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Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
____0,1______0,2_____0,1____0,1 (mol)
a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)
Giải thích: Đáp án C
Gọi kim loại hóa trị II là M
M + 2HCl -> MCl2 + H2
Mol 0,0125 <- 0,0125
=> MM = 40g => Ca
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{HCl}=\dfrac{0,4}{2}=0,2\left(l\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=2\cdot0,15=0,3\left(mol\right)\)
Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên sau p/ứ Zn dư
\(\Rightarrow n_{Zn}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\\ \Rightarrow m_{Zn}=0,15\cdot65=9,75\\ \Rightarrow m_{Zn\left(dư\right)}=13-9,75=3,25\left(g\right)\\ c,n_{H_2}=n_{Zn}=0,15\left(mol\right)\\ \Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)
1)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,15->0,3--->0,15-->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) mdd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
=> \(C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%=7,38\%\)
2)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4---->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
mZnCl2 = 0,2.136 = 27,2 (g)
c) \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,2}=2M\)
d)
PTHH: A + 2HCl --> ACl2 + H2
0,2<--0,4
=> \(M_A=\dfrac{4,8}{0,2}=24\left(g/mol\right)\)
=> A là Mg(Magie)
nFe = 11,2/56 = 0,2 (mol)
nHCl = 18,25/36,5 = 0,5 (mol)
PTHH: Fe + 2HCl -> FeCl2 + H2
LTL: 0,2 < 0,5/2 => HCl dư
nH2 (lt) = nFe = 0,2 (mol)
VH2 (lt) = 0,2 . 22,4 = 4,48 (l)
VH2 (tt) = 4,48 . 60% = 2,688 (l)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,1---------------------->0,1
=> VH2 =0,1.22,4 = 2,24(l)
\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Bảo toàn nguyên tố H : \(n_{HCl}.1=n_{H_2}.2\\ \Rightarrow n_{HCl}=0,5.2=1\left(mol\right)\\ \Rightarrow V_{HCl}=\dfrac{1}{2}=0,5\left(lít\right)\)
nH2=11,222,4=0,5(mol)nH2=11,222,4=0,5(mol)
Bảo toàn nguyên tố H : nHCl.1=nH2.2⇒nHCl=0,5.2=1(mol)⇒VHCl=12=0,5(lít)
F e + 2 H C l → F e C L 2 + H 2
Vì H = 85% nên:
n H 2 = n F e p ư = 0,01275 mol
V H 2 = 0,01275.22,4= 0,2856 lit
⇒ Chọn C.