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\(a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ b,n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ \Rightarrow n_{Al}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{H_2SO_4}=0,3(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,3.98}{9,8\%}=300(g)\\ d,n_{Al_2(SO_4)_3}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{5,4+300-0,3.2}.100\%=11,22\%\)
a.Mg + H2SO4 -> MgSO4 + H2
b.\(nH2=\dfrac{4.704}{22.4}=0.21mol\) = nMg
mMg = 0.21\(\times24=5.04g\)
\(\%mMg=\dfrac{5.04\times100}{25}=20.16\%\)
\(\%mAg=100-20.16=79.84\%\)
c.MgSO4 + 2KOH -> K2SO4 + Mg(OH)2
0.21 0.42
H2SO4 + 2KOH -> K2SO4 + H2O
0.04 0.08
\(nH2SO4=\dfrac{9.8\times250}{100\times98}=0.25mol\)
Mà nH2SO4 phản ứng = nH2 = 0.21 mol
\(\Rightarrow nH2SO4dư=0.25-0.21=0.04mol\)
=> nKOH = 0.42 + 0.08 = 0.5mol
\(\Rightarrow CM_{KOH}=\dfrac{0.5}{0.625}=0.8M\)
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
\(n_{Na_2CO_3}=\dfrac{360.21,2\%}{100\%.106}=0,72(mol)\\ n_{H_2SO_4}=2,5.0,2=0,5(mol)\\ PTHH:Na_2CO_3+H_2SO_4\to Na_2SO_4+H_2O+CO_2\uparrow\\ a,\text {Vì }\dfrac{n_{Na_2CO_3}}{1}>\dfrac{n_{H_2SO_4}}{1} \text {nên }Na_2CO_3\text { dư}\\ \Rightarrow n_{CO_2}=n_{H_2SO_4}=0,5(mol)\\ \Rightarrow V_{CO_2}=0,5.22,4=11,2(l)\\\)
\(b,A:Na_2SO_4\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,5(mol)\\ m_{dd_{H_2SO_4}}=200.1,1=220(g);V_{dd_{Na_2CO_3}}=\dfrac{360}{1,2}=300(ml)=0,3(l)\\ \Rightarrow C\%_{Na_2SO_4}=\dfrac{0,5.142}{360+200-0,5.44}.100\%=13,2\%\\ C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,3+0,2}=1M\)
\(n_{H_2}=\dfrac{3,36}{22,4}0,15(mol)\\ a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{Fe}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,15.56}{14,8}.100\%=56,76\%\\ \Rightarrow \%_{Cu}=100\%-56,76\%=43,24\%\\ c,n_{H_2SO_4}=0,15(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,15.98}{20\%}=73,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{73,5}{1,4}=52,5(l)\)
a, Fe2O3 + 3H2SO4 ----> Fe2(SO4)3 + 3H2O
b, Ta có
C% H2SO4=\(\dfrac{m_{ctH2SO4}}{147}.100=20\)
=> mct H2SO4=29,4 g
nH2SO4=\(\dfrac{29,4}{98}=0,3mol\)
Ta có: nH2SO4=\(\dfrac{1}{3}\)nFe3O4
=> nFe3O4=0,1 mol
=> mFe3O4=0,1.160=16 g
=> a=16 g
c, Ta có: nH2SO4=\(\dfrac{1}{3}\)nFe2(SO4)3
=> nFe2(SO4)3=0,1 mol
=> mFe2(SO4)3=400.0,1=40 g
C% Fe2(SO4)3 = \(\dfrac{40}{147+16}\).100=24,54%
\(n_{Al}=0,3mol\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,3 0,45 0,15 0,45 mol
a. \(C_M=\frac{0,45}{0,2}=2,25M\)
\(V_{H_2}=0,45.22,4=10,08l\)
c. \(C\%=\frac{0,15.342}{8,1-0,45.2+200.1,05}.100\%=23,62\%\)