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\(n_{FeCl_3}=0.2\cdot0.4=0.08\left(mol\right)\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(0.08...........0.24..............0.08\)
\(2Fe\left(OH\right)_3\underrightarrow{^{^{t^0}}}Fe_2O_3+3H_2O\)
\(0.08...........0.04\)
\(m_{Fe_2O_3}=0.04\cdot160=6.4\left(g\right)\)
\(V_{dd_{NaOH}}=\dfrac{0.24}{0.5}=0.48\left(l\right)\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\) (1)
\(2Fe\left(OH\right)_3\rightarrow Fe_2O_3+3H_2O\) (2)
\(n_{FeCl_3}=0,2.0,4=0,08\left(mol\right)\)
Bảo toàn nguyên tố Fe : \(n_{FeCl_3}=2n_{Fe_2O_3}=0,08\left(mol\right)\)
=> \(n_{Fe_2O_3}=0,04\left(mol\right)\)
=> \(m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\)
Theo PT (1) : \(n_{NaOH}=3n_{FeCl_3}=0,08.3=0,24\left(mol\right)\)
=> \(V_{NaOH}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
1
\(n_{CuCl_2}=0,2.0,5=0,1\left(mol\right)\\ n_{NaOH}=0,5.0,5=0,25\left(mol\right)\)
a. \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,1------->0,2------------>0,1---------->0,2
b. Xét \(\dfrac{0,1}{1}< \dfrac{0,25}{2}\) => NaOH dư
=> \(m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
c. \(n_{NaOH.dư}=0,25-0,2=0,05\left(mol\right)\)
Các chất có trong nước lọc:
\(CM_{NaOH}=\dfrac{0,05}{0,2+0,5}=\dfrac{1}{14}\approx0,07M\)
\(CM_{NaCl}=\dfrac{0,2}{0,2+0,5}=\dfrac{2}{7}\approx0,29M\)
2
\(n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ n_{NaOH}=\dfrac{150.8\%}{100\%}:40=0,3\left(mol\right)\)
a. \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,15<-------0,3--------->0,15------->0,3
b. Xét \(\dfrac{0,2}{1}>\dfrac{0,3}{2}\) => \(CuCl_2\) dư
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,15.98=14,7\left(g\right)\)
c. \(m_{dd}=27+150=177\left(g\right)\)
Các chất có trong nước lọc:
\(C\%_{CuCl_2}=\dfrac{\left(0,2-0,15\right).135.100\%}{177}=3,81\%\)
\(C\%_{NaCl}=\dfrac{0,3.58,5.100\%}{177}=9,92\%\)
3
\(n_{HCl}=0,3.1=0,3\left(mol\right)\\ n_{AgNO_3}=0,5.0,5=0,25\left(mol\right)\)
a. Hiện tượng: xuất hiện kết tủa trắng bạc clorua \(AgCl\)
b.
\(AgNO_3+HCl\rightarrow AgCl+HNO_3\)
0,25------->0,25----->0,25--->0,25
Xét \(\dfrac{0,25}{1}< \dfrac{0,3}{1}\)=> axit dư.
\(m_{kt}=m_{AgCl}=0,25.143,5=35,875\left(g\right)\)
c. Bạn xem đề đủ chưa, có thiếu D (khối lượng riêng) hay không rồi nói mình làm nhé: )
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)
\(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)
b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)
c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)
a, \(CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2+2KCl\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
b, \(n_{CuCl_2}=\dfrac{20,25}{135}=0,15\left(mol\right)\)
Theo PT: \(n_{KOH}=2n_{CuCl_2}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,3}{0,3}=1\left(M\right)\)
c, \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,15\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,15.80=12\left(g\right)\)
a)
\(FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4\)
b)
\(n_{FeSO_4} = 0,4.0,5 = 0,2(mol) ; n_{NaOH} = 0,5.0,5 = 0,25(mol)\)
Ta thấy : \(2n_{FeSO_4} = 0,4 > n_{NaOH} = 0,25\) nên FeSO4 dư.
Theo PTHH :
\(n_{Fe(OH)_2} = 0,5n_{NaOH} = 0,125(mol)\\ \Rightarrow m_{Fe(OH)_2} = 0,125.90 = 11,25(gam)\)
c)
\(4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O\)
Theo PTHH :
\(n_{Fe_2O_3} = 0,5n_{Fe(OH)_2} = 0,0625(mol)\\ \Rightarrow m_{Fe_2O_3} = 0,0625.160 = 10(gam)\)
a) PTHH: \(3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)
b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,5\cdot0,1=0,05\left(mol\right)\\n_{FeCl_3}=0,2\cdot0,2=0,04\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,05}{3}< \dfrac{0,04}{1}\) \(\Rightarrow\) NaOH p/ứ hết, FeCl3 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,05\left(mol\right)\\n_{FeCl_3\left(dư\right)}=\dfrac{7}{300}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,05\cdot58,5=2,925\left(g\right)\\m_{FeCl_3\left(dư\right)}=\dfrac{7}{300}\cdot162,5\approx3,8\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
Ta có: \(n_{Fe\left(OH\right)_3}=\dfrac{1}{60}\left(mol\right)\) \(\Rightarrow n_{H_2O}=\dfrac{1}{40}\left(mol\right)\) \(\Rightarrow m_{H_2O}=\dfrac{1}{40}\cdot18=0,45\left(g\right)\)