7. Cho 100g dd CH3COOH 12% tác dụng vừa đủ với dung dịch NaHCO3 8,4%. Tính mdd NAaHCO3 và C% của dung dịch muối thu được
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\(m_{CH_3COOH}=12\%.100=12\left(g\right)\\ n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2--------->0,2------------>0,2
\(m_{NaOH}=0,2.40=8\left(g\right)\\ m_{ddNaOH}=\dfrac{8}{8,4\%}=\dfrac{2000}{21}\left(g\right)\\ m_{ddCH_3COONa}=\dfrac{2000}{21}+100=\dfrac{4100}{21}\left(g\right)\\ m_{CH_3COONa}=0,2.82=16,4\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{16,4}{\dfrac{4100}{21}}.100\%=8,4\%\)
`=>` Gợi ý:
`CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O`
`mCH3COOH = 100x12/100 = 12` (g)
`==> nCH3COOH = m/M = 12/60 = 0.2` (mol)
Theo pt: `=> nNaHCO3 = 0.2` (mol)
`==> mNaHCO3 = n.M = 0.2x84 =16.8` (g)
`==> mdd NaHCO3 = 16.8x100/8.4 = 200` (g)
Ta có: `nCH3COONa = 0.2` (mol)
CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O
mCH3COOH = 100x12/100 = 12 (g)
==> nCH3COOH = m/M = 12/60 = 0.2 (mol)
Theo pt: => nNaHCO3 = 0.2 (mol)
==> mNaHCO3 = n.M = 0.2x84 =16.8 (g)
==> mdd NaHCO3 = 16.8x100/8.4 = 200 (g)
Ta có: nCH3COONa = 0.2 (mol)
==> mCH3COONa = n.M = 0.2 x 82 = 16.4 (g)
mdd sau pứ = 200 + 100 - 0.2 x 44 =291.2 (g)
C% = 16.4 x 100/ 291.2 = 5.63%
\(m_{Ba\left(OH\right)_2}=\dfrac{100\cdot17,1\%}{100\%}=17,1\left(g\right)\\ n_{Ba\left(OH\right)_2}=\dfrac{17,1}{171}=0,1\left(mol\right)\\ PTHH:Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+H_2O\\ n_{BaCl_2}=n_{Ba\left(OH\right)_2}=0,1\left(mol\right)\\ \Rightarrow m_{muối.sau.p/ứ}=m_{BaCl_2}=0,1\cdot208=20,8\left(g\right)\)
PTHH: \(CH_3COOH+KHCO_3\rightarrow CH_3COOK+H_2O+CO_2\uparrow\)
a) Ta có: \(n_{CH_3COOH}=\dfrac{200\cdot24\%}{60}=0,8\left(mol\right)=n_{KHCO_3}\)
\(\Rightarrow m_{ddKHCO_3}=\dfrac{0,8\cdot100}{16,8\%}\approx476.2\left(g\right)\)
b) Theo PTHH: \(n_{CH_3COOK}=0,8\left(mol\right)=n_{CO_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_3COOK}=0,8\cdot98=78,4\left(g\right)\\m_{CO_2}=0,8\cdot44=35,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddCH_3COOH}+m_{ddKHCO_3}-m_{CO_2}=641\left(g\right)\)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{78,4}{641}\cdot100\%\approx12,23\%\)
a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
Khối lượng dung dịch NaHCO3:
CH3COOH + NaHCO3 → CH3COONa + CO2 + H2O
nCH3COOH = 12 / 60 = 0,2 mol.
nNaHCO3 = 0,2mol.
mNaHCO3 cần dùng = 0,2 x 84 = 16,8g.
Khối lượng dung dịch NaHCO3 cần dùng: 16,8 x 100 / 8,4 = 200g.
\(m_{CH_3COOH}=\dfrac{80.9}{100}=7,2\left(g\right)\)
\(n_{CH_3COOH}=\dfrac{7,2}{60}=0,12\left(mol\right)\)
PTHH :
\(15CH_3COOH+10NaHCO_3\rightarrow10CH_3COONa+2H_2O+20CO_2\uparrow\)
0,12 0,08 0,08 0,016 0,16
\(a,m_{NaHCO_3}=84.0,08=6,72\left(g\right)\)
\(m_{ddNaHCO_3}=\dfrac{6,72.100}{4,2}=160\left(g\right)\)
\(b,m_{CH_3COONa}=0,08.82=6,56\left(g\right)\)
\(m_{H_2O}=0,016.18=0,288\left(g\right)\)
\(m_{CO_2}=0,16.44=7,04\left(g\right)\)
\(m_{ddCH_3COONa}=80+160-0,288-7,04=232,672\left(g\right)\)
\(C\%=\dfrac{6,56}{232,672}\approx2,82\%\)
a)
$CH_3COOH + NaHCO_3 \to CH_3COONa + CO_2 + H_2O$
b)
n NaHCO3 = n CH3COOH = 100.12%/60 = 0,2(mol)
m dd NaHCO3 = 0,2.84/8% = 210(gam)
c)
n CO2 = n CH3COOH = 0,2(mol)
=> V CO2 = 0,2.22,4 = 4,48(lít)
d)
m dd = m dd CH3COOH + m dd NaHCO3 - m CO2 = 100 + 210 - 0,2.44 = 301,2(gam)
C% CH3COONa = 0,2.82/301,2 .100% = 5,44%
Ta có: \(m_{CH_3COOH}=100.12\%=12\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{ddNaHCO_3}=\dfrac{0,2.84}{8,4\%}=200\left(g\right)\)
Ta có: m dd sau pư = m dd CH3COOH + m dd NaHCO3 - mCO2 = 100 + 200 - 0,2.44 = 291,2 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,2.82}{291,2}.100\%\approx2,82\%\)