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nFe = 16.8/56 = 0.3 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
2Fe + 3O2 -to-> Fe3O4
0.2___0.3________0.1
mFe dư = ( 0.3 - 0.2 ) * 56 = 5.6 (g)
mFe3O4 = 0.1*232 = 23.2 (g)
a)
3Fe+2O2→Fe3O4
b)
nFe=16,8/56=0,3mol
nO2=6,72/22,4=0,3mol
Ta có: 0,3/3<0,3/2=> O2 dư tính theo Fe
nFe3O4=0,3/3=0,1
mFe3O4=0,1.232=23,2g
\(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)
4P + 5O2 \(\underrightarrow{t^o}\) 2P2O5
\(\dfrac{0,1}{4}< \dfrac{0,2}{5}\) => O2 dư, Photpho đủ
\(n_{O_2}=0,2-0,04=0,16\left(mol\right)\)
\(m_{P_2O_5}=\) 0,05 . 142 = 7,1 ( g )
\(a) n_P = \dfrac{18,6}{31} = 0,6(mol)\\ n_{O_2} = \dfrac{20,16}{22,4} = 0,9(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,15 < \dfrac{n_{O_2}}{5} = 0,18 \to O_2\ dư\\ n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,75(mol)\\ \Rightarrow m_{O_2\ dư} = (0,9-0,75).32 = 4,8(gam)\\ b) n_{Fe} = \dfrac{56}{56} = 1(mol)\)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ \dfrac{n_{Fe}}{3} = \dfrac{1}{3}<\dfrac{n_{O_2}}{2} = 0,45\to Fe\ cháy\ hết.\\ c)\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,9.2 = 1,8(mol)\\ \Rightarrow m_{KMnO_4} = 1,8.158 =284,4(gam)\)
\(n_{KMnO_4}=\dfrac{18.96}{158}=0.12\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...........................................0.06\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(4Al+3O_2\underrightarrow{t^0}2Al_2O_3\)
\(0.08.....0.06.......0.04\)
\(m_{Al\left(dư\right)}=\left(0.2-0.08\right)\cdot27=3.24\left(g\right)\)
\(m_{Al_2O_3}=0.04\cdot102=4.08\left(g\right)\)
\(n_S=\dfrac{3,2}{32}=0,1\left(mol\right)\\
n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\
pthh:S+O_2\underrightarrow{t^o}SO_2\\
LTL:\dfrac{0,1}{1}>\dfrac{0,05}{1}\)
=> S dư
\(n_{S\left(P\text{Ư}\right)}=n_{SO_2}=n_{O_2}=0,05\left(mol\right)\\
m_S=\left(0,1-0,05\right).32=1,6\left(g\right)\\
V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}< \dfrac{0,4}{5}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\Rightarrow n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,15.32=4,8\left(g\right)\)
c, Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
d, \(m_{P_2O_5}=14,2.80\%=11,36\left(g\right)\)
nS=mS/MS=3,2/32=0,1(mol)
nO2=VO2/22,4=32/22,4=1,42(mol)
PTHH: S + O2 --> SO2 (1)
BĐ: 0,1 1,42
PỨ: 0,1-->0,1-->0,1
SPỨ: 0--->1,32-->0,1
a) Từ PT(1)=>O2 dư
VO2(dư)=nO2(dư) .22,4=1,32 .22,4=29,568(l)
b) Từ PT(1)=>nSO2=0,1(mol)
=>mSO2=n.M=0,1 .64=6,4(g)
Mình sửa lại nha mình nhầm ạ
PTHH : \(4Fe+3O_2\left(t^o\right)-->2Fe_2O_3\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16.8}{56}=0.3\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22.4}=\dfrac{17.92}{22.4}=0.8\left(mol\right)\)
Có \(n_{Fe}< n_{O_2}\) (0.3 < 0.8) => O2 dư , Fe hết
\(n_{O_2\left(dư\right)}=n_{O_2\left(PƯ\right)}-n_{Fe}=0.8-0.3=0.5\left(mol\right)\)
=> \(m_{O_2\left(dư\right)}=n_{O_2\left(dư\right)}.M=16\left(g\right)\)
Sản phẩm thu đc lak Fe2O3
Từ PTHH => \(\dfrac{1}{2}n_{Fe}=n_{Fe_2O_3}=0.15\left(mol\right)\)
=> \(m_{Fe_2O_3}=n.M=0,15.\left(56.2+16.3\right)=24\left(g\right)\)
cảm ơn bạn nha