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Ta có: \(\text{nHNO3=0,2.1=0,2 mol}\)
\(\text{nHCl=0,3.0,5=0,15 mol}\)
\(\text{nAgNO3=0,25.1=0,25 mol}\)
Cho X tác dụng với AgNO3
HCl + AgNO3\(\rightarrow\) AgCl kt + HNO3
Vì nAgNO3 > nHCl nên AgNO3 dư
\(\rightarrow\) nAgCl=nHCl=0,15 mol \(\rightarrow\)\(\text{m=0,15.(108+35,5)=21,525 gam}\)
Sau phản ứng dung dịch chứa HNO3 và AgNO3 dư
nHNO3=0,2+nHNO3 mới tạo ra\(\text{=0,2+0,15=0,35 mol}\)
nAgNO3 dư=0,25-0,15=0,1 mol
V dung dịch sau phản ứng\(\text{=0,2+0,3+0,25=0,75 lít}\)
CM HNO3=\(\frac{0,35}{0,75}\)=0,467M;
CM AgNO3 dư=\(\frac{0,1}{0,75}\)=0,1333M
nNaOH=nHNO3 + nAgNO3\(\text{=0,35+0,1=0,45 mol}\)
\(\rightarrow\) V NaOH=\(\frac{0,45}{0,5}\)=0,9 lít
a,
\(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\left(1\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\left(2\right)\)
b,
Ta có :
\(n_{NaCl}=\frac{20,475}{58,5}=0,35\left(mol\right)\)
\(n_{Na2CO3}=\frac{10,6}{106}=0,1\left(mol\right)\)
\(\Rightarrow n_{NaCl\left(1\right)}=0,1.2=0,2\left(mol\right)\)
\(n_{NaCl}=0,35-0,2=0,15\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,15\left(mol\right)\)
\(\Rightarrow x=CM_{NaOH}=\frac{0,15}{0,3}=0,5M\)
a , \(nFe=\dfrac{11,2}{56}=0,2\left(mol\right)\)
, pthh:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
1mol 2mol 1mol 1mol
0,2 0,4 0,2 0,2
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2\downarrow+2NaCl\)
1mol 2mol 1mol 2mol
0,2 0,4 0,2 0,4
b, \(mFe\left(OH\right)_2=0,2.90=18\left(gam\right)\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2mol\\ a.MgCO_3+H_2SO_4->MgSO_4+H_2O+CO_2\\ 2NaOH+H_2SO_{\text{4 }}->Na_2SO_4+2H_2O\\ b.n_{H_2SO_4dư}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.80.0,1:40=0,1mol\\ n_{H_2SO_4\left(MgCO_3\right)}=0,2mol\\ c.C\%=\dfrac{98.0,3}{200}.100\%=14,7\%\\ V=0,2.22,4=4,48L\\ d.m_{ddsau}=200+16,8-44.0,2+80=288g\\ C\%_{Na_2SO_4}=\dfrac{40.0,1}{288}.100\%=1,39\%\\ C\%_{MgSO_4}=\dfrac{120.0,2}{288}.100\%=8,33\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
\(n_{NaOH}=\dfrac{80}{40}=2\left(mol\right)\)
PTHH :
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\)
0,2 0,2 0,2
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
2 1 1
Vậy có 0,2 mol H2SO4 phản ứng với MgCO3
có 1 mol H2SO4 phản ứng với NaOH
\(m_{H_2SO_4}=1,2.98=117,6\left(g\right)\)
\(c,C\%_{H_2SO_4}=\dfrac{117,6}{200}.100\%=58,8\%\)
\(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(d,m_{Na_2SO_4}=1.142=142\left(g\right)\)
\(m_{ddNaOH}=\dfrac{80.100}{10}=800\left(g\right)\)
\(m_{ddH_2SO_4dư}=1.98:58,8\%\approx166,67\left(g\right)\)
\(m_{ddNa_2SO_4}=800+166,67=966,67\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{142}{966,67}.100\%\approx14,69\%\)
1.
Al2O3 + 2NaOH -> 2NaAlO2 + H2O (1)
nNaAlO2=0,225(mol)
Từ 1:
nNaOH=nNaAlO2=0,225(mol)
nal2O3=\(\dfrac{1}{2}\)nNaAlO2=0,1125(mol)
V dd NaOH=0,225:5=0,045(lít)
mAl2O3=0,1125.102=11,475(g)
mquặng=11,475.110%=12,6225(g)
Gọi $n_{Na} = a(mol)$
2Na + 2H2O → 2NaOH + H2
a...........................a..........0,5a.....(mol)
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
..a...........a............................................1,5a....(mol)
Suy ra : $0,5a + 1,5a = \dfrac{3,36}{22,4} = 0,15 \Rightarrow a = 0,075$
Vậy :
$m = 0,075.23 + 0,075.27 + 1,35 = 5,1(gam)$
Gọi nNa=a(mol)���=�(���)
2Na + 2H2O → 2NaOH + H2
a...........................a..........0,5a.....(mol)
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
..a...........a............................................1,5a....(mol)
Suy ra : 0,5a+1,5a=3,3622,4=0,15⇒a=0,0750,5�+1,5�=3,3622,4=0,15⇒�=0,075
Vậy :
m=0,075.23+0,075.27+1,35=5,1(gam)
Ta có:
\(V_{Dd_{NaOH}}=\frac{200}{1000}=0,2\left(l\right)\)
\(V_{dd_{HCl}}=\frac{300}{1000}=0,3\left(l\right)\)
\(V_{dd_{Ba\left(OH\right)2}}=\frac{25}{1000}=0,025\left(l\right)\)
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\)
\(n_{Ba\left(OH\right)2}=0,025.0,5=0,0125\left(mol\right)\)
\(n_{HCl}=0,3.1=0,3\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
\(n_{HCl_{pư}}=0,2\left(mol\right)\)
Vì n NaOH < n HCl
\(\Rightarrow n_{HCl_{dư}}=n_{HCl_{bđ}}-n_{HCl_{pư}}=0,3-0,2=0,1\left(mol\right)\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)