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\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
b,\(n_{HCl}=0,2.2=0,4\left(mol\right)\)
PTHH: CuO + 2HCl → CuCl2 + H2
Mol: 0,2 0,4
\(\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
c,\(n_{ZnO}=\dfrac{16,2}{81}=0,2\left(mol\right)\)
PTHH: ZnO + H2SO4 → ZnSO4 + H2
Mol: 0,2 0,2
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,2}{2}=0,1\left(l\right)\)
d,\(n_{H_2SO_4}=2.0,1=0,2\left(mol\right)\)
PTHH: H2SO4 + 2KOH → K2SO4 + 2H2O
Mol: 0,2 0,4
\(\Rightarrow V_{ddKOH}=\dfrac{0,4}{1}=0,4\left(l\right)\)
a, \(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
Theo PT: \(n_{NaOH}=2n_{Na_2O}=0,5\left(mol\right)\)
\(\Rightarrow CM_{NaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,46\left(ml\right)\)
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
a) \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
\(n_{KOH}=\dfrac{200.11,2\%}{56}=0,4\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,2\left(mol\right)\)
\(m_{ddH_2SO_4}=\dfrac{0,2.98}{10\%}=196\left(g\right)\)
b) \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,2\left(mol\right)\)
\(m_{ddsaupu}=200+196=396\left(g\right)\)
=> \(C\%_{K2SO4}=\dfrac{0,2.174}{396}.100=8,79\%\)
c) \(3KOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3KCl\)
\(n_{FeCl_3}=n_{Fe\left(OH\right)_3}=\dfrac{1}{3}n_{KOH}=\dfrac{2}{15}\left(mol\right)\)
=>\(V_{FeCl_3}=\dfrac{2}{15}=0,13\left(l\right)\)
\(m_{Fe\left(OH\right)_3}=\dfrac{2}{15}.107=14,27\left(g\right)\)