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Dung dịch A chứa CO32- (x mol) và HCO3- (y mol)
CO32- + H+ —> HCO3-
x…………x………….x
HCO3- + H+ —> CO2 + H2O
x+y…….0,15-x
Dung dịch B tạo kết tủa với Ba(OH)2 nên HCO3- dư, vậy nCO2 = 0,15 – x = 0,045 —> x = 0,105
HCO3- + OH- + Ba2+ —> BaCO3 + H2O
—> nBaCO3 = (x + y) – (0,15 – x) = 0,15 —> y = 0,09
—> a = 20,13 gam
a,nA=\(\dfrac{18,25}{36,5}\)=0,5(mol)
nB=\(\dfrac{10,95}{36,5}\)=0,3(mol)
→nC=0,3+0,5=0,8(mol)
→CM(C)=\(\dfrac{0,8}{2}\)=0,4M
b,CM(A)=\(\dfrac{0,5}{V1}\)
CM(B)=\(\dfrac{0,3}{V2}\)
→\(\dfrac{0,5}{V1}\)=\(\dfrac{0,3}{V2}\)=0,8
=>V1=0,625 l
=>V2=0,375 l
=>CmV1=\(\dfrac{0,5}{0,625}\)=0,8M
=>CmV2=\(\dfrac{0,3}{0,375}\)=0,8M
\(a,n_A=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ n_B=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
\(\rightarrow n_C=0,3+0,5=0,8\left(mol\right)\\ \rightarrow C_{M\left(C\right)}=\dfrac{0,8}{2}=0,4M\)
\(b,C_{M\left(A\right)}=\dfrac{0,5}{V_1}\\ C_{M\left(B\right)}=\dfrac{0,3}{V_2}\\ \rightarrow\dfrac{0,5}{V_1}:\dfrac{0,3}{V_2}=0,8\\ \rightarrow\dfrac{0,5}{V_1}=\dfrac{0,24}{V_2}=\dfrac{0,5+0,24}{V_1+V_2}=\dfrac{0,74}{2}=0,37\\ \rightarrow\left\{{}\begin{matrix}V_1=\dfrac{0,5}{0,34}=1,4\left(l\right)\\V_2=\dfrac{0,24}{0,34}=0.6\left(l\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}C_{M\left(A\right)}=\dfrac{0,5}{1,4}=0,36M\\C_{M\left(B\right)}=\dfrac{0,5}{0,6}=0,83M\end{matrix}\right.\)
\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,05 0,1 0,05
b) \(n_{H2}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddHCl}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
Chúc bạn học tốt
a, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(M+H_2SO_4\rightarrow MSO_4+H_2\)
Theo PT: \(n_M=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow M_M=\dfrac{11,2}{0,2}=56\left(g/mol\right)\)
→ M là Fe.
b, Theo PT: \(n_{FeSO_4}=n_{H_2SO_4\left(pư\right)}=n_{H_2}=0,2\left(mol\right)\)
⇒ nH2SO4 dư = 0,5.1 - 0,2 = 0,3 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\end{matrix}\right.\)
c, Ta có: \(n_{FeSO_4.7H_2O}=n_{FeSO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{FeSO_4.7H_2O}=0,2.278=55,6\left(g\right)\)
TN1:
\(C_{M\left(E\right)}=\dfrac{2x+y}{3}M\)
10ml dd E chứa \(0,01.\dfrac{2x+y}{3}\) mol H2SO4
\(n_{H_2}=\dfrac{0,05824}{22,4}=0,0026\left(mol\right)\)
PTHH: Zn + H2SO4 --> ZnSO4 + H2
=> 2x + y = 0,78 (1)
TN2:
\(C_{M\left(F\right)}=\dfrac{x+3y}{4}M\)
50ml dd F chứa \(0,05\dfrac{x+3y}{4}\) mol H2SO4
\(n_{NaOH}=\dfrac{16,8.5\%}{40}=0,021\left(mol\right)\)
PTHH: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
=> x + 3y = 0,84 (2)
(1)(2) => x = 0,3; y = 0,18
$a\big)$
$M_A=9,4.2=18,8(g/mol)$
$\to \dfrac{n_{CO_2}}{n_{H_2}}=\dfrac{18,8-2}{44-18,8}=\dfrac{2}{3}$
Mà $n_{CO_2}+n_{H_2}=\dfrac{11,2}{22,4}=0,5(mol)$
\(\begin{array} {l} \to n_{CO_2}=0,2(mol);n_{H_2}=0,3(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ FeCO_3+2HCl\to FeCl_2+CO_2+H_2O\\ \text{Theo PT: }n_{Fe}=n_{H_2}=0,3(mol);n_{FeCO_3}=n_{CO_2}=0,2(mol)\\ \to m=0,3.56+0,2.116=40(g) \end{array}\)
$b\big)$
Đổi $400ml=0,4l$
\(\begin{array} {l} \text{Theo PT: }n_{FeCl_2}=n_{H_2}+n_{CO_2}=0,5(mol)\\ \to C_{M\,FeCl_2}=\dfrac{0,5}{0,4}=1,25M \end{array}\)
$c\big)$
\(\begin{array}{l} m_{dd\,FeCl_2}=\dfrac{400}{1,2}\approx 333,33(g)\\ \to C\%_{FeCl_2}=\dfrac{0,5.127}{333,33}.100\%=19,05\%\end{array}\)
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