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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{KMnO_4}=\dfrac{15,8}{158}=0,1\left(mol\right)\\ 2KMnO_4+16HCl\rightarrow2KCl+2MnCl_2+5Cl_2+8H_2O\\ n_{Cl_2}=\dfrac{5}{2}.0,1=0,25\left(mol\right)\\ V_{Cl_2\left(đkc\right)}=0,25.24,79=6,1975\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
- PT: a, \(2KMnO_4+16HCl\rightarrow2KCl+2MnCl_2+5Cl_2+8H_2O\) (1)
\(MnO_2+4HCl_đ\underrightarrow{t^o}MnCl_2+Cl_2+2H_2O\) (2)
- Ta có: \(n_{HCl\left(1\right)}=n_{HCl\left(2\right)}=0,2.2=0,4\left(mol\right)\)
Theo PT (1): \(n_{Cl_2}=\dfrac{5}{16}n_{HCl\left(1\right)}=0,125\left(mol\right)\Rightarrow V_1=0,125.22,4=2,8\left(l\right)\)
(2): \(n_{Cl_2\left(2\right)}=\dfrac{1}{4}n_{HCl\left(2\right)}=0,1\left(mol\right)\Rightarrow V_2=0,1.22,4=2,24\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
- Theo bài ra \(\Rightarrow\left\{{}\begin{matrix}n_{KMnO_4}=0,1\\n_{KClO_3}=0,15\end{matrix}\right.\) ( mol )
\(2KMnO_4+16HCl\rightarrow2KCl+2MnCl_2+5Cl_2+8H_2O\)
.......0,1..........................................................0,25...........
\(KClO_3+6HCl\rightarrow KCl+3Cl_2+3H_2O\)
....0,15................................0,45....................
\(\Rightarrow n_{HCl}=0,7\left(mol\right)\)
\(6KOH+3Cl_2\rightarrow KClO_3+5KCl+3H_2O\)
Ta có : \(m=m_{KOH}+m_{Cl_2}=139,3\left(g\right)\)
Vậy ...
![](https://rs.olm.vn/images/avt/0.png?1311)
Chọn đáp án C
2 K M n O 4 + 16HCl → 2KCl + 2 M n C l 2 + 5 C l 2 + 8 H 2 O
n H C l = 14 , 6 36 , 5 = 0,4 (mol) => n C l 2 = 14 36 , 5 = 0,125 (mol)
=> V = 0,125.22,4 = 2,8 (lít)
2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 5Cl2 + 8H2O
0,1--------------------------------------------------0,25 mol
n KMnO4=\(\dfrac{15,8}{158}\)=0,1 mol
Hao hụt 10%
=>VCl2=0,25.22,4.90%=5,04l