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Theo đề bài ta có : nH2 = 10,08/22,4 = 0,45 (mol)
a) PTHH :
Fe+2HCl−>FeCl2+H2↑
0,45mol->,9mol->0,45mol
b) khối lượng mạt sắt tham gia phản ứng là :
mFe = 0,45.56 = 25,2(g)
c)
nồng độ mol của dd HCl đã dùng là :
CMddHCl = 0,9/0,15 = 6(M)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
a)\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
0,1 0,2 0,1 0,1 0,1
b)\(m_{HCl}=0,1\cdot36,5=3,65\left(g\right)\)
\(a\%=\dfrac{3,65}{100}\cdot100\%=3,65\%\)
c)\(m_{CaCO_3}=0,1\cdot100=10\left(G\right)\)
\(\Rightarrow\%m_{CaCO_3}=\dfrac{10}{16}\cdot100\%=62,5\%\)
\(\Rightarrow\%m_{CaCl_2}=100\%-62,5\%=37,5\%\)
d)\(m_{CaCl_2}=0,1\cdot111=11,1\left(g\right)\)
\(m_{H_2O}=0,1\cdot18=1,8\left(g\right)\)
\(m_{ddsau}=10+100-0,1\cdot44-1,8=103,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{11,1}{103,8}\cdot100\%=10,7\%\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)
Ta có: \(n_{Na_2CO_3}=0,4.1=0,4\left(mol\right)\)
PT: \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
a, \(n_{HCl}=2n_{Na_2CO_3}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,6}=\dfrac{4}{3}\left(M\right)\)
b, \(n_{NaCl}=2n_{Na_2CO_3}=0,8\left(mol\right)\Rightarrow m_{NaCl}=0,8.58,5=46,8\left(g\right)\)
\(n_{CO_2}=n_{Na_2CO_3}=0,4\left(mol\right)\Rightarrow V_{CO_2}=0,4.24,79=9,916\left(l\right)\)
c, \(C_{M_{NaCl}}=\dfrac{0,8}{0,4+0,6}=0,8\left(M\right)\)
nCaCO3 = \(\dfrac{m}{M}\)=\(\dfrac{10}{100}\)= 0,1 (mol)
a. PTHH:
CaCO3 + 2HCl → CaCl2 + CO2 + H2O
1 : 2 : 1 : 1 : 1 (mol)
0,1 : 0,2 : 0,1 : 0,1 : 0,1 (mol)
b. mHCl = n.M = 0,2.36,5 = 7,3 (g)
mdd HCl = \(\dfrac{m_{ct}.100\%}{C\%}\)=\(\dfrac{7,3.100}{10}\)= 73 (g)
mdd (pư) = 10 + 73 = 83 (g)
c. VCO2 (đktc) = n.22,4 = 0,1.22,4 = 2,24 (l)
d. mCaCl2 = n.M = 0,1.111 = 11,1 (g)
mdd (sau pư) = mdd (pư) - mCO2 = 83 + (0,1.44) = 87,4 (g)
C% = \(\dfrac{m_{ct}}{m_{dd}}\).100% = \(\dfrac{11,1}{87,4}\).100% = 12,7%
a) PTHH: CaCO3 + 2HCl → CaCl2 + CO2↑ + H2O
b) \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{CaCO_3}=2\times0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,2\times36,5=7,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{7,3\times100\%}{10\%}=73\left(g\right)\)
c) Theo PT: \(n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,1\times22,4=2,24\left(l\right)\)
\(m_{CO_2}=0,1\times44=4,4\left(g\right)\)
d) Theo PT: \(n_{CaCl_2}=n_{CaCO_3}=0,1\left(mol\right)\)
\(\Rightarrow m_{CaCl_2}=0,1\times111=11,1\left(g\right)\)
\(m_{dd}=10+73-4,4=78,6\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{11,1}{78,6}\times100\%=14,12\%\)