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Ta có: \(n_{Br_2}=\dfrac{6}{160}=0,0375\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,0375\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,0375.22,4}{6,72}.100\%=12,5\%\\\%V_{CH_4}=87,5\%\end{matrix}\right.\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{48}{160}=0,3\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,2.22,4}{5,6}.100\%=80\%\\\%V_{C_2H_2}=20\%\end{matrix}\right.\)
b, \(V_{ddBr_2}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, Ta có: \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,08\left(mol\right)\)
\(\Rightarrow V_{C_2H_4}=0,08.22,4=1,792\left(l\right)\)
c, Theo PT: \(n_{Br_2}=n_{C_2H_4Br_2}=0,08\left(mol\right)\)
\(\Rightarrow m_{Br_2}=0,08.160=12,8\left(g\right)\)
\(\Rightarrow m_{ddBr_2}=\dfrac{12,8}{8\%}=160\left(g\right)\)
\(n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,2}{1}\), ta được Br2 dư.
→ Dd Brom nhạt màu dần.
a)
C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)
\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,5 0,5
\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)
\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)
\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)
\(\%V_{C_2H_4}=100\%-60\%=40\%\)
a.b.\(m_{tăng}=m_{C_2H_4}=2,8g\)
\(n_{C_2H_4}=\dfrac{2,8}{28}=0,1mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(n_{hh}=\dfrac{6,72}{22,4}=0,3mol\)
\(\rightarrow m_{CH_4}=\left(0,3-0,1\right).16=3,2g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{2,8}{2,8+3,2}.100=46,67\%\\\%m_{CH_4}=100\%-46,67\%=53,33\%\end{matrix}\right.\)
c.\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,2 0,2 ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,1 0,2 ( mol )
\(V_{CO_2}=\left(0,2+0,2\right).22,4=8,96l\)
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