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Bài 2 :
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH :
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1 0,3
\(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
\(b,V_{ddH_2SO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\)
\(c,C_{M\left(Fe_2\left(SO_4\right)_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\)
Bài 3 :
\(n_{Mg}=\dfrac{4.8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2O\)
0,2 0,2 0,2 0,2
\(m_{MgSO_4}=0,2.120=24\left(g\right)\)
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(c,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(d,C_{M\left(MgSO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 4 :
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
PTHH :
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
0,3 0,45 0,15 0,45
\(V_{H_2}=0,45.24,79=11,1555\left(l\right)\)
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\)
\(C\%_{H_2SO_4}=\dfrac{44,1}{300}.100\%=14,7\%\)
\(m_{Al_2\left(SO_4\right)_3}=0,15.342=51,3\left(g\right)\)
\(m_{dd}=8,1+300-\left(0,45.2\right)=307,2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{51,3}{307,2}.100\%\approx16,7\%\)
Bài 5 :
\(n_{H_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,4}{0,2}=2\left(M\right)\)
\(C_{M\left(FeCl_2\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 → Fe2(SO4)3 + 3H2O
Mol: 0,1 0,1
\(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,3 0,3 0,3
a) \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(m_{H2SO4}=0,3.98=29,4\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{29,4.100}{9,8}=300\left(g\right)\)
Chúc bạn học tốt
\(a,n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\\ PTHH:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(b,\) Theo PT: \(n_{H_2}=n_{Mg}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2\left(đktc\right)}=0,3\cdot22,4=6,72\left(l\right)\)
\(c,n_{H_2SO_4}=n_{Mg}=0,3\left(mol\right)\\ \Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5M\)
Fe+2CH3COOH->(CH3COO)2Fe+H2
33\112-33\56---------------33\112
n Fe=\(\dfrac{33}{112}\) mol
=>m (CH3COO)2Fe=\(\dfrac{33}{112}\).174=51,267g
=>VCH3COOH=\(\dfrac{\dfrac{33}{56}}{3}=0,196l\)
\(n_{Fe}=\dfrac{16,5}{56}=0,29mol\)
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
0,29 0,58 0,29 0,29 ( mol )
\(V_{H_2}=0,29.22,4=6,496l\)
\(m_{\left(CH_3COO\right)_2Fe}=0,29.174=50,46g\)
\(C_{M_{CH_3COOH}}=\dfrac{0,29}{0,3}=0,96M\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ n_{MgSO_4}=n_{H_2}=n_{H_2SO_4}=n_{Mg}=0,2\left(mol\right)\\ a,m_{MgSO_4}=120.0,2=24\left(g\right)\\ b,V_{H_2\left(đkc\right)}=24,79.0,2=4,958\left(l\right)\\ c,Oxide:A_2O_x\left(x:hoá.trị.A\right)\\ A_2O_x+xH_2SO_4\rightarrow A_2\left(SO_4\right)_x+xH_2O\\ n_{Oxide}=\dfrac{\dfrac{3}{4}.0,2.1}{x}=\dfrac{0,15}{x}\left(mol\right)\\ M_{A_2O_x}=\dfrac{8}{\dfrac{0,15}{x}}=\dfrac{160}{3}x\)
Xét x=1;x=2;x=3;x=8/3 thấy x=3 (TM) khi đó KLR oxide là 160g/mol
\(M_{M_2O_3}=2M_M+3.16=160\left(\dfrac{g}{mol}\right)\\ \Rightarrow M_M=\dfrac{160-48}{2}=56\left(\dfrac{g}{mol}\right)\)
Nên: M là sắt (Fe=56)
Oxide CTHH: Fe2O3
\(a,PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\ b,n_{FeCl_2}=n_{H_2}=n_{Fe}=0,4\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ c,m_{FeCl_2}=127.0,4=50,8\left(g\right)\)
\(n_{Fe2O3}=\dfrac{8}{160}=0,05\left(mol\right)\)
a) Pt : \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2|\)
1 3 1 3
0,05 0,15 0,05
b) \(n_{Fe2\left(SO4\right)3}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
⇒ \(m_{Fe2\left(SO4\right)3}=0,05.400=20\left(g\right)\)
c) \(n_{H2SO4}=\dfrac{0,05.3}{1}=01,5\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{0,15}{2}=0,075\left(M\right)\)
Chúc bạn học tốt