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\(n_{H_2}=0,045mol\\ \text{Bảo toàn nguyên tố H:}\\ 2.n_{H_2}=n_{HCl}=0,09mol\\ \text{BTKL}\\ m_{hh}+m_{HCl}=m_{Khan}+m_{H_2}\\ m_{hh}+0,09.36,5=4,575+0,045.2\\ m_{hh}=1,38g\)
Ta có: \(n_{H_2}=\dfrac{1,008}{22,4}=0,045\left(mol\right)\) \(\Rightarrow m_{H_2}=0,045\cdot2=0,09\left(g\right)\)
Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,09\left(mol\right)\) \(\Rightarrow m_{HCl}=0,09\cdot36,5=3,285\left(g\right)\)
Bảo toàn khối lượng: \(m_{KL}=m_{muối}+m_{H_2}-m_{HCl}=1,38\left(g\right)\)
\(a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ n_{Mg}=\dfrac{4,8}{24}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(V_{H_2}=\left(0,1+0,2\right).22,4=6,72l\\ b)V_{ddHCl}=\dfrac{0,2+0,4}{2}=0,3l\\ c)m_{muối}=0,1.127+95.0,2=31,7g\)
a) Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\left(\text{Đ}K:a,b>0\right)\)
PTHH: Zn + H2SO4 ---> ZnSO4 + H2
a------>a---------->a----------->a
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
b----->1,5b--------->0,5b------->1,5a
=> \(\left\{{}\begin{matrix}65a+27b=20,3\\161b+0,5a.342=65,9\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,25\\b=0,15\end{matrix}\right.\)
=> \(V=V_{H_2}=\left(0,25+0,15.1,5\right).22,4=10,64\left(l\right)\)
b) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,25.65}{20,3}.100\%=80,05\%\\\%m_{Al}=100\%-80,05\%=19,95\%\end{matrix}\right.\)
c) \(m_{\text{dd}H_2SO_4}=\dfrac{\left(0,25+1,5.0,15\right).98}{10\%}=465,5\left(g\right)\)
\(Mg+2HCl \to MgCl_2+H_2\\ n_{H_2}=0,15(mol)\\ \to n_{Mg}=n_{H_2}=0,15(mol)\\ \%m_{Mg}=\frac{0,15.24}{10}.100\%=36\%\\ \%m_{Cu}=100\%-36\%=64\%\)
MCO3 + 2HCl\(\rightarrow\)MCl2 + CO2 + H2O (1)
M'CO3 + 2HCl\(\rightarrow\)M'Cl2 + CO2 + H2O (2)
Đặt nMCO3=a
nM'CO3=b
Ta có:
\(\left\{{}\begin{matrix}\left(M_M+60\right)a+\left(M_{M'}+60\right)b=4\\\left(M_M+71\right)a+\left(M_M+71\right)b=5,1\end{matrix}\right.\)
\(\Rightarrow\)a+b=0,1
VCO2=0,1.22,4=2,24(lít)