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\(n_{HCl}=\dfrac{400\cdot36.5\%}{36.5}=4\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(2.............4............2..........2\)
\(V_{H_2}=2\cdot22.4=44.8\left(l\right)\)
\(m_{MgCl_2}=2\cdot95=190\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng}}=2\cdot24+400-2\cdot2=444\left(g\right)\)
\(C\%MgCl_2=\dfrac{190}{444}\cdot100\%=42.79\%\)
a)
$Mg + 2HCl \to MgCl_2 + H_2$
b)
n HCl = 400.36,5%/36,5 = 4(mol)
n H2 = 1/2 n HCl = 2(mol)
V H2 = 2.22,4 = 44,8(lít)
c)
n MgCl2 = n H2 = 2(mol)
m MgCl2 = 2.95 = 190(gam)
d) n Mg = n H2 = 2(mol)
Sau phản ứng :
mdd = m Mg + mdd HCl - m H2 = 2.24 + 400 -2.2 = 444(gam)
C% MgCl2 = 190/444 .100% = 42,79%
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\); \(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,8}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2-->0,6---->0,2----->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b) \(\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,8-0,6\right).36,5=7,3\left(g\right)\end{matrix}\right.\)
=> mchất tan = 26,7 + 7,3 = 34 (g)
c) mdd sau pư = 5,4 + 200 - 0,3.2 = 204,8 (g)
\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{26,7}{204,8}.100\%=13,04\%\\C\%_{HCl\left(dư\right)}=\dfrac{7,3}{204,8}.100\%=3,56\%\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3
\(V_{H_2}=0,3.22,4=6,72L\\ m_{AlCl_3}=133,5.0,2=26,7g\\ m_{\text{dd}}=5,4+200-\left(0,3.2\right)=204,8g\\ C\%=\dfrac{26,7}{204,8}.100\%=13\%\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b, \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, \(n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\Rightarrow m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{3,375}{27}=0,125\left(mol\right)\\n_{H_2SO_4}=\dfrac{300\cdot4,9\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,125}{2}>\dfrac{0,15}{3}\) \(\Rightarrow\) Al còn dư, H2SO4 p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,15\left(mol\right)\\n_{Al\left(dư\right)}=0,025\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2}=0,15\cdot2=0,3\left(g\right)\\m_{Al\left(dư\right)}=0,025\cdot27=0,672\left(g\right)\\m_{Al_2\left(SO_4\right)_3}=0,05\cdot342=17,1\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{Al\left(dư\right)}-m_{H_2}=302,403\left(g\right)\)
\(\Rightarrow C\%_{Al_2\left(SO_4\right)_3}=\dfrac{17,1}{302,403}\cdot100\%\approx5,65\%\)
Fe+H2SO4->FeSO4+H2
0,15---0,15-----0,15---0,15 mol
n Fe=8,4\56=0,15 mol
=>VH2=0,15.22,4=3,36l
=>m H2SO4=0,15.98=14,7g
=>C% H2SO4=14,7\245 .100=6%
=>m dd muối=8,4+245-0,15.2=253,1g
=>C% muối =0,15.152\253,1 .100=9%
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b, \(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,45\left(mol\right)\Rightarrow V_{H_2}=0,45.22,4=10,08\left(l\right)\)
c, Ta có: m dd sau pư = 8,1 + 200 - 0,45.2 = 207,2 (g)
Theo PT: \(n_{AlCl_3}=n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,3.133,5}{207,2}.100\%\approx19,33\%\)