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a) $2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
b)
n H2SO4 = 0,03.1 = 0,03(mol)
n NaOH = 2n H2SO4 = 0,06(mol)
=> CM NaOH = 0,06/0,05 = 1,2M
c) $H_2SO_4 + 2KOH \to K_2SO_4 + 2H_2O$
n KOH = 2n H2SO4 = 0,06(mol)
=> m KOH = 0,06.56 = 3,36 gam
=> m dd KOH = 3,36/5,6% = 60(gam)
=> V dd KOH = m/D = 60/1,045 = 57,42(ml)
1.
Al2O3 + 2NaOH -> 2NaAlO2 + H2O (1)
nNaAlO2=0,225(mol)
Từ 1:
nNaOH=nNaAlO2=0,225(mol)
nal2O3=\(\dfrac{1}{2}\)nNaAlO2=0,1125(mol)
V dd NaOH=0,225:5=0,045(lít)
mAl2O3=0,1125.102=11,475(g)
mquặng=11,475.110%=12,6225(g)
\(n_{Mg}=\dfrac{7.2}{24}=0.3\left(mol\right)\)
\(n_{HCl}=\dfrac{200\cdot14.6\%}{36.5}=0.8\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.3.........0.6.........0.3..........0.3\)
\(n_{HCl\left(dư\right)}=0.8-0.6=0.2\left(mol\right)\)
\(KOH+HCl\rightarrow KCl+H_2O\)
\(0.2........0.2\)
\(V_{dd_{KOH}}=\dfrac{0.2}{2}=0.1\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=7.2+200-0.3\cdot2=206.6\left(g\right)\)
\(m_{MgCl_2}=0.3\cdot95=28.5\left(g\right)\)
\(C\%MgCl_2=\dfrac{28.5}{206.6}\cdot100\%=13.8\%\)
\(C\%HCl\left(dư\right)=\dfrac{0.2\cdot36.5}{206.6}\cdot100\%=3.53\%\)
\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)
\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)
\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)
\(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)
Theo PT : \(n_{HCl}=2n_{Ba\left(OH\right)_2}=2.\dfrac{400.1,2.17,1\%}{171}=0,96\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,96.36,5}{3,65\%.1,05}=914,29\left(ml\right)\)
\(m_{Ba\left(OH\right)_2}=400\cdot1.2\cdot17.1\%=82.08\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{82.08}{171}=0.48\left(mol\right)\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.48..............0.96\)
\(m_{HCl}=0.96\cdot36.5=35.04\left(g\right)\)
\(m_{dd_{HCl}}=\dfrac{35.04}{3.65\%}=960\left(g\right)\)
\(V_{dd_{HCl}}=\dfrac{960}{1.05}=1008\left(ml\right)\)
Bài 8:
nH2SO4=0,5(mool)
PTHH: 2 KOH + H2SO4 -> K2SO4 + 2 H2O
nKOH= 2.0,5=1(mol) => mKOH=1.56=56(g)
=> mddKOH= (56.100)/25=224(g)
Bài 7:
mddNaOH= 2.1000.1,15=2300(g)
=> mNaOH=2300.30%=690(g)
=>nNaOH=690/40=17,25(mol)
??? Ủa xút là NaOH mà??
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
KOH + HCl -> KCl + H2O
nHCl=\(\dfrac{200.3,65\%}{36,5}=0,2\left(mol\right)\)
Theo PTHH ta có:
nKCl=nHCl=nKOH=0,2(mol)
Vdd KOH=\(\dfrac{0,2}{0,5}=0,4\left(lít\right)\)
mdd KOH=400.1,1=440(g)
mKCl=0,2.74,5=14,9(g)
C% dd KCl=\(\dfrac{14,9}{440+200}.100\%=2,33\%3\%\)