.Trung hòa 200g dd H2SO4, 9% bằng dd KOH 2M có khối lượng riêng là 1.12g/ml . Tính :
a)Thể tích dd KOH cần dùng cho phản ứng trên ?
b)Khối lượng muối tạo thành ? Khối lượng của dd KOH đã phản ứng?
c)Nồng độ % của muối trong dd muối tạo thành?
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2KOH+ H2SO4 ------> K2SO4+ 2H2O
0.2...........0.1...................0.1.........0.2
nH2SO4=(200.4.9%)/98=0.1 mol
a) VddKOH=\(\dfrac{0.2\cdot56}{1.12}\)=10 ml ( V=m/D)
b)mK2SO4=174*0.1=17.4 g
mddKOH=1.12*10=11.2 g (m=D*V)
c) mdd=200+11.2=211.2 g
=>C%K2SO4=(17.4*100)/211.2=8.24%
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
PTHH: \(2KOH\left(0,36\right)+H_2SO_4\left(0,18\right)\rightarrow K_2SO_4\left(0,18\right)+2H_2O\)
\(m_{H_2SO_4}=200.0,09=18\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{18}{98}\approx0,18\left(mol\right)\)
a) \(V_{ddKOH}=\dfrac{0,36}{2}=0,18l\)
b) \(m_{K_2SO_4}=0,18.174=31,32\left(g\right)\)
\(m_{ddKOH}=1,12.0,18=0,2016\left(g\right)\)
c) \(m_{ddsaupư}=m_{ddH_2SO_4}+m_{ddKOH}=200+0,2016=200,2016\left(g\right)\)
\(\Rightarrow C\%ddK_2SO_4=\dfrac{31,32}{200,2016}.100\%\approx15,64\%\%\)
mKOH=28(g)
nKOH=0.5(mol)
PTHH:2KOH+H2SO4->K2SO4+2H2O
a)Theo pthh:nH2SO4=1/2 nKOH->nH2SO4=0.25(mol)
mH2SO4=0.25*98=24.5(g)
C%ddH2SO4=24.5/100*100=24.5%
theo pthh:nK2SO4=nH2SO4->nK2SO4=0.25(mol)
mK2SO4=0.25*(39*2+96)=43.5(g)
c)mdd sau phản ứng:200+100=300(g)
d) C% muối=43.5:300*100=14.5%
\(n_{H_2SO_4}=0,1.0,75=0,075mol\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,075 0,15 0,075 0,15
\(a)m_{K_2SO_4}=0,075.175=13,05mol\)
\(b)H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{NaOH}=0,075.2=0,15mol\\ m_{ddNaOH}=\dfrac{0,15.40}{15\%}\cdot100\%=40g\\ V_{ddNaOH}=\dfrac{40}{1,05}=38,1ml\)
a) H2SO4 + 2NaOH --> Na2SO4 + 2H2O
b) \(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
PTHH: H2SO4 + 2NaOH --> Na2SO4 + 2H2O
0,2---->0,4
=> mNaOH = 0,4.40 = 16 (g)
=> \(m_{dd.NaOH}=\dfrac{16.100}{20}=80\left(g\right)\)
c)
PTHH: H2SO4 + 2KOH --> K2SO4 + 2H2O
0,2---->0,4
=> mKOH = 0,4.56 = 22,4 (g)
=> \(m_{dd.KOH}=\dfrac{22,4.100}{5,6}=400\left(g\right)\)
=> \(V_{dd.KOH}=\dfrac{400}{1,045}=382,775\left(ml\right)\)
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ pthh:H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,2 0,4
\(m_{\text{ }NaOH}=0,4.40=16g\\ m_{\text{dd}NaOH}=\dfrac{16.100}{20}=80g\)
\(pthh:H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,2 0,4
\(m_{KOH}=0,4.56=22,4g\\
m_{\text{dd}KOH}=\dfrac{22,4.100}{5,6}=400g\\
V_{\text{dd}}=\dfrac{400}{1,045}=382,7ml\)
\(V_{dd}=\dfrac{22,4}{1,045}=21,4354ml\)
Câu 16:
PTHH: \(KOH+HCl\rightarrow KCl+H_2O\)
Ta có: \(n_{HCl}=0,25\cdot1,5=0,375\left(mol\right)=n_{KOH}=n_{KCl}\)
\(\Rightarrow\left\{{}\begin{matrix}V_{KOH}=\dfrac{0,375}{2}=0,1875\left(l\right)\\C_{M_{KCl}}=\dfrac{0,375}{0,1875+0,25}\approx0,86\left(M\right)\end{matrix}\right.\)
Câu 18:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
a) Ta có: \(n_{H_2SO_4}=\dfrac{200\cdot14,7\%}{98}=0,3\left(mol\right)\)
\(\Rightarrow n_{KOH}=0,6\left(mol\right)\) \(\Rightarrow m_{ddKOH}=\dfrac{0,6\cdot56}{5,6\%}=600\left(g\right)\) \(\Rightarrow V_{ddKOH}=\dfrac{600}{10,45}\approx57,42\left(ml\right)\)
b) Theo PTHH: \(n_{K_2SO_4}=0,3\left(mol\right)\) \(\Rightarrow C\%_{K_2SO_4}=\dfrac{0,3\cdot174}{600+200}\cdot100\%=6,525\%\)
a) \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
\(n_{KOH}=\dfrac{200.11,2\%}{56}=0,4\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,2\left(mol\right)\)
\(m_{ddH_2SO_4}=\dfrac{0,2.98}{10\%}=196\left(g\right)\)
b) \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,2\left(mol\right)\)
\(m_{ddsaupu}=200+196=396\left(g\right)\)
=> \(C\%_{K2SO4}=\dfrac{0,2.174}{396}.100=8,79\%\)
c) \(3KOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3KCl\)
\(n_{FeCl_3}=n_{Fe\left(OH\right)_3}=\dfrac{1}{3}n_{KOH}=\dfrac{2}{15}\left(mol\right)\)
=>\(V_{FeCl_3}=\dfrac{2}{15}=0,13\left(l\right)\)
\(m_{Fe\left(OH\right)_3}=\dfrac{2}{15}.107=14,27\left(g\right)\)