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a. Số mol oxit sắt từ : nFe3O4=2,32(56.3+16.4)nFe3O4=2,32(56.3+16.4) = 0,01 (mol).
Phương trình hóa học.
3Fe + 2O2 -> Fe3O4
3mol 2mol 1mol.
0,01 mol.
Khối lượng sắt cần dùng là : m = 56.3.0,011=1,6856.3.0,011=1,68 (g).
Khối lượng oxi cần dùng là : m = 32.2.0,011=0,6432.2.0,011=0,64 (g).
a)\(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Theo PTHH, ta có:\(n_{Fe}=3n_{Fe_3O_4}=3.0,01=0,03\left(mol\right)\Rightarrow m_{Fe}=0,03.56=1,68\left(g\right)\)
Theo PTHH ta có:\(n_{O_2}=2n_{Fe_3O_4}=2.0,01=0,02\left(mol\right)\Rightarrow m_{O_2}=0,02.32=0,64\left(g\right)\)
b)PTHH:\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
__________2____________________________1
________0,04___________________________0,02
\(m_{KMnO_4}=0,04.158=6,32\left(g\right)\)
Bài 1: lấy cùng một lượng KClO3 và KMnO4 để điều chế khí O2. Chất nào cho nhiều khí O2 hơn ?
2KClO3 | → | 2KCl | + | 3O2 |
2KMnO4⟶MnO2+O2+K2MnO4
==>KClO3 THU ĐC NHIỀU KHÍ HƠNa, \(3Fe+2O_2\underrightarrow{^{to}}Fe_3O_4\)
\(n_{Fe3O4}=\frac{4,64}{232}=0,02\left(mol\right)\)
\(\rightarrow n_{Fe}=3n_{Fe3O4}=0,06\left(mol\right)\)
\(n_{O2}=2n_{Fe3O4}=0,04\left(mol\right)\)
b,\(PTHH:2KMnO_4\underrightarrow{^{to}}KMnO_2+MnO_2+O_2\)
\(n_{KMnO4}=2n_{O2}=0,08\left(mol\right)\)
\(\rightarrow m_{KMnO4O}=0,08.158=12,64\left(g\right)\)
a,4P+5O2→t02P2O5
b,nP=mM=6,232=0,19375(mol)
Theo PTHH :
nO2=54nP=54.0,19375=0,24(mol)
⇒VO2=n.22,4=0,24.22,4=5,376(l)
c, Theo PTHH :
nP2O5=12nP=12.0,19375=0,097(mol)
⇒mP2O5=n.M=0,097.142=13,774(g)
d, 2KMnO4→K2MnO4+MnO2+O2
Theo PTHH :
nKMnO4=2nO2=2.0,24=0,48(mol)
⇒mKMnO4=n.M=0,48.158=75,84(g)
a,\(4P+5O_2\rightarrow^{t^0}2P_2O_5\)
\(b,n_P=\dfrac{m}{M}=\dfrac{6,2}{32}=0,19375\left(mol\right)\)
Theo PTHH :
\(n_{O_2}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,19375=0,24\left(mol\right)\)
\(\Rightarrow V_{O_2}=n.22,4=0,24.22,4=5,376\left(l\right)\)
c, Theo PTHH :
\(n_{P_2O_5}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,19375=0,097\left(mol\right)\)
\(\Rightarrow m_{P_2O_5}=n.M=0,097.142=13,774\left(g\right)\)
d, \(2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
Theo PTHH :
\(n_{KMnO_4}=2n_{O_2}=2.0,24=0,48\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=n.M=0,48.158=75,84\left(g\right)\)
1) nFe3O4= 46,4:232=0,2 mol
PTHH :3Fe+2O2\(\rightarrow\) Fe3O4
0,6 0,4 \(\leftarrow\)0,2 (mol)
PTHH: 2KMnO4\(\rightarrow\) K2MnO4+MnO2+O2
0,8 \(\leftarrow\) 0,4 (mol)
\(\Rightarrow\) m KMnO4= 0,8.158=126,4 g
1) 3Fe + 2O2 ---> Fe3O4 ---> nO2 = 2nFe3O4 = 2.46,4/232 = 0,4 mol.
2KMnO4 ---> K2MnO4 + MnO2 + O2 ---> nKMnO4 = 2nO2 = 0,8 mol
---> mKMnO4 = 158.0,8 = 126,4 g.
2) KClO3 ---> KCl + 3/2O2 ---> nKClO3 = 2/3nO2
---> nKClO3:nKMnO4 = 2/3:2 = 1:3 ---> mKClO3:mKMnO4 = 158/3.122,5 = 0,43
3) KNO3 ---> KNO2 + 1/2O2 ; Cu(NO3)2 ---> CuO + 2NO2 + 1/2O2
Như vậy nếu thu được cùng lượng oxi thì KClO3 sẽ có khối lượng nhỏ nhất.
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
\(a,PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
(mol) 3 2 1
(mol) 0,03 0,02 0,01
- Số mol \(Fe_3O_4:n_{Fe_3O_4}=\dfrac{m}{M}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
b. Thể tích khí Oxi cần dùng là:
\(V_{O_2}=n.22,4=0,02.22,4=0,0448\left(l\right)\)
c.
\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_2+MnO_2+O_2\uparrow\)
(mol) 2 1
(mol) 0,04 0,02
Số gam kalipenmaganat cần dùng là:
\(m_{KMnO_4}=n.M=0,04.158=6,32\left(g\right)\)