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a) CuO+2HCl--->CuCl2+H2O
n CuO=4/80=0,05(mol)
n HCl=2,92/36,5=0,08(mol)
Lập tỉ lệ
0,05/1>0,08/2
-->CuO dư..tính theo n HCl
Theo pthh
n CuCl2=1/2n HCl=0,04(mol)
m CuCl2=0,04.135=5,4(g_
n H2O=1/2n HCl=0,04(mol)
m H2O=0,04.18=0,72(g)
CuO+h2-->Cu+H2O
0,05--0,05 mol
=>VH2=0,05.22,4=1,12 l
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
b, Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,25}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{H_2}=0,2\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,25-0,2=0,05\left(mol\right)\)
\(\Rightarrow m_{CuO\left(dư\right)}=0,05.80=4\left(g\right)\)
\(a.n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Vì:\dfrac{0,15}{1}< \dfrac{0,5}{1}\\ \rightarrow CuOdư\\ n_{CuO\left(p.ứ\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\\ \rightarrow n_{CuO\left(dư\right)}=0,5-0,15=0,35\left(mol\right)\\ m_{CuO\left(DƯ\right)}=0,35.80=28\left(g\right)\\ b.m_{Cu}=0,35.64=22,4\left(g\right)\\ c.m_{hh_{rắn}}=m_{Cu}+m_{CuO\left(dư\right)}=22,4+28=50,4\left(g\right)\)
Zn+2HCl->ZnCl2+H2
0,05--------------------0,05
CuO+H2-to>Cu+H2O
0,05----0,05
n Zn=\(\dfrac{3,25}{65}=0,05mol\)
=>n CuO=\(\dfrac{6}{80}=0,075mol\)
=>CuO dư
=>m Cu=0,05.64=3,2g
=>m CuO dư=0,025.80=2g
\(a,PTHH:\\ Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\left(1\right)\\ CuO+H_2\underrightarrow{t^o}Cu+H_2O\left(2\right)\\ b,n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\\ Theo.pt\left(1\right):n_{H_2}=n_{Zn}=0,05\left(mol\right)\\ n_{CuO}=\dfrac{6}{80}=0,075\left(mol\right)\\ LTL.pt\left(2\right):0,075>0,05\Rightarrow CuO,dư\\ Theo.pt\left(2\right):n_{Cu}=n_{CuO\left(pư\right)}=n_{H_2}=0,05\left(mol\right)\\ m_{Cu}=0,05.64=3,2\left(g\right)\\ c,m_{CuO\left(dư\right)}=\left(0,075-0,05\right).80=2\left(g\right)\)
a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1-------------->0,1------>0,1
\(\Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b) \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c) \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
0,1<---0,1
\(\Rightarrow m_{CuO}=0,1.80=8\left(g\right)\)
a: Zn+2HCl->ZnCl2+H2
0,2 0,4 0,2 0,2
mZnCl2=0,2*136=27,2(g)
b: V=0,2*22,4=4,48(lít)
a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{CuO}=\dfrac{3,2}{80}=0,04\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{H_2O}=n_{CuO}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,04.64=2,56\left(g\right)\\m_{H_2O}=0,04.18=0,72\left(g\right)\end{matrix}\right.\)
b, PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Ta có: \(n_{Fe_3O_4}=\dfrac{10,8}{232}=\dfrac{27}{580}\left(mol\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{\dfrac{27}{580}}{1}< \dfrac{0,2}{4}\), ta được H2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{H_2\left(pư\right)}=n_{H_2O}=4n_{Fe_3O_4}=\dfrac{27}{145}\left(mol\right)\\n_{Fe}=3n_{Fe_3O_4}=\dfrac{81}{580}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2\left(dư\right)}=0,2-\dfrac{27}{145}=\dfrac{2}{145}\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=\dfrac{2}{145}.2\approx0,0276\left(g\right)\)
\(m_{H_2O}=\dfrac{27}{145}.18\approx3,35\left(g\right)\)
\(m_{Fe}=\dfrac{81}{580}.56\approx7,82\left(g\right)\)
Bạn tham khảo nhé!
Sửa đề: 1,2 (l) → 1,12 (l)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{CuO}=n_{H_2}=0,05\left(mol\right)\)
a, \(m_{CuO}=0,05.80=4\left(g\right)\)
b, \(m_{Cu}=0,05.64=3,2\left(g\right)\)
c, PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,025\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,025.22,4=0,56\left(l\right)\)
a) \(CuO+2HCl-->.CuCl2+H2O\)
\(n_{CuO}=\frac{4}{80}=0,05\left(mol\right)\)
\(n_{HCl}=\frac{2,92}{36,5}=0,08\left(mol\right)\)
\(\frac{0,05}{1}>\frac{0,08}{2}\Rightarrow HCl\) hết , CuO dư
\(n_{CuO}=\frac{1}{2}n_{HCl}=0,04\left(mol\right)\)
\(n_{CuO}dư=0,05-0,04=0,01\left(mol\right)\)
\(m_{CuO}dư=0,01.80=0,8\left(g\right)\)
b) \(CuO+H2-->Cu+H2O\)
\(n_{H2}=n_{CuO}=0,05\left(mol\right)\)
\(V_{H2}=0,05.22,4=1,12\left(l\right)\)
\(n_{Cu}=n_{CuO}=0,05\left(mol\right)\)
m\(_{Cu}=0,0.64=3,2\left(g\right)\)