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\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ pthh:FeO+H_2\underrightarrow{t^o}Fe+H_2O\)
0,2 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + H2SO4 ---> ZnSO4 + H2
0,2--->0,2--------->0,2------>0,2
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\\ m_{H_2SO_4}=\dfrac{0,2.98}{20\%}=98\left(g\right)\\ \rightarrow V_{ddH_2SO_4}=\dfrac{98}{1,14}=86\left(ml\right)=0,086\left(l\right)\\ \rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,086}=2,33M\)
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,5 0,5 0,5
\(m_{MgSO_4}=0,5.120=60g\\
V_{H_2}=0,5.22,4=11,2\left(mol\right)\\
\)
c)
\(n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\\
pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\
LTL:0,5>0,2\)
=> H2SO4 dư
\(n_{Zn\left(p\text{ư}\right)}=n_{H_2SO_4}=0,2\left(mol\right)\\
n_{Zn\left(d\right)}=0,5-0,2=0,3\left(mol\right)\)
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, Ta có: \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,35}{1}\), ta được H2 dư.
Theo PT: \(n_{H_2\left(pư\right)}=n_{CuO}=0,15\left(mol\right)\)
\(\Rightarrow n_{H_2\left(dư\right)}=0,35-0,15=0,2\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=0,2.2=0,4\left(g\right)\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2--->0,3-------->0,1----------->0,3
b) `V_{H_2} = 0,3.22,4 = 6,72 (l)`
c) `m_{H_2SO_4} = 0,3.98 = 29,4 9g)`
d) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Xét tỉ lệ: 0,2 < 0,3 => H2 dư
\(nZn=\dfrac{13}{65}=0,2\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
1 1 1 1 (mol)
0,2 0,2 0,2 0,2 (mol)
\(VH_2=0,2.22,4=4,48\left(l\right)\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
1 3 2 3 (mol)
0,2 2/15 (mol)
\(mFe=\dfrac{2}{15}.56=7,47\left(g\right)\)
\(n_{Mg}=\dfrac{10,8}{24}=0,45\left(mol\right)\\ pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
0,45 0,45 0,45
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\\ C\%_{H_2SO_4}=\dfrac{44,1}{176,4}.100\%=25\%\\ V_{H_2}=0,45.22,4=10,08\left(l\right)\)