Cho 10,08lit hỗn hợp khí X gồm axetilen và menta qua dd brom dư thấy có 64g bom mất màu a. Viết pthh và tính V khí metan b. Đốt cháy hết X, rồi dẫn sp cháy qua dd nc vôi trong dư. Tính khối lượng kết tủa thu được (Các khí đo ở nhiệt độ tiêu chuẩn) Cần gấp ạ!!!
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\(n_{hh}=6,72:22,4=0,3mol\\ C_2H_2+2Br_2->C_2H_2Br_4\\ C_2H_4+Br_2->C_2H_2Br_2\\ n_{Br_2}=0,4mol\\ n_{C_2H_2}=a;n_{C_2H_4}=b\\ a+b=0,3\\ 2a+b=0,4\\ a=0,2;b=0,1\\ \%V_{C_2H_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\ \%V_{C_2H_4}=33,33\%\)
1/2 hỗn hợp có 0,1 mol C2H2 và 0,05mol C2H4
\(BT.C:n_{CO_2}=2n_{C_2H_2}+2n_{C_2H_4}=0,3mol\\ n_{CaCO_3}=n_{CO_2}=0,3\\ m_{KT}=0,3.100=30g\)
a)
PTHH: C2H2+2Br2 --> C2H2Br4
b) \(n_{C_2H_2}=\dfrac{36}{26}=\dfrac{18}{13}\left(mol\right)\)
=> \(V_{C_2H_2}=\dfrac{18}{13}.22,4=\dfrac{2016}{65}\left(l\right)\)
\(n_{CH_4}=\dfrac{42-36}{16}=0,375\left(mol\right)\)
=> \(V_{CH_4}=0,375.22,4=8,4\left(l\right)\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{\dfrac{2016}{65}}{\dfrac{2016}{65}+8,4}.100\%=78,69\%\\\%V_{CH_4}=\dfrac{8,4}{\dfrac{2016}{65}+8,4}.100\%=21,31\%\end{matrix}\right.\)
Theo gt ta có: $n_{hh}=0,08(mol);n_{Br_2}=0,08(mol)$
$C_2H_2+2Br_2\rightarrow C_2H_2Br_4$
Suy ra $n_{C_2H_2}=0,04(mol)=n_{CH_4}$
a, $\Rightarrow \%V_{C_2H_2}=\%V_{C_2H_4}=50\%$
b, $CH_4+2O_2\rightarrow CO_2+2H_2O$
$2C_2H_2+5O_2\rightarrow 4CO_2+2H_2O$
Ta có: $n_{O_2}=0,04.2+0,04.5=0,28(mol)\Rightarrow m_{O_2}=8,96(g)$
\(a)C_2H_2 +2Br_2 \to C_2H_2Br_2\\ n_{C_2H_2} = \dfrac{1}{2}n_{Br_2} = \dfrac{0,4.0,2}{2} = 0,04(mol)\\ \Rightarrow V_{C_2H_2} = 0,04.22,4 = 0,896(lít)\\ \%V_{C_2H_2} =\dfrac{0,896}{1,792}.100\% = 50\%\\ \Rightarrow \%V_{CH_4} = 100\% -50\% = 50\%\\ b)\\V_{CH_4} = V_{C_2H_2} = 0,896(lít)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_2 + \dfrac{5}{2}O_2 \xrightarrow{t^o} 2CO_2 + H_2O\\ \)
\(V_{O_2} = 2V_{CH_4} + \dfrac{5}{2}V_{C_2H_2} = 4,032(lít)\\ \Rightarrow m_{O_2} = \dfrac{4,032}{22,4}.32 = 5,76(gam)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
a) Ta có: \(n_{C_2H_4}=\dfrac{9,1}{28}=0,325\left(mol\right)=n_{Br_2}\) \(\Rightarrow V_{Br_2}=\dfrac{0,325}{2}=0,1625\left(l\right)=162,5\left(ml\right)\)
b) Ta có: \(\left\{{}\begin{matrix}n_{C_2H_4}=0,325\left(mol\right)\\n_{CH_4}=\dfrac{13,44}{22,4}-0,325=0,275\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{hh}=9,1+0,275\cdot16=13,5\left(g\right)\)
c) PTHH: \(CH_4+2O_2 \underrightarrow{t^o} CO_2+2H_2O\)
\(C_2H_4+3O_2 \underrightarrow{t^o} 2CO_2+ 2H_2O\)
Theo các PTHH: \(\Sigma n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=1,525\left(mol\right)\)
\(\Rightarrow V_{O_2}=1,525\cdot22,4=34,16\left(l\right)\)
C2H4+Br2->C2H4Br2
0,05----0,05
n Br2=\(\dfrac{8}{160}\)=0,05 mol
=>%VC2H4=\(\dfrac{0,05.22,4}{5,6}.100=20\%\)
=>%VCH4=80%
c)CH4+2O2-to>CO2+2H2O
1.10-3----2.10-3 mol
C2H4+3O2-to>2CO2+2H2O
2,5.10-4-7,5.10-4 mol
n hh=\(\dfrac{0,028}{22,4}\)=1,25.10-3 mol
=>n C2H4=2,5.10-4 mol
=>n CH4=1.10-3 mol
=>VO2=(2.10-3+7,5.10-4).22,4=0,0616l
\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)
\(\Rightarrow n_{etilen}=n_{Br_2}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(\Rightarrow n_{metan}=n_{hh}-n_{etilen}=0,25-0,05=0,2mol\)
a)\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b)\(\%V_{metan}=\dfrac{0,2}{0,25}\cdot100\%=80\%\)
\(\%V_{etilen}=100\%-80\%=20\%\)
a)
$C_2H_4 + Br_2 \to C_2H_4Br_2$
$CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
$CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$
b) Theo PTHH :
$n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160} = 0,05(mol)$
$n_{CH_4} = n_{CaCO_3} = \dfrac{15}{100} = 0,15(mol)$
$\%V_{C_2H_4} = \dfrac{0,05}{0,05 + 0,15}.100\% = 25\%$
$\%V_{CH_4} = 100\% - 25\% = 75\%$
a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{200.8\%}{160}=0,1\left(mol\right);n_{hh}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1<-----0,1
b) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1}{0,3}.100\%=33,33\%\\\%V_{CH_4}=100\%-33,33\%=66,67\%\end{matrix}\right.\)
c) \(n_{CH_4}=0,3-0,1=0,2\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,2--->0,4
\(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)
0,1--->0,3
\(\Rightarrow V_{O_2}=\left(0,3+0,4\right).24,79=17,353\left(l\right)\)
\(n_{CO_2}=\dfrac{8,96}{22,4}=0,4mol\)
\(m_{tăng}=m_{Br_2}=m_{C_2H_2}=2,6g\)
\(\Rightarrow n_{C_2H_2}=\dfrac{2,6}{26}=0,1mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,1 0,1
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^o}2CO_2+H_2O\)
0,1 0,25 0,2
\(\Rightarrow n_{CO_2\left(CH_4\right)}=0,4-0,2=0,2mol\)
\(\Rightarrow n_{CH_4}=0,2mol\Rightarrow n_{O_2}=0,4mol\)
a)\(\%V_{CH_4}=\dfrac{0,2}{0,4}\cdot100\%=50\%\)
\(\%V_{C_2H_2}=100\%-50\%=50\%\)
b)\(\Sigma n_{O_2}=0,4+0,25=0,65mol\)
\(\Rightarrow V_{O_2}=0,65\cdot22,4=14,56l\)
\(\Rightarrow V_{kk}=14,56\cdot5=72,8l\)
Sửa : 29,25 \(\to\) 29,55
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160} = 0,05(mol)\\ \Rightarrow m_{C_2H_4} = 0,05.28 = 1,4(gam)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 +3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ba(OH)_2 \to BaCO_3 + H_2O\\ n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = n_{CH_4} + 0,05.2 = n_{BaCO_3} = \dfrac{29,55}{197}=0,15(mol) \\ \Rightarrow n_{CH_4} = 0,05(mol)\\ \Rightarrow m_{CH_4} = 0,05.16 = 0,8(gam)\)
Đầu tiên, không có nước Br chỉ có nước Br2 em nhé!
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nBr2= 8/160=0,05(mol)
PTHH: C2H4 + Br2 -> C2H4Br2
nC2H4=nBr2=0,05(mol) => mC2H4=0,05.28=1,4(g)
- Khí bay ra là khí CH4.
CH4 + 2 O2 -to-> CO2 + 2 H2O
CO2 + Ba(OH)2 -> BaCO3 + H2O
nBaCO3=29,25/197= 117/ 788 (mol ) (Số xấu quá em ơi)
=> nCH4=nCO2=nBaCO3= 117/788(mol)
=> mCH4=16. 117/788= 468/197(g)
a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\)
Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,2\left(mol\right)\)
Mà: \(n_X=\dfrac{10,08}{22,4}=0,45\left(mol\right)\Rightarrow n_{CH_4}=0,25\left(mol\right)\)
\(\Rightarrow V_{CH_4}=0,25.22,4=5,6\left(l\right)\)
c, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,65\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,65\left(mol\right)\Rightarrow m_{CaCO_3}=0,65.100=65\left(g\right)\)