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\(a,n_{H_2SO_4}=0,3.0,75+0,3.0,25=0,3\left(mol\right)\\ V_{ddH_2SO_4}=300+300=600\left(ml\right)=0,6\left(l\right)\\ \rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,6}=0,5M\\ m_{H_2SO_4}=0,3.98=29,4\left(g\right)\\ m_{ddH_2SO_4}=600.1,02=612\left(g\right)\\ \rightarrow C\%_{H_2SO_4}=\dfrac{29,4}{612}.100\%=4,8\%\)
\(b,\) Đặt kim loại M có hoá trị n (n ∈ N*)
PTHH: \(2M+nH_2SO_4\rightarrow M_2\left(SO_4\right)_n+nH_2\uparrow\)
\(\dfrac{0,6}{n}\)<---0,3--------------------------->0,3
\(\rightarrow M_M=\dfrac{5,4}{\dfrac{0,6}{n}}=9n\left(g\text{/}mol\right)\)
Vì n là hoá trị của M nên ta xét bảng
| \(n\) | \(1\) | \(2\) | \(3\) |
| \(M_M\) | \(9\) | \(18\) | \(27\) |
| \(Loại\) | \(Loại\) | \(Al\) |
Vậy M là Al
\(c,n_{KClO_3}=\dfrac{15,3125}{122,5}=0,125\left(mol\right)\)
PTHH:
\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
0,3-->0,15
\(2KClO_3\xrightarrow[]{t^o}2KCl+3O_2\uparrow\)
0,1<---------------------0,15
\(\rightarrow H=\dfrac{0,1}{0,125}.100\%=80\%\)
a)
\(n_{H_2}=\dfrac{0,6}{2}=0,3\left(mol\right)\)
PTHH: 2M + 3H2SO4 --> M2(SO4)3 + 3H2
0,2<----0,3<--------0,1<-------0,3
=> \(M_M=\dfrac{5,4}{0,2}=27\left(g/mol\right)\)
=> M là Al
b) \(C\%_{dd.H_2SO_4}=\dfrac{0,3.98}{395,2}.100\%=7,44\%\)
c)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2-->0,6
=> \(V_{dd.HCl}=\dfrac{0,6}{1}=0,6\left(l\right)=600\left(ml\right)\)
\(Đặt.oxit:A_2O_3\\ A_2O_3+3H_2SO_4\rightarrow A_2\left(SO_4\right)_3+3H_2O\\ n_{Al_2O_3}=\dfrac{34,2-10,2}{96.3-16.3}=0,1\left(mol\right)\\ M_{A_2O_3}=\dfrac{10,2}{0,1}=102\left(\dfrac{g}{mol}\right)=2M_A+48\\ \Rightarrow M_A=27\left(\dfrac{g}{mol}\right)\\ a,\Rightarrow A.là.nhôm\left(Al=27\right)\\ b,n_{H_2SO_4}=3.0,1=0,3\left(mol\right)\\ C\%_{ddH_2SO_4}=\dfrac{0,3.98}{100}.100=29,4\%\\ c,n_{Al_2\left(SO_4\right)_3}=n_{Al_2O_3}=0,1\left(mol\right)\\ Al_2\left(SO_4\right)_3+6NaOH\rightarrow2Al\left(OH\right)_3+3Na_2SO_4\\ n_{NaOH}=6.0,1=0,6\left(mol\right)\\ V_{ddNaOH}=\dfrac{0,6}{1,5}=0,4\left(l\right)\)
a) \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
0,1---->0,1------->0,1---->0,1
=> \(m_{dd.H_2SO_4}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)
b) mdd sau pư = 2,4 + 200 - 0,1.2 = 202,2 (g)
mMgSO4 = 0,1.120 = 12 (g)
\(C\%_{MgSO_4}=\dfrac{12}{202,2}.100\%=5,9\%\)
c)
\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,25}{1}>\dfrac{0,1}{1}\) => Hiệu suất tính theo H2
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,05<-----0,05
=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
PTHH: Mg + H2SO4 ---> MgSO4 + H2
0,1--->0,1---------->0,1-------->0,1
\(m_{dd\left(H_2SO_4\right)}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)
b, \(m_{dd\left(sau.pư\right)}=2,4+200-0,2.2=202,2\left(g\right)\)
\(\rightarrow C\%_{MgSO_4}=\dfrac{0,1.120}{202,2}.100\%=5,93\%\)
c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,25 > 0,1 => CuO dư
\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)
Theo pt: \(n_{H_2}=n_{Cu}=0,05\left(mol\right)\)
=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(2A+2nHCl\rightarrow2ACl_n+nH_2\)
\(\dfrac{0.2}{n}.......................0.1\)
\(M_A=\dfrac{2.4}{\dfrac{0.2}{n}}=12n\left(\dfrac{g}{mol}\right)\)
\(BL:n=2\Rightarrow M=24\)
\(A:Mg\)
\(m_{MgCl_2}=0.1\cdot95=9.5\left(g\right)\)
\(m_{ddHCl}=\dfrac{0.2\cdot36.5}{7.3\%}=100\left(g\right)\)
\(m_{dd}=2.4+100-0.1\cdot2=102.2\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{9.5}{102.2}\cdot100\%=9.3\%\)
Fe+H2SO4->FeSO4+H2
0,15---0,15-----0,15---0,15 mol
n Fe=8,4\56=0,15 mol
=>VH2=0,15.22,4=3,36l
=>m H2SO4=0,15.98=14,7g
=>C% H2SO4=14,7\245 .100=6%
=>m dd muối=8,4+245-0,15.2=253,1g
=>C% muối =0,15.152\253,1 .100=9%