Để trung hòa 50g đ H2So4 19,6% cần vừa đủ 25g dd NaOH đã dùng ??😐😐😐
A) Tính nồng độ % của dd NaOH
B) Tính nồng độ % của ddthu được sau phản ứng
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\(n_{CuSO4}=\dfrac{16\%.50}{100\%.160}=0,05\left(mol\right)\)
Pt : \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,05-------->0,1---------->0,05--------->0,05
a) \(C\%_{ddNaOH}=\dfrac{0,1.40}{250}.100\%=1,6\%\)
b) \(m_{ddspu}=50+250-0,05.98=295,1\left(g\right)\)
\(C\%_{Na2SO4}=\dfrac{0,05.142}{295,1}.100\%=2,41\%\)
\(n_{CuSO_4}=\dfrac{m_{dd}\cdot C\%}{100\cdot M}=\dfrac{50\cdot16\%}{100\cdot\left(64+32+16\cdot4\right)}=0,05\left(mol\right)\)
\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
1 2 1 1
0,05 0,1 0,05 0,05 (mol)
\(a)C\%_{NaOH}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{01\cdot100\cdot\left(23+16+1\right)}{250}=1,6\%\)
\(b)m_{dd-sau-pư}=m_{dd_đ}+m_{ct_đ}-m\downarrow-m\uparrow\)
\(=50+250-\left(0,05\cdot23+32+16\cdot4\right)=294,05\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{0,05\cdot100\cdot\left(23\cdot2+32+16\cdot4\right)}{294,05}\approx2,41\%.\)
\(n_{NaOH}=0,02.2=0,04\left(mol\right)\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ a.n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,04}{2}=0,02\left(mol\right)\\ C_{MddH_2SO_4}=\dfrac{0,02}{0,08}=0,25\left(M\right)\\ b.\left[Na^+\right]=\dfrac{0,02.2}{0,02+0,08}=0,4\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,02+0,08}=0,2\left(M\right)\)
\(n_{NaOH}=0,2.4=0,8\left(mol\right)\)
PT: \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,4\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{50}.100\%=78,4\%\)
a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
b. Đổi 100ml = 0,1 lít
Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)
=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)
c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)
=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2mol\\ a.MgCO_3+H_2SO_4->MgSO_4+H_2O+CO_2\\ 2NaOH+H_2SO_{\text{4 }}->Na_2SO_4+2H_2O\\ b.n_{H_2SO_4dư}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.80.0,1:40=0,1mol\\ n_{H_2SO_4\left(MgCO_3\right)}=0,2mol\\ c.C\%=\dfrac{98.0,3}{200}.100\%=14,7\%\\ V=0,2.22,4=4,48L\\ d.m_{ddsau}=200+16,8-44.0,2+80=288g\\ C\%_{Na_2SO_4}=\dfrac{40.0,1}{288}.100\%=1,39\%\\ C\%_{MgSO_4}=\dfrac{120.0,2}{288}.100\%=8,33\%\)
\(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
\(n_{NaOH}=\dfrac{80}{40}=2\left(mol\right)\)
PTHH :
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\)
0,2 0,2 0,2
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
2 1 1
Vậy có 0,2 mol H2SO4 phản ứng với MgCO3
có 1 mol H2SO4 phản ứng với NaOH
\(m_{H_2SO_4}=1,2.98=117,6\left(g\right)\)
\(c,C\%_{H_2SO_4}=\dfrac{117,6}{200}.100\%=58,8\%\)
\(V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(d,m_{Na_2SO_4}=1.142=142\left(g\right)\)
\(m_{ddNaOH}=\dfrac{80.100}{10}=800\left(g\right)\)
\(m_{ddH_2SO_4dư}=1.98:58,8\%\approx166,67\left(g\right)\)
\(m_{ddNa_2SO_4}=800+166,67=966,67\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{142}{966,67}.100\%\approx14,69\%\)
\(n_{Zn}=\dfrac{19.5}{65}=0.3\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.3........0.6.........0.3......0.3\)
\(m_{HCl}=0.3\cdot36.5=10.95\left(g\right)\)
\(C\%_{HCl}=\dfrac{10.95}{200}\cdot100\%=5.475\%\)
\(m_{\text{dung dịch sau phản ứng}}=19.5+200-0.3\cdot2=218.9\left(g\right)\)
\(m_{ZnCl_2}=0.3\cdot136=40.8\left(g\right)\)
\(C\%_{ZnCl_2}=\dfrac{40.8}{218.9}\cdot100\%=18.63\%\)
nCO2=0,4(mol)
a) PTHH: 2 NaOH + CO2 -> Na2CO3 + H2O
0,8_________0,4________0,4(mol)
=> mNaOH=0,8.40=32(g)
=>C%ddNaOH=(32/200).100=16%
b) mddNa2CO3=mddNaOH+mCO2=200+0,4.44=217,6(g)
mNa2CO3=106.0,4=42,4(g)
=>C%ddNa2CO3=(42,4/217,6).100=19,485%
Chúc em học tốt!
nCO2=8,96/22,4=0,4mol
a/ CO2+2NaOH→Na2CO3+H2O
0,4 0,8 0,4 0,4
mNaOH=0,8.40=32g
C%ddNaOH=mct/mdd.100%=32/200.100%=16%
b/mCO2=0,4.44=17,6g
Theo định luật bảo toàn khối lượng:
mCO2+mNaOH=mNa2CO3
17,6g+200g=217,6g
mNa2CO3=0,4.106=42,4g
C%ddNa2CO3=mct/mdd.100%=42,4/217,6.100=19,4852g
H2SO4 + 2NaOH → Na2SO4 + 2H2O
\(m_{H_2SO_4}=50\times19,6\%=9,8\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
a) Theo PT: \(n_{NaOH}=2n_{H_2SO_4}=2\times0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,2\times40=8\left(g\right)\)
\(\Rightarrow C\%_{ddNaOH}=\dfrac{8}{25}\times100\%=32\%\)
b) Theo PT: \(n_{Na_2SO_4}=n_{H_2SO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{Na_2SO_4}=0,1\times142=14,2\left(g\right)\)
\(\Sigma m_{dd}=50+25=75\left(g\right)\)
\(\Rightarrow C\%_{ddNa_2SO_4}=\dfrac{14,2}{75}\times100\%=18,93\%\)