Hoà tan 5,6g Fe trong dd 100ml dd HCl 1M, tính thể tích H2 (dktc) thu được?
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\(n_{Fe}=\dfrac{5,6}{56}=0,1(mol);n_{HCl}=1.0,3=0,3(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ \)
Vì \(\dfrac{n_{Fe}}{1}<\dfrac{n_{HCl}}{2}\) nên HCl dư
Do đó \(n_{H_2}=n_{Fe}=0,1(mol)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24(l)\)
\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\
Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(n_{Fe_2O_3}=\dfrac{21,6-56.0,1}{160}=0,1mol\\
Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2\)
0,1 0,6 0,2 0,3
\(V_{ddHCl}=\dfrac{0,2+0,6}{1}=0,8l\\
b.C_{M_{FeCl_2}}=\dfrac{0,1}{0,8}=0,125M\\
C_{M_{FeCl_3}}=\dfrac{0,2}{0,8}=0,25M\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{HCl}=2n_{Fe}=0,2(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,2}{0,5}=0,4(l)\)
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{HCl}=0,2.2,5=0,5\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=0,2\left(mol\right);n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b,V_{ddsau}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddFeCl_2}=\dfrac{0,2}{0,2}=1\left(M\right);C_{MddHCl\left(dư\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right);n_{HCl}=0,1.1=0,1\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{2}\) => HCl hết, Fe dư
PTHH: Fe + 2HCl --> FeCl2 + H2
___________0,1-------------->0,05_____(mol)
=> VH2 = 0,05.22,4 = 1,12(l)