Cho 2,7g nhôm tác dụng với 100g dd HCl, thu được V lít khí và dd muối.
a) Tính V chất khí ở đktc
b) Tính nồng độ % của HCl
c) Tính nồng độ % của dd muối
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`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
a) \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2HCl + CaCO3 → CaCl2 + CO2 + H2O
Mol: 0,4 0,2 0,2
b) \(C\%_{ddHCl}=\dfrac{0,4.36,5.100\%}{100}=14,6\%\)
c) \(m_{CaCl_2}=0,2.101=20,2\left(g\right)\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
b) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\); nHCl = 0,5.2 = 1 (mol)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,1->0,3---->0,1---->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,5}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{1-0,3}{0,5}=1,4M\end{matrix}\right.\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(a,V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(b,m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{10}=146\left(g\right)\)
\(c,m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{ddMgCl_2}=4,8+146-\left(0,2.2\right)=150,4\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{150,4}.100\%\approx12,63\%\)
2.
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\)
\(2K+2H_2O\rightarrow2KOH+H_2\uparrow\)
0,2 0,2 0,1
\(m_{KOH}=0,2.56=11,2\left(g\right)\)
\(m_{ddKOH}=7,8+100-\left(0,1.2\right)=107,6\left(g\right)\)
\(C\%=\dfrac{11,2}{107,6}.100\%\approx10,4\%\)
a: \(n_{Zn}=\dfrac{2.6}{65}=0.04\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,04 0,04
\(m_{ZnCl_2}=0.04\left(65+35.5\cdot2\right)=5.44\left(g\right)\)
b: \(n_{HCl}=2\cdot0.04=0.08\left(mol\right)\)
\(m_{ct\left(HCl\right)}=0.08\cdot36.5=2.92\left(g\right)\)
\(C\%\left(HCl\right)=\dfrac{2.92}{200}=0.0146\)
d: \(n_{H_2}=n_{Zn}=0.04\left(mol\right)\)
V=0,04*22,4=0,896(lít)
C% thì đơn vị phải là phần trăm, PTHH cho ý cuối đâu
Theo gt ta có: $n_{Al}=0,1(mol)$
a, $2Al+6HCl\rightarrow 2AlCl_3+3H_2$
b, $\Rightarrow n_{H_2}=0,15(mol)\Rightarrow V_{H_2}=3,36(l)$
c, Ta có: $n_{HCl}=0,3(mol)\Rightarrow m_{HCl}=10,95(g)\Rightarrow \%m_{ddHCl}=219(g)$
d, Bảo toàn khối lượng ta có: $m_{dd}=221,4(g)$
$\Rightarrow \%C_{AlCl_3}=6,02\%$
Bài 1:
\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)
Bài 2:
\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)
\(n_{Al}=\dfrac{2.7}{27}=0.1\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0.1......0.3............0.1.........0.15\)
\(V_{H_2}=0.15\cdot22.4=3.36\left(l\right)\)
\(m_{HCl}=0.3\cdot36.5=10.95\left(g\right)\)
\(C\%_{HCl}=\dfrac{10.95}{100}\cdot100\%=10.95\%\)
\(m_{dd}=2.7+100-0.15\cdot2=102.4\left(g\right)\)
\(m_{AlCl_3}=0.1\cdot133.5=13.35\left(g\right)\)
\(C\%_{AlCl_3}=\dfrac{13.35}{102.4}\cdot100\%=13.04\%\)