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a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\)
Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,2\left(mol\right)\)
Mà: \(n_X=\dfrac{10,08}{22,4}=0,45\left(mol\right)\Rightarrow n_{CH_4}=0,25\left(mol\right)\)
\(\Rightarrow V_{CH_4}=0,25.22,4=5,6\left(l\right)\)
c, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,65\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,65\left(mol\right)\Rightarrow m_{CaCO_3}=0,65.100=65\left(g\right)\)
\(n_{hh}=\dfrac{V_{hh}}{22,4}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{CO_2\left(CH_4\right)}=x\\n_{CO_2\left(C_2H_4\right)}=2y\end{matrix}\right.\)
\(n_{CaCO_3}=\dfrac{m_{CaCO_3}}{M_{CaCO_3}}=\dfrac{10}{100}=0,1mol\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
x+2y x+2y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\x+2y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,025\end{matrix}\right.\)
\(\%CH_4=\dfrac{0,05}{0,075}.100=66,66\%\)
\(\%C_2H_4=100\%-66,66\%=33,34\%\)
\(m_{CH_4}=0,05.16=0,8g\)
\(m_{C_2H_4}=0,025.28=0,7g\)
a)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ b) n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160}=0,05(mol)\\ n_{CaCO_3} = n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = \dfrac{50}{100} = 0,5(mol)\\ \Rightarrow n_{CH_4} = 0,5 - 0,05.2 = 0,4(mol)\\ \%m_{CH_4}= \dfrac{0,4.16}{0,4.16 + 0,05.28}.100\% = 82,05\%\\ \%m_{C_2H_4} =100\% - 82,05\% = 17,95\%\)
\(n_{Br_2}=\dfrac{16}{160}=0,1mol\Rightarrow n_{CH_2}=0,1mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(\Rightarrow n_{CH_4}=0,25-0,1=0,15mol\)
\(\%V_{CH_2}=\dfrac{0,1}{0,25}\cdot100\%=40\%\)
\(\%V_{CH_4}=100\%-40\%=60\%\)
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(CH_2+\dfrac{3}{2}O_2\underrightarrow{t^o}CO_2+H_2O\)
\(\Rightarrow\Sigma n_{CO_2}=0,15+0,1=0,25mol\)
\(BTC:n_{CO_2}=n_{CaCO_3}=0,25mol\)
\(\Rightarrow m_{\downarrow}=0,25\cdot100=25g\)
nhh khí = 5,6/22,4 = 0,25 (mol)
nBr2 = 16/160 = 0,1 (mol)
PTHH: C2H2 + 2Br2 -> C2H2Br4
Mol: 0,05 <--- 0,1
nCH4 = 0,25 - 0,05 = 0,2 (mol)
%VC2H2 = 0,05/0,25 = 20%
%VCH4 = 100% - 20% = 80%
PTHH:
2C2H2 + 5O2 -> (t°) 4CO2 + 2H2O
0,05 ---> 0,125 ---> 0,1
CH4 + 2O2 -> (t°) CO2 + 2H2O
0,2 ---> 0,4 ---> 0,2
nCO2 = 0,2 + 0,1 = 0,3 (mol)
PTHH: Ca(OH)2 + CO2 -> CaCO3 + H2O
nCaCO3 = 0,3 (mol)
mCaCO3 = 0,3 . 100 = 30 (g)
Sửa : 29,25 \(\to\) 29,55
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160} = 0,05(mol)\\ \Rightarrow m_{C_2H_4} = 0,05.28 = 1,4(gam)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 +3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ba(OH)_2 \to BaCO_3 + H_2O\\ n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = n_{CH_4} + 0,05.2 = n_{BaCO_3} = \dfrac{29,55}{197}=0,15(mol) \\ \Rightarrow n_{CH_4} = 0,05(mol)\\ \Rightarrow m_{CH_4} = 0,05.16 = 0,8(gam)\)
Đầu tiên, không có nước Br chỉ có nước Br2 em nhé!
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nBr2= 8/160=0,05(mol)
PTHH: C2H4 + Br2 -> C2H4Br2
nC2H4=nBr2=0,05(mol) => mC2H4=0,05.28=1,4(g)
- Khí bay ra là khí CH4.
CH4 + 2 O2 -to-> CO2 + 2 H2O
CO2 + Ba(OH)2 -> BaCO3 + H2O
nBaCO3=29,25/197= 117/ 788 (mol ) (Số xấu quá em ơi)
=> nCH4=nCO2=nBaCO3= 117/788(mol)
=> mCH4=16. 117/788= 468/197(g)
\(m_{C_2H_4}=5.6\left(g\right)\)
\(n_{C_2H_4}=\dfrac{5.6}{28}=0.2\left(mol\right)\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(V_{CH_4}=11.2-0.2\cdot22.4=6.72\left(l\right)\)
\(n_{CH_4}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(m_{CH_4}=0.3\cdot16=4.8\left(g\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^0}2CO_2+2H_2O\)
\(V_{O_2}=\left(0.3\cdot2+0.2\cdot3\right)\cdot22.4=26.88\left(l\right)\)
\(Đặt:n_{C_2H_2}=a\left(mol\right),n_{CH_4}=b\left(mol\right)\)
\(n_{hh}=a+b=0.15\left(mol\right)\left(1\right)\)
\(C_2H_2\rightarrow2CO_2\)
\(CH_4\rightarrow CO_2\)
\(n_{CO_2}=2a+b=0.2\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.05,b=0.1\)
\(\%C_2H_2=\dfrac{0.05}{0.15}\cdot100\%=33.33\%\)
\(\%CH_4=66.67\%\)
\(2NaOH+CO_2\rightarrow Na_{_{ }2}CO_3+H_2O\)
\(0.4...............0.2............0.2\)
\(C_{M_{Na_2CO_3}}=\dfrac{0.2}{0.5}=0.4\left(M\right)\)
\(C_{M_{NaOH\left(dư\right)}}=\dfrac{0.5-0.4}{0.5}=0.2\left(M\right)\)
\(n_{hh}=6,72:22,4=0,3mol\\ C_2H_2+2Br_2->C_2H_2Br_4\\ C_2H_4+Br_2->C_2H_2Br_2\\ n_{Br_2}=0,4mol\\ n_{C_2H_2}=a;n_{C_2H_4}=b\\ a+b=0,3\\ 2a+b=0,4\\ a=0,2;b=0,1\\ \%V_{C_2H_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\ \%V_{C_2H_4}=33,33\%\)
1/2 hỗn hợp có 0,1 mol C2H2 và 0,05mol C2H4
\(BT.C:n_{CO_2}=2n_{C_2H_2}+2n_{C_2H_4}=0,3mol\\ n_{CaCO_3}=n_{CO_2}=0,3\\ m_{KT}=0,3.100=30g\)
a) C2H4 + Br2 ---> C2H4Br2
Khí thoát ra là CH4 (metan) ---> mCH4 = 0,2.16 = 3,2g ---> mC2H4 = 6 - 3,2 = 2,8g. (0,1 mol).
---> %CH4 = 0,2/0,3 = 66,7%; %C2H4 = 33,3%.
b) nCO2 = nCH4 + 2nC2H4 = 0,4 mol.
CO2 + Ca(OH)2 ---> CaCO3 + H2O
CO2 + CaCO3 + H2O ---> Ca(HCO3)2
---> nCaCO3 = 0,2 mol ---> m = 0,2.100 = 20g.
nCa(OH)2=0.3=>nCaCO3=0.3 chứ