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\(PTHH:2CH_3COOH+Ca\rightarrow\left(CH_3COO\right)_2Na+H_2\)
Ta có:
\(n_{\left(CH3COO\right)2Na}=\frac{4,47}{158}=0,03\left(mol\right)\)
\(\Rightarrow n_{CH3COOH}=0,03.2=0,06\left(mol\right)\)
\(\Rightarrow CM_{CH3COOH}=\frac{0,06}{0,2}=0,3M\)
\(n_{H2}=0,03\left(mol\right)\Rightarrow V_{H2}=0,03.22,4=6,72\left(l\right)\)
PTHH :
\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
_0,06________0,06_____________________
\(\Rightarrow V_{NaOH}=\frac{0,06}{0,5}=0,12\left(l\right)=120\left(ml\right)\)
a)
$C_2H_5OH + CH_3COOH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O$
b)
n CH3COOC2H5 = n C2H5OH = 9,2/46 = 0,2(mol)
=> m este = 0,2.88 = 17,6 gam
c)
n este = 8,8/88 = 0,1(mol)
=> n C2H5OH = n CH3COOH = 0,1/60% = 1/6 mol
=> m C2H5OH = 46 . 1/6 = 7,67(gam) ; m CH3COOH = 60 . 1/6 = 10(gam)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{2,84}{142}=0,02\left(mol\right)\)
PTHH :
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,04 0,02 0,02
\(a,C_M=\dfrac{n}{V}=\dfrac{0,04}{0,1}=0,4M\)
\(b,V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(c,PTHH:\)
\(CH_3COOH+C_2H_5OH\underrightarrow{t^o,H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
0,04 0,04
\(m_{este}=0,04.90\%.88=3,168\left(g\right)\)
\(a) C_6H_{12}O_6 \xrightarrow{t^o,xt} 2CO_2 + 2C_2H_5OH\\ C_2H_5OH + O_2 \xrightarrow{men\ giấm} CH_3COOH + H_2O\\ CH_3COOH + C_2H_5OH \to CH_3COOC_2H_5 + H_2O\\ b) C_{12}H_{22}O_{11} + H_2O \xrightarrow{H^+}C_6H_{12}O_6 + C_6H_{12}O_6\\ C_6H_{12}O_6 \xrightarrow{t^o,xt} 2CO_2 + 2C_2H_5OH\\C_2H_5OH + O_2 \xrightarrow{men\ giấm} CH_3COOH + H_2O\\ CH_3COOH + NaOH \to CH_3COONa + H_2O\\ c) CH_3COOC_2H_5 + NaOH \to CH_3COONa + C_2H_5OH\\ d) 2CH_3COOC_2H_5 + Ca(OH)_2 \to (CH_3COO)_2Ca + 2C_2H_5OH\)
\((CH_3COO)_2Ca + H_2SO_4 \to CaSO_4 + 2CH_3COOH\)
\(n_{NaOH}=0,2.1,5=0,3\left(mol\right)\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,1---------->0,1
=> mNaOH = 0,1.40 = 4 (g)
=> \(C\%_{NaOH}=\dfrac{4}{80}.100\%=5\%\)
PTHH: CH3COOH + C2H5OH --H2SO4(đặc), to--> CH3COOC2H5 + H2O
0,3------------------------------------------------>0,3
=> meste = 0,3.88.80% = 21,12 (g)
Cảm ơn bạn nhìu nhoa ^-^