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a) PTHH: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
b) Ta có: \(\%V_{CH_4}=\dfrac{3,36}{8,96}=37,5\%\) \(\Rightarrow\%V_{C_2H_2}=62,5\%\)
c) Theo PTHH: \(n_{Br_2}=2n_{C_2H_2}=2\cdot\dfrac{8,96-3,36}{22,4}=0,5\left(mol\right)\) \(\Rightarrow m_{Br_2}=0,5\cdot160=80\left(g\right)\)
\(C_2H_2+2Br_2->C_2H_2Br_4\\ n_{hh}=\dfrac{3,36}{22,4}=0,15mol\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\\ n_{C_2H_2}=0,05mol\\ n_{Br_2}=2.0,05=0,1mol\\ m_{Br_2}=0,1.160=16g\\ \%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\ \%V_{C_2H_2}=33,33\%\)
n Br2=\(\dfrac{32}{160}\)=0,2 mol
C2H2+2Br2->C2H2Br4
0,1------0,2 mol
=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%
=>%VCH4=100-40=60%
=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol
CH4+2O2-to>CO2+2H2O
0,15----0,3
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
0,1-----0,25 mol
=>VO2=(0,3+0,25).22,4=12,32l
\(n_{hh}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\)
Gọi số mol của \(C_2H_4\) là: \(a\)
Gọi số mol của \(C_2H_2Br_4\) là: \(b\)
\(PTHH:\\ +)C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\+)C_2H_4+Br_2\rightarrow C_2H_4Br_2 \)
\(\left\{{}\begin{matrix}a+b=0,3\\a+2b=0,4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\%V_{C_2H_4}=\dfrac{0,2}{0,3}.100\%=66,67\%\\ \%V_{C_2H_2}=100\%-66,67\%=33,33\%\)
a, \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,1\left(mol\right)\)
\(\Rightarrow V=V_{CH_4}=4,48-0,1.22,4=2,24\left(l\right)\)
b, \(n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,1.26}.100\%\approx38,1\%\\\%m_{C_2H_2}\approx61,9\%\end{matrix}\right.\)
a)
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
$Mg + H_2SO_4 \to MgSO_4 + H_2$
b)
Gọi $n_{Zn} = a(mol) ; n_{Mg} = b(mol) \Rightarrow 65a + 24b = 19,85(1)$
Theo PTHH :
$n_{H_2} = a + b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,25 ; b = 0,15
$\%m_{Zn} = \dfrac{0,25.65}{19,85}.100\% = 81,9\%$
$\%m_{Mg} = 100\% - 81,9\% = 18,1\%$
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{Br_2}=\dfrac{2,4}{160}=0,015mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,0075 0,015 ( mol )
\(V_{C_2H_2}=0,0075.22,4=0,168l\)
\(V_{CH_4}=3,36-0,168=3,192l\)
\(\%V_{C_2H_2}=\dfrac{0,168}{3,36}.100=5\%\)
\(\%V_{CH_4}=100\%-5\%=95\%\)
C2H4 + Br2==>C2H4Br2
metan(CH4) ko td với brom
b, mol hỗn hợp = 0.15(mol)
Do chỉ có etilen td được với brom nên khí thoát ra là metan
==>mol Ch4=0.1(mol)==>molC2H4=0.05(mol)
%V CH4=66.67%==>%VC2H4=33.33(bài này dễ mà )
\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025<-0,125
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
nkhí thoát ra(CH4) =0,1 mol
nhh khí bđ=0,15 mol
=>nC2H2=0,05 mol
C2H2 +2Br2 =>C2H2Br4
%V CH4=0,1/0,15.100%=66,67%
%V C2H2=33,33%