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\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\\ n_{O_2}=\dfrac{17}{32}=0,53125\left(mol\right)\\ 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ Vì:\dfrac{0,4}{4}< \dfrac{0,53125}{5}\Rightarrow O_2dư\\ n_{O_2\left(dư\right)}=\dfrac{5}{4}.0,4=0,5\left(mol\right)\\ \Rightarrow m_{O_2\left(dư\right)}=32.\left(0,53125-0,5\right)=1\left(g\right)\\ n_{P_2O_5}=\dfrac{2}{4}.0,4=0,2\left(mol\right)\\ \Rightarrow m_{P_2O_5}=142.0,2=28,4\left(g\right)\)
$a) 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
$n_P = \dfrac{6,2}{31} = 0,2(mol) ; n_{O_2} = \dfrac{7,84}{22,4} = 0,35(mol)$
$n_P : 4 = 0,05 < n_{O_2} :5 = 0,07$ nên $O_2$ dư
$n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)$
$\Rightarrow m_{O_2\ dư} = (0,35 - 0,25).32 = 3,2(gam)$
c) $n_{P_2O_5} = \dfrac{1}{2}n_P = 0,1(mol)$
$m_{P_2O_5} = 0,1.142 = 14,2(gam)$
\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\\a, 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ V\text{ì}:\dfrac{0,35}{5}>\dfrac{0,2}{4}\Rightarrow O_2d\text{ư}\\ n_{O_2\left(d\text{ư}\right)}=0,35-\dfrac{5}{4}.0,2=0,1\left(mol\right)\\b, m_{O_2\left(d\text{ư}\right)}=0,1.32=3,2\left(g\right)\\ c,n_{P_2O_5}=\dfrac{n_P}{2}=\dfrac{0,2}{2}=0,1\left(mol\right)\\ m_{r\text{ắn}}=m_{P_2O_5}=142.0,1=14,2\left(g\right)\)
\(n_P = \dfrac{6,2}{31} = 0,2(mol)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)
Do đó : O2 dư.
4P + 5O2 \(\xrightarrow{t^o} \) 2P2O5
0,2..............0,25..................0,1..................(mol)
\(n_{O_2\ dư} = 0,3 - 0,25 = 0,05(mol)\)
\(m_{P_2O_5} = 0,1.142 = 14,2(gam)\)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}< \dfrac{0,4}{5}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\Rightarrow n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,15.32=4,8\left(g\right)\)
c, Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
d, \(m_{P_2O_5}=14,2.80\%=11,36\left(g\right)\)
\(n_{KClO_3}=\dfrac{29.4}{122.5}=0.24\left(mol\right)\)
\(2KClO_3\underrightarrow{^{^{t^0}}}2KCl+3O_2\)
\(0.24.....................0.36\)
KClO3 : Kali clorat
KCl : Kali clorua
\(V_{O_2}=0.36\cdot22.4=8.064\left(l\right)\)
\(b.\)
\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)
\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)
Lập tỉ lệ :
\(\dfrac{0.2}{4}< \dfrac{0.36}{5}\) => O2 dư
\(n_{O_2\left(dư\right)}=0.36-0.2\cdot\dfrac{5}{4}=0.11\left(mol\right)\)
\(m_{O_2}=0.11\cdot32=3.52\left(g\right)\)
\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)
Chúc em học tốt nhé !
a, PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, Ta có: \(n_{P_2O_5}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
Theo PT: \(n_P=2n_{P_2O_5}=0,1\left(mol\right)\)
\(\Rightarrow m_P=0,1.31=3,1\left(g\right)\)
\(n_{O_2}=\dfrac{5}{2}n_{P_2O_5}=0,125\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,125.22,4=2,8\left(l\right)\)
c, Có: \(V_{O_2\left(dư\right)}=2,8.15\%=0,42\left(l\right)\)
\(\Rightarrow V_{O_2}=2,8+0,42=3,22\left(l\right)\)
Tóm tắt:
mP = 6.2 g
VO2 = 4,48g
__________________________________________________
a. PTHH
b. Chất nào dư? dư bao nhiêu mol?
c.mP2O5 = ?
a. 4 P + 5 O2 ----------- 2 P2O5
4mol 5 mol 2mol
0,2 mol
b. Số mol P là: n =\(\dfrac{m}{M}\)=\(\dfrac{6,2}{31}\)= 0,2 mol
Số mol O2 là: n =\(\dfrac{V}{22,4}\)=\(\dfrac{4,48}{22,4}\) = 0,2 mol
Lập tỉ lệ : \(\dfrac{0,2}{4}\) < \(\dfrac{0,2}{5}\) => O2 dư
Số mol dư : nO2 = nbd - nphân huỷ
= 0,2 - \(\dfrac{0,2.4}{5}\)= 0,04 mol
c. Số mol P2O5 : \(\dfrac{0,2.2}{4}\)=0,1
Khối lượng P2O5 : m = n.M= 0,1 . 142 = 14,2g