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\(m_{CH_3COOH}=12\%.100=12\left(g\right)\\ n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2--------->0,2------------>0,2
\(m_{NaOH}=0,2.40=8\left(g\right)\\ m_{ddNaOH}=\dfrac{8}{8,4\%}=\dfrac{2000}{21}\left(g\right)\\ m_{ddCH_3COONa}=\dfrac{2000}{21}+100=\dfrac{4100}{21}\left(g\right)\\ m_{CH_3COONa}=0,2.82=16,4\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{16,4}{\dfrac{4100}{21}}.100\%=8,4\%\)
`=>` Gợi ý:
`CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O`
`mCH3COOH = 100x12/100 = 12` (g)
`==> nCH3COOH = m/M = 12/60 = 0.2` (mol)
Theo pt: `=> nNaHCO3 = 0.2` (mol)
`==> mNaHCO3 = n.M = 0.2x84 =16.8` (g)
`==> mdd NaHCO3 = 16.8x100/8.4 = 200` (g)
Ta có: `nCH3COONa = 0.2` (mol)
a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
PTHH: \(CH_3COOH+KHCO_3\rightarrow CH_3COOK+H_2O+CO_2\uparrow\)
a) Ta có: \(n_{CH_3COOH}=\dfrac{200\cdot24\%}{60}=0,8\left(mol\right)=n_{KHCO_3}\)
\(\Rightarrow m_{ddKHCO_3}=\dfrac{0,8\cdot100}{16,8\%}\approx476.2\left(g\right)\)
b) Theo PTHH: \(n_{CH_3COOK}=0,8\left(mol\right)=n_{CO_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_3COOK}=0,8\cdot98=78,4\left(g\right)\\m_{CO_2}=0,8\cdot44=35,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddCH_3COOH}+m_{ddKHCO_3}-m_{CO_2}=641\left(g\right)\)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{78,4}{641}\cdot100\%\approx12,23\%\)
mCH3COOH= 150*6/100=9g
nCH3COOH= 9/60=0.15 mol
CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0.15_________0.15__________0.15______0.15
mNaHCO3= 0.15*84=12.6g
mdd NaHCO3= 12.6*100/8.4=150g
m dung dịch sau phản ứng=mdd CH3COOH + mdd NaHCO3 - mCO2= 150+150-0.15*44==293.4g
C%CH3COONa= 12.3/293.4*100%= 4.19%
CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O
mCH3COOH = 150 x 6/100 = 9 (g)
===> nCH3COOH = m/M = 9/60 = 0.15 (mol)
Theo phương trình ==> nNaHCO3 = 0.15 (mol)
mNaHCO3 = n.M = 0.15 x 84 = 12.6 (g)
===> mddNaHCO3 = 12.6 x 100/8.4 = 150 (g)
mdd sau pứ = 150 + 150 - 0.3 = 299.7 (g)
mCH3COONa = n.M = 0.15 x 82 = 12.3 (g)
C%ddCH3COONa = 4.104 %
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
a) Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,0125<-----0,025------------>0,025------>0,0125
=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)
c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)
\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)
\(m_{CH_3COOH}=24\%.150=36\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 ---> 2CH3COONa + CO2 + H2O
0,6 0,3 0,6 0,3
=> VCO2 = 0,3.22,4 = 6,72 (l)
\(m_{Na_2CO_3}=0,3.31,8\left(g\right)\)
=> \(m_{ddNa_2CO_3}=\dfrac{31,8}{21,2\%}=150\left(g\right)\)
mCO2 = 0,3.44 = 13,2 (g)
\(m_{dd}=150+150-13,2=286,8\left(g\right)\)
\(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{24,6}{286,8}=8,58\%\)
\(n_{CH_3COOH}=\dfrac{100.12\%}{60}=0,2\left(mol\right)\)
PTHH: CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O
0,2------>0,2-------------->0,2------->0,2
=> \(m_{dd.NaHCO_3.8,4\%}=\dfrac{0,2.84.100}{8,4}=200\left(g\right)\)
mdd sau pư = 100 + 200 - 0,2.44 = 291,2 (g)
\(m_{CH_3COONa}=0,2.82=16,4\left(g\right)\)
=> \(C\%_{CH_3COONa}=\dfrac{16,4}{291,2}.100\%=5,632\%\)
CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O
mCH3COOH = 100x12/100 = 12 (g)
==> nCH3COOH = m/M = 12/60 = 0.2 (mol)
Theo pt: => nNaHCO3 = 0.2 (mol)
==> mNaHCO3 = n.M = 0.2x84 =16.8 (g)
==> mdd NaHCO3 = 16.8x100/8.4 = 200 (g)
Ta có: nCH3COONa = 0.2 (mol)
==> mCH3COONa = n.M = 0.2 x 82 = 16.4 (g)
mdd sau pứ = 200 + 100 - 0.2 x 44 =291.2 (g)
C% = 16.4 x 100/ 291.2 = 5.63%
Cho em hỏi 44 ở dòng gần cuối ở đâu ra vậy ạ??