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\(n_{CO_2\left(đktc\right)}=\dfrac{10,64}{22,4}=0,475\left(mol\right)\\a, K_2CO_3+2CH_3COOH\rightarrow2CH_3COOK+CO_2+H_2O\\ b,n_{K_2CO_3}=n_{CO_2}=0,475\left(mol\right)\\ \Rightarrow m_{K_2CO_3}=138.0,475=65,55\left(g\right)\\ n_{CH_3COOH}=0,475.2=0,95\left(mol\right)\\ C\%_{ddCH_3COOH}=\dfrac{0,95.60}{200}.100=28,5\%\)
$a\big)$
$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$
$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$
Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$
$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$
$\to \%m_{ZnO}=100-61,61=38,39\%$
$b\big)$
$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$
Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$
$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,2 ( mol )
\(m_{Zn}=0,2.65=13g\)
\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)
\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,4 ( mol )
\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)
\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)
0,1 0,2 ( mol )
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)
\(n_{Na}=\dfrac{9,2}{23}=0,4mol\)
\(Na+CH_3COOH\rightarrow CH_3COONa+\dfrac{1}{2}H_2\)
0,4 0,4 ( mol )
\(m_{CH_3COOH}=0,4.60=24g\)
Phương trình hóa học:
2CH3COOH + K2CO3 => CH3COOK + CO2 + H2O
nCO2 = V/22.4 = 10.64/22.4 = 0.475 (mol)
Theo phương trình => nCH3COOH = 0.95 (mol)
a = mCH3COOH = n.M = 0.95 x 60 = 57 (g)
C% = 57 x 100/200 = 28.5 (%)
\(n_{CH_3COOH}=\dfrac{130.12}{100.60}=0,26\left(mol\right)\)
\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\)
0,13 0,26 0,13 0,13 ( mol )
\(m_{CaCO_3}=0,13.100=13\left(g\right)\)
\(V_{CO_2}=0,13.22,4=2,912\left(l\right)\)
\(m_{ddspứ}=13+130-0,13.44=137,28\left(g\right)\)
\(C\%_{\left(CH_3COO\right)_3Ca}=\dfrac{0,13.158}{137,28}.100=14,96\%\)
2CH3COOH+Mg->(CH3COO)2Mg+H2
0,02---------------0,01-------0,01----------0,01
n muối=0,01mol
=>CM=\(\dfrac{0,02}{0,04}=0,5M\)
=>VH2=0,01.22,4=0,224l
CH3COOH+NaOH->CH3COONa+H2O
0,02--------------0,02
=>VNaOH=\(\dfrac{0,02}{0,75}=0,03l\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,01<-------0,02<------------0,01------->0,01
=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,04}=0,5M\)
b) VH2 = 0,01.22,4 = 0,224 (l)
c)
PTHH: NaOH + CH3COOH --> CH3COONa + H2O
0,02<------0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,75}=\dfrac{2}{75}\left(l\right)=\dfrac{80}{3}\left(ml\right)\)
\(n_{CO_2}=\dfrac{V}{22,4}=\dfrac{8,4}{22,4}=0,375\) (mol)
\(2Na_2CO_3+CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)
\(0,75\) mol \(0,375\) mol \(0,75\)mol \(0,375\)mol \(0,375\) mol
\(m_{Na_2CO_2}=n.M=0,75.106=79,5\)(g)
\(m_{CH_3COOH}=n.M=0,375.60=22,5\)(g)
\(C\%=\dfrac{m_{CH_3COOH}.100}{m_{ddCH_3COOH}}=\dfrac{22,5.100}{300}=7,5\%\)