\rightarrow2H_2O\)
0,1 0,05 \(\leftarrow\) 0,1
\(\Sigma n_{O_2}=0,5a+0,05=0,15\)
\(\Rightarrow a=n_{O_2\left(CO\right)}=0,2mol\)
\(V_{CO}=2\cdot0,2\cdot22,4=8,96l\)
\(V_{H_2}=0,1\cdot22,4=2,24l\)
\(m_{CO_2}=0,2\cdot44=8,8g\)
a/ \(2CO\left(0,2\right)+O_2\left(0,1\right)\rightarrow2CO_2\left(0,2\right)\)
\(2H_2\left(0,1\right)+O_2\left(0,05\right)\rightarrow2H_2O\left(0,1\right)\)
\(n_{H_2O}=\frac{1,8}{18}=0,1\)
\(n_{O_2}=\frac{3,36}{22,4}=0,15\)
Số mol O2 phản ứng ở phản ứng đầu là: \(0,15-0,05=0,1\)
\(\Rightarrow m_{CO_2}=0,2.44=8,8\)
b/ \(m_{CO}=0,2.28=5,6\)
\(m_{H_2}=0,1.2=0,2\)
c/ \(\%CO=\frac{0,2}{0,3}.100\%=66,67\%\)
\(\Rightarrow\%H_2=100\%-66,67\%=33,33\%\)
\(n_{H2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Pt : \(2Zn+O_2\underrightarrow{t^o}2ZnO|\)
2 1 2
a 0,5b 0,2
\(2Mg+O_2\underrightarrow{t^o}2MgO|\)
2 1 2
b 0,5b 0,1
a) Gọi a là số mol của Zn
b là số mol của Mg
\(m_{Zn}+m_{Mg}=15,4\left(g\right)\)
⇒ \(n_{Zn}.M_{Zn}+n_{Mg}.M_{Mg}=15,4g\)
⇒ 65a + 24b = 15,4g (1)
Theo phương trình : 0,5a + 0,5b = 0,15 (2)
65a + 24b = 15,4g
0,5a + 0,5b = 0,15
⇒ \(\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(m_{Zn}=0,2.65=13\left(g\right)\)
\(m_{Mg}=01.24=2,4\left(g\right)\)
b) Có : \(n_{ZnO}=\dfrac{0,2.2}{2}=0,2\left(mol\right)\)
⇒ \(m_{ZnO}=0,2.81=16,2\left(g\right)\)
\(n_{MgO}=\dfrac{0,1.2}{2}=0,1\left(mol\right)\)
⇒ \(m_{MgO}=0,1.40=4\left(g\right)\)
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