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Bài 9 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05--->0,1-------->0,05
a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)
Câu 10 :
\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
0,05-->0,1------->0,05
\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)
\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)
Lần sau bạn đăng tách từng bài ra nhé.
Bài 1:
Ta có: \(n_{NaOH}=\dfrac{100.12\%}{40}=0,3\left(mol\right)\)
PT: \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
a, Theo PT: \(n_{FeCl_2}=n_{Fe\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,15\left(mol\right)\)
\(\Rightarrow m_{FeCl_2}=0,15.127=19,05\left(g\right)\)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{19,05}{200}.100\%=9,525\%\)
b, Ta có: m dd sau pư = 200 + 100 - 0,15.90 = 286,5 (g)
\(n_{NaCl}=n_{NaOH}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{NaCl}=\dfrac{0,3.58,5}{286,5}.100\%\approx6,13\%\)
c, Phần này mình coi như nung trong điều kiện không có không khí nhé.
PT: \(Fe\left(OH\right)_2\xrightarrow[\left(kckk\right)]{t^o}FeO+H_2O\)
Theo PT: \(n_{FeO}=n_{Fe\left(OH\right)_2}=0,15\left(mol\right)\Rightarrow m_{FeO}=0,15.72=10,8\left(g\right)\)
Bài 4:
Ta có: \(n_{CuCl_2}=0,1.1,5=0,15\left(mol\right)\)
PT: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
a, \(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,15\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,15.98=14,7\left(g\right)\)
b, \(n_{NaOH}=2n_{CuCl_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(n_{NaCl}=2n_{CuCl_2}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,3}{0,15+0,1}=1,2\left(M\right)\)
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,3\left(mol\right)\\n_{ZnCl_2}=0,15\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{ZnCl_2}=0,15\cdot136=20,4\left(g\right)\\C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
a, Theo PT: \(n_{CuCl_2}=n_{CuO}=0,1\left(mol\right)\Rightarrow m_{CuCl_2}=0,1.135=13,5\left(g\right)\)
b, \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
