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a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2SO_4} = n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)$
$V = 0,3.22,4 = 6,72(lít)$
$C_{M_{H_2SO_4}} = \dfrac{0,3}{0,25} = 1,2M$
b)
$n_{CuO} = \dfrac{16}{80} = 0,2(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{CuO} < n_{H_2}$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,2(mol)$
$m_{Cu} = 0,2.64 = 12,8(gam)$
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PT:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 (mol)
a) V= n. 22,4 = 0,3 . 22,4 = 6,72(l)
\(C\%=\dfrac{m_{H_2SO_4}}{m_{dd}}.100\%=\dfrac{0,3.98}{200}.100\%=11,76\%\)
b) PT: \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3
=> mCu=n.M=0,3.64=19,2(g)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)
200ml = 0,2l
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,3 0,6 0,3 0,3
a) \(n_{ZnCl2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(C_{M_{ZnCl2}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
b) \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)
c) Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)
1 1 1 1
0,6 0,6
\(n_{NaOH}=\dfrac{0,6.1}{1}=0,6\left(mol\right)\)
\(m_{NaOH}=0,6.40=24\left(g\right)\)
\(m_{ddNaOH}=\dfrac{24.100}{20}=120\left(g\right)\)
Chúc bạn học tốt
\(n_{Fe}=\dfrac{11,2}{56}=0,2(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=0,2(mol)\\ a,V_{H_2}=0,2.22,4=4,48(l)\\ b,m_{dd_{H_2SO_4}}=\dfrac{0,2.98}{9,8\%}=200(g)\\ c,C\%_{FeSO_4}=\dfrac{0,2.152}{11,2+200-0,2.2}.100\%=14,42\%\)
nZn= 19,5/65=0,3(mol); nFe2O3=19,2/160=0,12(mol)
PTHH: Zn + 2 HCl -> ZnCl2 + H2
Fe2O3 + 3 H2 -to-> 2 Fe +3 H2O
nH2=nZnCl2= nZn=0,3(mol) => V(H2,đktc)=0,3.22,4= 6,72(l)
b) nHCl= 2.0,3=0,6(mol) => mHCl=0,6.36,5=21,9(g)
=>mddHCl=(21,9.100)/20=109,5(g)
=>m=109,5(g)
c) mH2=0,3.2=0,6(mol)
mddZnCl2=19,5+109,5 - 0,6= 128,4(g)
mZnCl2=0,3. 136= 40,8(g)
=>C%ddZnCl2= (40,8/128,4).100=31,776%
d) Ta có: 0,3/3 < 0,12/1
=> H2 hết, Fe2O3 dư, tính theo nH2
=> nFe= 2/3. nH2= 2/3. 0,3= 0,2(mol)
=>mFe=0,2.56=11,2(g)
a, nZn = 19,5/65=0,3 (mol)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,15 0,3 0,3
=> \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b,mHCl=0,15.36,5=5,475 (g)
=> m=mddHCl=5,475:20%=27,375 (g)
c,mdd sau pứ =19,5+27,375=46,875 (g)
\(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{46,875}.100\%=87,04\%\)
d,\(n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,3 0,2
Tỉ lệ: 0,12/1>0,3/3 ⇒ Fe2O3 dư,H2 pứ hết
=> mFe=0,2.56=11,2 (g)
Bài 4 :
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)0/0
d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)
\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)
\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)0/0
Chúc bạn học tốt
Bài 3 :
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,5 0,5 0,5 0,5
b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)0/0
d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)
\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)
\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)0/0
Chúc bạn học tốt
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
a) \(n_{H2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,1.22,4=2,24\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
100ml = 0,1l
\(C_{M_{ddHCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\)
c) \(n_{FeCl2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(C_{M_{FeCl2}}=\dfrac{0,1}{2}=0,05\left(M\right)\)
Chúc bạn học tốt
Mình xin lỗi bạn nhé , bạn sửa lại giúp mình chỗ :
\(C_{M_{FeCl2}}=\dfrac{0,1}{0,1}=1\left(M\right)\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
Theo đề bài ta có : ⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol){VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol)
nFe = 1,68/56 = 0,03 mol
a) Ta có PTHH :
2NaOH + H2SO4 -> Na2SO4 + 2H2O
0,1mol......0,05mol
=> CMH2SO4 = 0,05/0,05=1(M)