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PTHH: R + 2HCl ---> RCl2 + H2 (1)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(n_{HCl}=\dfrac{100}{1000}.5=0,5\left(mol\right)\)
Ta thấy: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)
Vậy HCl dư.
Theo PT(1): \(n_R=n_{H_2}=0,2\left(mol\right)\)
=> \(M_R=\dfrac{4,8}{0,2}=24\left(g\right)\)
Vậy R là magie (Mg)
PT: Mg + 2HCl ---> MgCl2 + H2 (2)
Ta có: \(m_{dd_{MgCl_2}}=4,8+\dfrac{100}{1000}-0,2.2=4,5\left(lít\right)\)
Theo PT(2): \(n_{MgCl_2}=n_{H_2}=0,2\left(mol\right)\)
=> \(C_{M_{MgCl_2}}=\dfrac{0,2}{4,5}=\dfrac{2}{45}M\)
\(a,n_{CO_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ PTHH:M_2CO_3+2HCl\to 2MCl+H_2O+CO_2\uparrow\\ \Rightarrow n_{M_2CO_3}=n_{CO_2}=0,15(mol)\\ \Rightarrow M_{M_2CO_3}=\dfrac{15,9}{0,15}=106(g/mol)\\ \Rightarrow M_{M}=\dfrac{106-12-16.3}{2}=23(g/mol)\)
Vậy M là natri (Na)
\(b,n_{HCl}=2n_{CO_2}=0,3(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,3}{0,75}=0,4(l)\\ X:NaCl\\ n_{NaCl}=n_{HCl}=0,3(mol)\\ \Rightarrow C_{M_{NaCl}}=\dfrac{0,3}{0,4}=0,75M\)
\(n_{H_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(2A+2nH_2O\rightarrow2A\left(OH\right)_n+nH_2\)
\(\dfrac{0.1}{n}........................0.05\)
\(M_A=\dfrac{3.9}{\dfrac{0.1}{n}}=39n\)
Với : \(n=1\rightarrow A=39\)
\(A:K\)
\(m_{KOH}=0.1\cdot56=5.6\left(g\right)\)
\(m_{ddX}=3.9+46.2-0.05\cdot2=50\left(g\right)\)
\(C\%_{KOH}=\dfrac{5.6}{50}\cdot100\%=11.2\%\)
\(b.\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.1....................0.2\)
\(m_{KOH}=0.2\cdot56=11.2\left(g\right)\)
\(m_{dd_X}=\dfrac{11.2}{28\%\%}=40\left(g\right)\)
nH2 = 2,24/22,4 = 0,1 (mol)
PTHH: R + 2H2O -> R(OH)2 + H2
Mol: 0,1 <--- 0,2 <--- 0,1 <--- 0,1
M(R) = 13,7/0,1 = 137 (g/mol)
=> R là Bari
CMBa(OH)2 = 0,1/0,2 = 0,5M
a) Gọi kim loại cần tìm là R
\(n_R=\dfrac{7,56}{M_R}\left(mol\right)\)
PTHH: 2R + 2nHCl --> 2RCln + nH2
\(\dfrac{7,56}{M_R}\)------------>\(\dfrac{7,56}{M_R}\)
=> \(M_{RCl_n}=M_R+35,5n=\dfrac{37,38}{\dfrac{7,56}{M_R}}\)
=> \(M_R=9n\left(g/mol\right)\)
Xét n = 1 => MR = 9(Loại)
Xét n = 2 => MR = 18 (Loại)
Xét n = 3 => MR = 27(g/mol) => R là Al (Nhôm)
b)
\(n_{Al}=\dfrac{7,56}{27}=0,28\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,28-->0,84--->0,28--->0,42
=> \(V_{H_2}=0,42.22,4=9,408\left(l\right)\)
\(m_{HCl}=0,84.36,5=30,66\left(g\right)\)
=> \(m_{ddHCl}=\dfrac{30,66.100}{12}=255,5\left(g\right)\)
c) mdd sau pư = 7,56 + 255,5 - 0,42.2 = 262,22 (g)
=> \(C\%_{AlCl_3}=\dfrac{37,38}{262,22}.100\%=14,255\%\)