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a. PTHH:
Fe + 2HCl ---> FeCl2 + H2 (1)
Mg + 2HCl ---> MgCl2 + H2 (2)
b. Gọi x, y lần lượt là số mol của Fe và Mg
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT(1): \(n_{H_2}=n_{Fe}=x\left(mol\right)\)
Theo PT(2): \(n_{H_2}=n_{Mg}=y\left(mol\right)\)
\(\Rightarrow x+y=0,25\) (*)
Theo đề, ta lại có: 56x + 24y = 8,25 (**)
Từ (*) và (**), ta có HPT:
\(\left\{{}\begin{matrix}x+y=0,25\\56x+24y=8,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x\approx0,07\\y\approx0,18\end{matrix}\right.\)
=> \(m_{Fe}=0,07.56=3,92\left(g\right)\)
=> \(\%_{m_{Fe}}=\dfrac{3,92}{8,25}.100\%=47,52\%\)
\(\%_{m_{Mg}}=100\%-47,52\%=52,48\%\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,3\left(mol\right)=n_{ZnCl_2}\\n_{HCl}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0.3\cdot65}{35,5}\cdot100\%\approx54,93\%\\\%m_{Cu}=45,07\%\\C\%_{HCl}=\dfrac{0,6\cdot36,5}{500}\cdot100\%=4,38\%\\m_{ZnCl_2}=0,3\cdot136=40,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(\left\{{}\begin{matrix}m_{Cu}=35,5-0,3\cdot65=16\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{KL}+m_{ddHCl}-m_{Cu}-m_{H_2}=518,9\left(g\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{518,9}\cdot100\%\approx7,86\%\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow m_{Zn}=0,1\cdot65=6,5\left(g\right)\)
\(\Rightarrow\%m_{Zn}=\dfrac{6,5}{10}\cdot100\%=65\%\) \(\Rightarrow\%m_{Cu}=35\%\)
c) Theo PTHH: \(n_{HCl}=2n_{Zn}=0,2mol\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2\cdot36,5}{5\%}=146\left(g\right)\)
a) Đặt: nMg=x(mol); nZnO=y(mol)
nH2SO4= 0,2(mol)
PTHH: Mg + H2SO4 -> MgSO4 + H2
x___________x____x_______x(mol)
ZnO + H2SO4 -> ZnSO4 + H2O
y____y______y(mol)
Ta có:
\(\left\{{}\begin{matrix}24x+81y=12,9\\22,4x=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
mMg=0,2.24=4,8(g)
%mMg=(4,8/12,9).100=37,209%
=>%mZnO=62,791%
b) nH2SO4=x+y=0,3(mol)
=> \(C\%ddH2SO4=\dfrac{0,3.98}{120}.100=24,5\%\)
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
a)
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
$Mg + H_2SO_4 \to MgSO_4 + H_2$
b)
Gọi $n_{Zn} = a(mol) ; n_{Mg} = b(mol) \Rightarrow 65a + 24b = 19,85(1)$
Theo PTHH :
$n_{H_2} = a + b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,25 ; b = 0,15
$\%m_{Zn} = \dfrac{0,25.65}{19,85}.100\% = 81,9\%$
$\%m_{Mg} = 100\% - 81,9\% = 18,1\%$