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\(a) Mg + H_2SO_4 \to MgSO_4 + H_2\\ n_{H_2} = n_{H_2SO_4} = \dfrac{4,9}{98} =0,05(mol)\\ V_{H_2} = 0,05.22,4 = 1,12(lít)\\ b) Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = \dfrac{1}{2} n_{HCl} = \dfrac{1}{2} . \dfrac{4,9}{36,5} = \dfrac{49}{730} (mol)\\ V_{H_2} = \dfrac{49}{730} .22,4 = 1,504(lít) > 1,12\\ \text{Suy ra, thể tích Hidro thay đổi.}\)
a) Zn + 2HCl →ZnCl2 + H2
b) nZn = 6,5/65 = 0,1 mol . Theo tỉ lệ pư => nH2 = nZn = nZnCl2 =0,1 mol <=> VH2(đktc) = 0,1.22,4 = 2,24 lít.
c) mZnCl2 = 0,1 . 136 = 13,6 gam
d) nHCl =2nZn = 0,2 mol => mHCl = 0,2.36,5= 7,3 gam
Cách 2: áp dụng định luật BTKL => mHCl = mZnCl2 + mH2 - mZn
<=> mHCl = 13,6 + 0,1.2 - 6,5 = 7,3 gam
a) \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH : Zn + 2HCl -> ZnCl2 + H2
0,25 0,5 0,5 0,5
Xét tỉ lệ : \(\dfrac{0,3}{1}>\dfrac{0,5}{2}\) => Zn dư , HCl đủ
b) \(m_{Zn\left(dư\right)}=\left(0,3-0,25\right).65=3,25\left(g\right)\)
c) \(m_{ZnCl_2}=0,25.136=34\left(g\right)\)
\(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ a,Zn+2HCl\rightarrow ZnCl_2+H_2\\b, Vì:\dfrac{0,5}{2}< \dfrac{0,3}{1}\Rightarrow Zndư\\ n_{Zn\left(dư\right)}=0,3-\dfrac{0,5}{2}=0,05\left(mol\right)\\ \Rightarrow m_{Zn\left(dư\right)}=0,05.65=3,25\left(g\right)\\ c,n_{ZnCl_2}=n_{H_2}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,25.136=34\left(g\right)\\ V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
\(0,3:0,6:0,3:0,3\left(mol\right)\)
\(V_{H_2}=n.22,4=0,3.22,4=6.72\left(l\right)\)
\(m_{ZnCl_2}=n.M=0,3.\left(65+71\right)=0,3.136=40,8\left(g\right)\)
a.b.c.\(n_{Zn}=\dfrac{m}{M}=\dfrac{13}{65}=0,2mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 0,2 ( mol )
\(m_{ZnCl_2}=n.M=0,2.136=27,2g\)
\(V_{H_2}=n.22,4=0,2.22,4=4,48l\)
d.\(n_{CuO}=\dfrac{m}{M}=\dfrac{32}{80}=0,4mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,4 > 0,2 ( mol )
0,2 0,2 0,2 ( mol )
\(m_{chất.rắn}=m_{CuO\left(dư\right)}+m_{Cu}=0,2.80+0,2.64=16+12,8=28,8g\)
\(\%m_{CuO}=\dfrac{16}{28,8}.100=55,55\%\)
\(\%m_{Cu}=100\%-55,55\%=44,45\%\)
Theo gt ta có: $n_{Zn}=0,1(mol)$
a, $Zn+2HCl\rightarrow ZnCl_2+H_2$
b, Ta có: $n_{H_2}=0,1(mol)\Rightarrow V_{H_2}=2.24(l)$
c, Ta có: $n_{HCl}=2.n_{Zn}=0,2(mol)\Rightarrow m_{HCl}=7,3(g)$
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{39}{65}=0,6\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Zn}=1,2\left(mol\right)\Rightarrow m_{HCl}=1,2.36,5=43,8\left(g\right)\)
c, \(n_{H_2}=n_{Zn}=0,6\left(mol\right)\Rightarrow V_{H_2}=0,6.24,79=14,874\left(l\right)\)
d, - Quỳ tím hóa đỏ do HCl dư.
\(n_{HCl}=\dfrac{36.5}{36.5}=1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(........1..............0.5\)
\(n_{H_2SO_4}=\dfrac{36.5}{98}=\dfrac{73}{196}\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(.......\dfrac{73}{196}..............\dfrac{73}{196}\)
\(\text{Tỉ lệ thể tích tương ứng với tỉ lệ số mol nên : }\)
\(n_{H_2\left(HCl\right)}>n_{H_2\left(H_2SO_4\right)}\)