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Câu 1:
CuO + H2SO4 → CuSO4 + H2O
\(n_{CuO}=\frac{3,2}{80}=0,04\left(mol\right)\)
\(m_{H_2SO_4}=200\times9,8\%=19,6\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\frac{19,6}{98}=0,2\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{H_2SO_4}\)
Theo bài: \(n_{CuO}=\frac{1}{5}n_{H_2SO_4}\)
Vì \(\frac{1}{5}< 1\) ⇒ H2SO4 dư
Dung dịch sau pư gồm: H2SO4 dư và CuSO4
Ta có: \(m_{dd}saupư=3,2+200=203,2\left(g\right)\)
Theo Pt: \(n_{H_2SO_4}pư=n_{CuO}=0,04\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}dư=0,2-0,04=0,16\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}dư=0,16\times98=15,68\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}dư=\frac{15,68}{203,2}\times100\%=7,72\%\)
Theo Pt: \(n_{CuSO_4}=n_{CuO}=0,04\left(mol\right)\)
\(\Rightarrow m_{CuSO_4}=0,04\times160=6,4\left(g\right)\)
\(\Rightarrow C\%_{CuSO_4}=\frac{6,4}{203,2}\times100\%=3,15\%\)
Câu 2:
ZnO + H2SO4 → ZnSO4 + H2O
\(n_{ZnO}=\frac{8,1}{81}=0,1\left(mol\right)\)
\(m_{H_2SO_4}=200\times24,5\%=49\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\frac{49}{98}=0,5\left(mol\right)\)
Theo Pt: \(n_{ZnO}=n_{H_2SO_4}\)
Theo bài: \(n_{ZnO}=\frac{1}{5}n_{H_2SO_4}\)
Vì \(\frac{1}{5}< 1\) ⇒ H2SO4 dư
Dung dịch sau pư gồm: H2SO4 dư và ZnSO4
Ta có: \(m_{dd}saupư=8,1+200=208,1\left(g\right)\)
Theo PT: \(n_{H_2SO_4}pư=n_{ZnO}=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}dư=0,5-0,1=0,4\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,4\times98=39,2\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\frac{39,2}{208,1}\times100\%=18,84\%\)
Theo pT: \(n_{ZnSO_4}=n_{ZnO}=0,1\left(mol\right)\)
\(\Rightarrow m_{ZnSO_4}=0,1\times161=16,1\left(g\right)\)
\(\Rightarrow C\%_{ZnSO_4}=\frac{16,1}{208,1}\times100\%=7,74\%\)
\(m_{H_2SO_4}=\dfrac{19,6.100}{100}=19,6\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)
PTHH: 2KOH + H2SO4 ---> K2SO4 + 2H2O
0,4<-----0,2--------->0,2
\(\rightarrow m_{ddKOH}=\dfrac{0,4.56}{5,6\%}=400\left(g\right)\\ m_{dd\left(sau.pư\right)}=400+100=500\left(g\right)\\ m_{K_2SO_4}=174.0,2=34,8\left(g\right)\\ \rightarrow C\%_{K_2SO_4}=\dfrac{34,8}{500}.100\%=6,96\%\)
\(n_{H_2SO_4}=\dfrac{100.19,6\%}{98}=0,2mol\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
0,4 0,2 0,2 ( mol )
\(m_{ddKOH}=\dfrac{0,4.56}{5,6\%}=400g\)
\(C\%_{K_2SO_4}=\dfrac{0,2.174}{100+400}.100=6,96\%\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{200}.100\%=14,7\%\)
=> \(m_{H_2SO_4}=29,4\left(g\right)\)
=> \(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
a. PTHH: 2KOH + H2SO4 ---> K2SO4 + 2H2O
Theo PT: \(n_{KOH}=2.n_{H_2SO_4}=2.0,3=0,6\left(mol\right)\)
=> \(m_{KOH}=0,6.56=33,6\left(g\right)\)
Ta có: \(C_{\%_{KOH}}=\dfrac{33,6}{m_{dd_{KOH}}}.100\%=5,6\%\)
=> \(m_{dd_{KOH}}=600\left(g\right)\)
Theo đề, ta có:
\(D=\dfrac{600}{V_{dd_{KOH}}}=10,45\)(g/ml)
=> \(V_{dd_{KOH}}=57,42\left(ml\right)\)
b. Ta có: \(m_{dd_{K_2SO_4}}=200+33,6=233,6\left(g\right)\)
Theo PT: \(n_{K_2SO_4}=n_{H_2SO_4}=0,3\left(mol\right)\)
=> \(m_{K_2SO_4}=0,3.174=52,2\left(g\right)\)
=> \(C_{\%_{K_2SO_4}}=\dfrac{52,2}{233,6}.100\%=22,35\%\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 0,1
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\\
V_{H_2}=0,1.22,4=2,24l\\
m_{\text{dd}}=6,5+200-\left(0,1.2\right)=206,3g\)
bài 2 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(m_{HCl}=0,4.36,5=14,6g\\
V_{H_2}=0,2.22,4=4,48l\\
m\text{dd}=4,8+200-0,4=204,4g\\
C\%=\dfrac{0,2.136}{204,4}.100\%=13,3\%\)
mKOH=28(g)
nKOH=0.5(mol)
PTHH:2KOH+H2SO4->K2SO4+2H2O
a)Theo pthh:nH2SO4=1/2 nKOH->nH2SO4=0.25(mol)
mH2SO4=0.25*98=24.5(g)
C%ddH2SO4=24.5/100*100=24.5%
theo pthh:nK2SO4=nH2SO4->nK2SO4=0.25(mol)
mK2SO4=0.25*(39*2+96)=43.5(g)
c)mdd sau phản ứng:200+100=300(g)
d) C% muối=43.5:300*100=14.5%
Có nhầm đề không vậy ?
Câu 2
\(n_{H_2SO_4}=\dfrac{200.9,8\%}{98.100\%}=0,2\left(mol\right)\)
\(n_{KOH}=\dfrac{200.5,6\%}{56.100\%}=0,2\left(mol\right)\)
\(H_2SO_4+2KOH-->K_2SO_4+2H_2O\)
Ta có \(\dfrac{0,2}{1}>\dfrac{0,2}{2}\) => H2SO4 là chât còn dư
\(m_{K_2SO_4}=0,1.174=17,4\%\)
\(C\%_{K_2SO_4}=\dfrac{17,4}{200+200}.100\%=4,35\%\)
\(m_{H_2SO_4du}=\left(0,2-0,1\right).98=9,8\left(g\right)\)
\(C\%_{H_2SO_4du}=\dfrac{9,8}{200+200}.100\%=2,45\%\)