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\(a.n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Vì:\dfrac{0,15}{1}< \dfrac{0,5}{1}\\ \rightarrow CuOdư\\ n_{CuO\left(p.ứ\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\\ \rightarrow n_{CuO\left(dư\right)}=0,5-0,15=0,35\left(mol\right)\\ m_{CuO\left(DƯ\right)}=0,35.80=28\left(g\right)\\ b.m_{Cu}=0,35.64=22,4\left(g\right)\\ c.m_{hh_{rắn}}=m_{Cu}+m_{CuO\left(dư\right)}=22,4+28=50,4\left(g\right)\)
a) PTHH : \(2Al+6HCl-->2AlCl_3+3H_2\) (1)
\(Fe+2HCl-->FeCl_2+H_2\) (2)
\(H_2+CuO-t^o->Cu+H_2O\) (3)
b) Ta có : \(m_{CR\left(giảm\right)}=m_{O\left(lay.di\right)}\)
=> \(m_{O\left(lay.di\right)}=32-26,88=5,12\left(g\right)\)
=> \(n_{O\left(lay.di\right)}=\frac{5,12}{16}=0,32\left(mol\right)\)
Theo pthh (3) : \(n_{H_2\left(pứ\right)}=n_{O\left(lay.di\right)}=0,32\left(mol\right)\)
=> \(tổng.n_{H_2}=\frac{0,32}{80}\cdot100=0,4\left(mol\right)\)
Đặt \(\hept{\begin{cases}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{cases}}\) => \(27a+56b=11\left(I\right)\)
Theo pthh (1) và (2) : \(n_{H_2\left(1\right)}=\frac{3}{2}n_{Al}=\frac{3}{2}a\left(mol\right)\)
\(n_{H_2\left(2\right)}=n_{Fe}=b\left(mol\right)\)
=> \(\frac{3}{2}a+b=0,4\left(II\right)\)
Từ (I) và (II) => \(\hept{\begin{cases}a=0,2\\b=0,1\end{cases}}\)
=> \(\hept{\begin{cases}m_{Al}=27\cdot0,2=5,4\left(g\right)\\m_{Fe}=56\cdot0,1=5,6\left(g\right)\end{cases}}\)
\(n_{Zn}=\dfrac{19.5}{65}=0.3\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{98}{98}=1\left(mol\right)\)
\(n_{CuO}=\dfrac{36}{80}=0.45\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(0.3.....................................0.3\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(0.3.......0.3.....0.3....0.3\)
\(m_{Cr}=m_{CuO\left(dư\right)}+m_{Cu}=\left(0.45-0.3\right)\cdot80+0.3\cdot64=31.2\left(g\right)\)
\(m_{H_2O}=0.3\cdot18=5.4\left(g\right)\)
Chúc em học tốt !!
Zn+H2SO4→ZnSO4+H2 bạn biến đổi nó ra phương trình này kiểu gì vậy?
\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{4,48}{22,4}=0,2mol\)
\(n_{Fe_2O_3}=\dfrac{m_{Fe_2O_3}}{M_{Fe_2O_3}}=\dfrac{23,2}{160}=0,145mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,145 > 0,2 ( mol )
1/15 0,2 2/15 ( mol 0
Chất còn dư là \(Fe_2O_3\)
\(m_{Fe_2O_3\left(du\right)}=n_{Fe_2O_3\left(du\right)}.M_{Fe_2O_3}=\left(0,145-\dfrac{1}{15}\right).160=12,53g\)
\(m_{Fe}=n_{Fe}.M_{Fe}=\dfrac{2}{15}.56=7,4666g\)
\(n_{Fe_3O_4}=\dfrac{4,64}{232}=0,02mol\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\)
\(Fe_3O_4+4H_2\rightarrow3Fe+4H_2O\)
0,02 0,4 0 0
0,02 0,08 0,06 0,08
0 0,32 0,06 0,08
b)\(m_{Fe}=0,06\cdot56=3,36g\)
\(m_{H_2O}=0,08\cdot18=1,44g\)
c)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,06 0,5 0 0
\(\Rightarrow\)Tính theo \(Fe\)
\(\Rightarrow V_{H_2}=0,06\cdot22,4=1,344l\)
a)
\(Zn + 2HCl \to ZnCl_2 + H_2\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2\)
Theo PTHH : \(n_{Zn} = n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\)
\(\Rightarrow n_{Fe_2O_3} = \dfrac{35,5-0,3.65}{160} = 0,1\\ \Rightarrow n_{HCl} = 2n_{Zn} + 6n_{Fe_2O_3} = 0,3.2 + 0,1.6 = 1,2(mol)\\ \Rightarrow m_{HCl} = 1,2.36,5 = 43,8(gam)\)
b)
\(CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\)
Gọi \(n_{CuO} = a;n_{Fe_2O_3} = b\)
\(\left\{{}\begin{matrix}80a+160b=19,6\\a+3b=0,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,135\\b=0,055\end{matrix}\right.\)
Vậy :
\(\left\{{}\begin{matrix}n_{Cu}=0,135\\n_{Fe}=0,055.2=0,11\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,135.64=8,64\left(gam\right)\\m_{Fe}=0,11.56=6,16\left(gam\right)\end{matrix}\right.\)
a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ta có: \(n_{CuO}=\dfrac{3,2}{80}=0,04\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{H_2O}=n_{CuO}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,04.64=2,56\left(g\right)\\m_{H_2O}=0,04.18=0,72\left(g\right)\end{matrix}\right.\)
b, PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Ta có: \(n_{Fe_3O_4}=\dfrac{10,8}{232}=\dfrac{27}{580}\left(mol\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{\dfrac{27}{580}}{1}< \dfrac{0,2}{4}\), ta được H2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{H_2\left(pư\right)}=n_{H_2O}=4n_{Fe_3O_4}=\dfrac{27}{145}\left(mol\right)\\n_{Fe}=3n_{Fe_3O_4}=\dfrac{81}{580}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2\left(dư\right)}=0,2-\dfrac{27}{145}=\dfrac{2}{145}\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=\dfrac{2}{145}.2\approx0,0276\left(g\right)\)
\(m_{H_2O}=\dfrac{27}{145}.18\approx3,35\left(g\right)\)
\(m_{Fe}=\dfrac{81}{580}.56\approx7,82\left(g\right)\)
Bạn tham khảo nhé!
cảm ơn nhé !