Hòa tan hoàn toàn 16 gam Fe2O3 vào dung dịch H2SO4 25%.
Tính khối lượng và nồng độ % của dung dịch muối thu được.
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Bài 1: a) \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
Theo PT: \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)
=> \(m_{ddHCl}=\dfrac{0,6.36,5}{14,6\%}=150\left(g\right)\)
b) \(n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)
=> \(m_{FeCl_3}=0,2.162,5=32,5\left(g\right)\)
a) \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
Theo PT: \(n_{H_2}=n_{H_2SO_4}=\dfrac{4,9\%.100}{98}=0,05\left(mol\right)\)
=> \(V_{H_2}=0,05.22,4=1,12\left(l\right)\)
b)Theo PT: \(n_{Mg}=n_{H_2SO_4}=0,05\left(mol\right)\)
=> \(m_{Mg}=0,05.24=1,2\left(g\right)\)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,2 0,2 0,2 0,2
a)\(V_{H_2}=0,2\cdot22,4=4,48l\)
b)\(m_{ZnSO_4}=0,2\cdot161=32,2g\)
\(m_{ddZnSO_4}=30+200-0,2\cdot2=229,6g\)
\(C\%=\dfrac{m_{ct}}{m_{dd}}\cdot100\%=\dfrac{32,2}{229,6}\cdot100\%=14,02\%\)
c)\(n_{CuO}=\dfrac{24}{80}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,2 0,2
\(m_{rắn}=m_{Cu}=0,2\cdot64=12,8g\)
nZn=1365=0,2molnZn=1365=0,2mol
Zn+H2SO4→ZnSO4+H2Zn+H2SO4→ZnSO4+H2
0,2 0,2 0,2 0,2
a)VH2=0,2⋅22,4=4,48lVH2=0,2⋅22,4=4,48l
b)mH2SO4=0,2⋅98=19,6gmH2SO4=0,2⋅98=19,6g
C%=mctmdd⋅100%=19,6200⋅100%=9,8%C%=mctmdd⋅100%=19,6200⋅100%=9,8%
c)nCuO=2480=0,3molnCuO=2480=0,3mol
CuO+H2→Cu+H2OCuO+H2→Cu+H2O
0,3 0,2 0,2
mrắn=mCu=0,2⋅64=12,8g.
Ta có: \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
______0,2_____0,4_____0,2 (mol)
a, \(m_{CuCl_2}=0,2.135=27\left(g\right)\)
b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow C\%_{HCl}=\dfrac{14,6}{300}.100\%\approx4,867\%\)
c, Ta có: m dd sau pư = 16 + 300 = 316 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{27}{316}.100\%\approx8,54\%\)
a)
Khối lượng của dung dịch:
\(m_{dd}=m_{ct}+m_{dm}=20+180=200\left(g\right)\)
Nồng độ phần trăm của dung dịch:
\(C\%=\dfrac{m_{ct}}{m_{dd}}.100\%=\dfrac{20}{200}.100\%=10\%\)
b) đề sai nha bạn
a) \(n_{FeCl_3}=\dfrac{16,25}{162,5}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
0,05<----0,3<-----0,1
=> \(m_{Fe_2O_3}=0,05.160=8\left(g\right)\)
b)
\(m_{HCl\left(bd\right)}=91,25.16\%=14,6\left(g\right)\)
mdd sau pư = 8 + 91,25 = 99,25 (g)
\(\left\{{}\begin{matrix}C\%\left(FeCl_3\right)=\dfrac{16,25}{99,25}.100\%=16,373\%\\C\%\left(HCldư\right)=\dfrac{14,6-0,3.36,5}{99,25}.100\%=3,678\%\end{matrix}\right.\)
\(n_{HCl}=1\cdot0,2=0,2\left(mol\right)\\ PTHH:MgO+2HCl\rightarrow MgCl_2+H_2O\\ a,n_{MgO}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\\ \Rightarrow m=m_{MgO}=0,1\cdot40=4\left(g\right)\\ b,n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\\ \Rightarrow m_{MgCl_2}=0,1\cdot95=9,5\left(g\right)\\ c,m_{CT_{HCl}}=0,2\cdot36,5=7,3\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{7,3}{250}\cdot100\%=2,92\%\)
\(n_{H_2O}=n_{MgO}=0,1\left(mol\right)\\ \Rightarrow m_{H_2O}=0,1\cdot18=1,8\left(g\right)\\ \Rightarrow m_{dd_{MgCl_2}}=4+250-1,8=252,2\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{252,2}\cdot100\%\approx3,77\%\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1mol\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1 0,3
\(m_{H_2SO_4}=0,3\cdot98=29,4\left(g\right)\)\(\Rightarrow m_{ddH_2SO_4}=\dfrac{29,4}{25}\cdot100=117,6\left(g\right)\)
\(m_{H_2O}=0,3\cdot18=5,4\left(g\right)\)
\(m_{Fe_2\left(SO_4\right)_3}=0,1\cdot400=40\left(g\right)\)
\(m_{ddsau}=16+117,6-5,4=128,2\left(g\right)\)
\(C\%=\dfrac{40}{128,2}\cdot100\%=31,2\%\)
Ta có: \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O
Theo PT: \(n_{H_2SO_4}=3.n_{H_2SO_4}=3.0,1=0,3\left(mol\right)\)
=> \(m_{H_2SO_4}=0,3.98=29,4\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{29,4}{m_{dd_{H_2SO_4}}}.100\%=25\%\)
=> \(m_{dd_{H_2SO_4}}=117,6\left(g\right)\)
=> \(m_{dd_{Fe_2\left(SO_4\right)_3}}=117,6+16=133,6\left(g\right)\)
Theo PT: \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,1\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}\dfrac{40}{133,6}.100\%=29,94\%\)