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a)
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$
b)
Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$
$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$
c) $Fe + CuSO_4 \to FeSO_4 + Cu$
$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$
$= 3,6 + 0,15.64 = 13,2(gam)$
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,15<-0,3<----0,15<---0,15
\(\left\{{}\begin{matrix}\%Fe=\dfrac{0,15.56}{12}.100\%=70\%\%\\\%Cu=100\%-70\%=30\%\end{matrix}\right.\)
c) mHCl = 0,3.36,5 = 10,95 (g)
=> \(m_{dd}=\dfrac{10,95.100}{10}=109,5\left(g\right)\)
d) mdd = 12 + 109,5 - 0,15.2 = 121,2 (g)
\(C\%\left(FeCl_2\right)=\dfrac{0,15.127}{121,2}.100\%=15,718\%\)
Chỉ có Zn phản ứng thôi. Cu không phản ứng, không tan.---->Chất rắn không tan là Cu
Zn+ H2SO4 ---> ZnSO4+ H2↑
0.1 0.1
nH2= 2.24: 22.4=0.1 mol
mZn= 0.1x65=6.5 g
mCu=10.5-6,5=4 g
%Zn=6.5:10.5x100%=61.9%
%Cu=4:10.5x100%=38.1%
a) Gọi `n_{Al} = a (mol); n_{Fe} = b (mol)`
PTHH:
`2Al + 3H_2SO_4 -> Al_2(SO_4)_3 + 3H_2`
`Fe + H_2SO_4 -> FeSO_4 + H_`
b) `n_{H_2} = (0,56)/(22,4) = 0,025 (mol)`
Theo PT: `n_{H_2} = n_{Fe} + 3/2 n_{Al}`
`=> b + 1,5a = 0,025`
Giải hpt \(\left\{{}\begin{matrix}27a+56b=0,83\\1,5a+b=0,025\end{matrix}\right.\Leftrightarrow a=b=0,01\)
=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%=32,53\%\\\%m_{Fe}=100\%-32,53\%=67,47\%\end{matrix}\right.\)
a)\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,15 0,3 0,15
\(m_{Zn}=0,15\cdot65=9,75\left(g\right)\)
\(\%m_{Zn}=\dfrac{9,75}{17,85}\cdot100\%=54,62\%\)
\(\%m_{ZnO}=100\%-54,62\%=45,38\%\)
b)\(m_{ZnO}=17,85-9,75=8,1\left(g\right)\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1mol\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
0,1 0,2
\(\Rightarrow\Sigma n_{HCl}=0,3+0,2=0,5mol\)
\(\Rightarrow V=\dfrac{0,5}{1}=0,5l=500ml\)
a. PTHH:
Cu + H2SO4 ---x--->
Mg + H2SO4 ---> MgSO4 + H2
b. Ta có: \(n_{H_2SO_4}=2.\dfrac{100}{1000}=0,2\left(mol\right)\)
Theo PT: \(n_{Mg}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,2.24=4,8\left(g\right)\)
\(\Rightarrow\%_{m_{Mg}}=\dfrac{4,8}{6}.100\%=80\%\)
\(\%_{m_{Cu}}=100\%-80\%=20\%\)
c. Theo PT: \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(lít\right)\)
d. PTHH: \(Cu+2H_2SO_{4_đ}\overset{t^o}{--->}CuSO_4+SO_2+2H_2O\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\\ a)ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,15 0,15 0,15 0,15
\(b)m_{Fe}=0,15.56=8,4g\\ m_{ZnO}=16,5-8,4=8,1g\\ c)n_{ZnO}=\dfrac{8,1}{81}=0,1mol\\ ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)
0,1 0,1 0,1 0,1
\(V_{ddH_2SO_4}=\dfrac{0,15+0,1}{2}=0,125M\\ d)Fe+CuSO_4\rightarrow FeSO_4+Cu\)
0,15 0,15 0,15 0,15
\(m_{rắn}=m_{ZnO}+m_{Cu}=8,1+0,15.64=17,7g\)